Related papers: H2CS deuteration maps towards the pre-stellar core…
Nitrogen (N) fractionation is used as a tool to search for a link between the chemical history of the Solar System and star-forming regions. A large variation of $^{14}$N/$^{15}$N is observed towards different astrophysical sources, and…
We determined the ortho/para (o/p) ratios of NH2D and NHD2 in the archetypical pre-stellar core L1544. The core was observed in the two lowest rotational lines of ortho- and para-NH2D using the APEX and the IRAM 30 m telescopes. The…
We present observations of the singly and doubly deuterated species of thioformaldehyde, HDCS and D$_2$CS, towards the dark cloud Barnard 1. This is the first detection of D$_2$CS in Space and in dense and cold prestellar regions. Column…
Context: Despite the low elemental deuterium abundance in the Galaxy, enhanced molecular D/H ratios have been found in the environments of low-mass star-forming regions and, in particular, the Class 0 protostar IRAS 16293-2422. Aims: The…
Measurements of deuterium in the local interstellar medium have revealed large variations in D/H along different lines of sight. Moreover, recent {\it Far Ultraviolet Spectroscopic Explorer} (FUSE) measurements find D/H to be anticorrelated…
Velocity profiles of ground state lines of H2D+, HC18O+ and N2H+, observed previously with the CSO and IRAM 30m telescopes, are modeled with a Monte Carlo radiative transfer program to study the temperature, density and velocity structure…
The deuterium enrichment of molecules is sensitive to their formation environment. Constraining patterns of deuterium chemistry in protoplanetary disks is therefore useful for probing how material is inherited or reprocessed throughout the…
Isotopologue abundance ratios are important to understand the evolution of astrophysical objects and ultimately the origins of a planetary system like our own. Being nitrogen a fundamental ingredient of pre-biotic material, understanding…
Aims: For the first time we investigate the role of the grain surface chemistry in the Horsehead Photo-dissociation region (PDR). Methods: We performed deep observations of several H2CO rotational lines toward the PDR and its associated…
The 692 GHz para ground-state line of D2H+ has been detected at the Caltech Submillimeter Observatory towards the pre-stellar core 16293E. The derived D2H+ abundance is comparable to that of H2D+, as determined by observations of the 372…
We model the interstellar dust content of the reionization era with a suite of cosmological, fluid-dynamical simulations of galaxies with stellar masses ranging from $\sim 10^5 - 10^9 M_{\odot}$ in the first $1.2$ billion years of the…
(abridged) We have mapped the prestellar core H-MM1 in Ophiuchus in rotational lines of ortho-H2D+ (oH2D+), N2H+, and DCO+ at the wavelength 0.8 mm with the Large APEX sub-Millimeter Array (LAsMA) multibeam receiver of the Atacama…
Dense cloud cores present chemical differentiation due to the different distribution of C-bearing and N-bearing molecules, the latter being less affected by freeze-out onto dust grains. In this letter we show that two C-bearing molecules,…
Prestellar cores exhibit a strong chemical differentiation, which is mainly caused by the freeze-out of molecules onto the grain surfaces. Understanding this chemical structure is important, because molecular lines are often used as probes…
Deuterium fractionation is a well-established evolutionary tracer in low-mass star formation, but its applicability to the high-mass regime remains an open question. The abundances and ratios of deuterated species have often been proposed…
We report the first detection of doubly-deuterated methanol (CHD2OH), as well as firm detections of the two singly-deuterated isotopomers of methanol (CH2DOH and CH3OD), towards the solar-type protostar IRAS16293-2422. From the present…
We use the COMPLETE Survey's observations of the Perseus star-forming region to assess and intercompare three methods for measuring column density in molecular clouds: extinction mapping (NIR); thermal emission mapping (FIR); and mapping…
The chemical evolution of pre-stellar cores during their transition to a protostellar stage is not yet fully understood. Detailed chemical characterizations of these sources are needed to better define their chemistry during star formation.…
We investigate 35 pre-stellar cores and 36 proto-stellar cores in the Perseus molecular cloud. We find a very tight correlation between the physical parameters describing the N2H+ and NH3 gas. Both the velocity centroids and the line widths…
The [HDO]/[H2O] ratio is a crucial parameter for probing the history of water formation. So far, it has been measured for only three solar type protostars and yielded different results, possibly pointing to a substantially different history…