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Molecular spin systems based on photoexcited triplet pairs formed via singlet fission (SF) are attractive as carriers of quantum information because of their potentially pure and controllable spin polarization, but developing systems that…

Mesoscale and Nanoscale Physics · Physics 2022-11-09 Gajadhar Joshi , Ryan D. Dill , Karl J. Thorley , John E. Anthony , Obadiah G. Reid , Justin C. Johnson

Singlet fission is a photoconversion process that generates a doubly excited, maximally spin entangled pair state. This state has applications to quantum information and computing that are only beginning to be realized. In this article, we…

Chemical Physics · Physics 2020-11-11 Kori Smyser , Joel Eaves

High-spin states in molecular systems hold significant interest for a wide range of applications ranging from optoelectronics to quantum information and singlet fission (SF). Quintet and triplet states play crucial roles, particularly in SF…

Molecular quantum sensors represent a promising frontier for the detection of nuclear magnetic resonance signals and alternating current magnetic fields at the nanoscale, potentially reaching single-proton sensitivity. Although the triplet…

Chemical Physics · Physics 2026-05-18 Maria Grazia Concilio , Yiwen Wang , Siyuan Wang , Xueqian Kong

Singlet fission, a process that splits a singlet exciton into a biexciton, has promise in quantum information. We report time-resolved electron paramagnetic resonance measurements on a molecule, TIPS-BP1$'$, designed to exhibit strongly…

Chemical Physics · Physics 2022-02-22 Ryan D. Dill , Kori E. Smyser , Niels H. Damrauer , Joel D. Eaves

For the theoretical screening of Singlet Fission (SF) rates in molecular aggregates, commonly dimer model systems are employed. However, there is experimental evidence, that the SF process proceeds from the $^{1}$(TT) state via an…

Chemical Physics · Physics 2023-12-22 Anurag Singh , Merle I. S. Röhr

This paper explores the potential for spin-triplet superconductivity in molecular beam epitaxy grown PbTe/SnTe semiconductor heterostructures. We present convincing evidence for spin-triplet pairing by soft point-contact spectroscopy…

From organic electronics to biological systems, understanding the role of intermolecular interactions between spin pairs is a key challenge. Here we show how such pairs can be selectively addressed with combined spin and optical…

Singlet exciton fission (SF), the conversion of one spin-singlet exciton (S1) into two spin-triplet excitons (T1), could provide a means to overcome the Shockley-Queisser limit in photovoltaics. SF as measured by the decay of S1 has been…

Singlet fission and triplet-triplet annihilation (TTA) are spin-dependent phenomena critical to optoelectronics. The dynamics of spin populations during geminate triplet pair separation are crucial for controlling fission and TTA rates. We…

Chemical Physics · Physics 2025-02-12 Yan Sun , M. Monteverde , V. Derkach , T. Chaneliere , E. Aldridge , J. E. Anthony , A. D. Chepelianskii

A theory of singlet fission in carotenoid dimers is presented which aims to explain the mechanism behind the creation of two uncorrelated triplets. Following the initial photoexcitation of a carotenoid chain to a "bright" $n^1B_u^+$ state,…

Chemical Physics · Physics 2024-11-22 Alexandru G. Ichert , William Barford

Singlet fission is commonly defined to involve a process by which an overall singlet state with local triplet structure spin-decoheres into two triplet states, thereby completing the fission process. This process, often defined in loose…

Chemical Physics · Physics 2020-07-29 Max Marcus , William Barford

Singlet fission (SF) is a photophysical process where a singlet excitation generates two triplet excited states, enhancing exciton multiplication potentially useful for solar energy conversion. Since SF typically outcompetes radiative…

Chemical Physics · Physics 2025-12-24 Sumanta Paul , Oleksandr Yampolskyy , Zehua Wu , Klaus Müllen , Thomas Basché

Spin triplet exciton formation sets limits on technologies using organic semiconductors that are confined to singlet-triplet photophysics. In contrast, excitations in the spin doublet manifold in organic radical semiconductors can show…

Chemical Physics · Physics 2023-12-19 Qinying Gu , Sebastian Gorgon , Alexander S. Romanov , Feng Li , Richard H. Frienda , Emrys Evansd

Singlet fission, the molecular process through which photons are effectively converted into pairs of lower energy triplet excitons, holds promise as a means of boosting photovoltaic device efficiencies. In the preceding article of this…

Materials Science · Physics 2017-05-12 Roel Tempelaar , David R. Reichman

The growing interest in harnessing singlet fission for photovoltaic applications stems from the possibility of generating two excitons from a single photon. Quantum efficiencies above unity have been reported, yet the correlation between…

We study the semi-inclusive production of real, high-$p_T$, isolated photons in unpolarized and polarized lepton-proton collisions, $\ell p\to \ell\gamma X$. In particular we analyze the transverse nucleon single-spin asymmetry within the…

High Energy Physics - Phenomenology · Physics 2020-03-25 Weeam S. Albaltan , Alexei Prokudin , Marc Schlegel

By measuring the THz electron spin resonance (ESR) transmission spectra and high-field magnetization on the spin-gapped system CuTe$_2$O$_5$, we identified the singlet-triplet excitations in the dimerized non-magnetic ground state. The…

Strongly Correlated Electrons · Physics 2011-11-22 Zhe Wang , M. Schmidt , Y. Goncharov , Y. Skourski , J. Wosnitza , H. Berger , H. -A. Krug von Nidda , A. Loidl , J. Deisenhofer

Non-relativistic spin-splitting in unconventional antiferromagnets has garnered much attention for its promising spintronic applications and open fundamental questions. Here, we uncover a unique even-parity spin texture in chiral…

Superconductivity · Physics 2026-02-24 Song-Bo Zhang , Lun-Hui Hu

When considering the optimal molecular packing to realize charge multiplication in organic photovoltaic materials, subtle changes in intermolecular charge transfer (CT) coupling can strongly modulate singlet fission. To understand why…

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