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In this paper a formalism for studying the dynamics of quantum systems coupled to classical spin environments is reviewed. The theory is based on generalized antisymmetric brackets and naturally predicts open-path off-diagonal geometric…

Quantum Physics · Physics 2016-10-21 Alessandro Sergi

Recently, synthetic spin-orbit coupling has been introduced into cold-atom systems for more flexible control of the Hamiltonian, which was further made time-varying through two-photon detuning to achieve dynamic control of the cold-atom…

Quantum Physics · Physics 2024-03-05 Dong Liu , Zejian Ren , Wai Chun Wong , Entong Zhao , Chengdong He , Ka Kwan Pak , Gyu-Boong Jo , Jensen Li

In this paper the evolution of a quantum system drived by a non-Hermitian Hamiltonian depending on slowly-changing parameters is studied by building an universal high-order adiabatic approximation(HOAA) method with Berry's phase ,which is…

High Energy Physics - Theory · Physics 2009-10-22 Chang-Pu Sun

In this article, we propose a Frozen Gaussian Sampling (FGS) algorithm for simulating nonadiabatic quantum dynamics at metal surfaces with a continuous spectrum. This method consists of a Monte-Carlo algorithm for sampling the initial wave…

Computational Physics · Physics 2022-11-30 Zhen Huang , Limin Xu , Zhennan Zhou

Reliable trajectory-based nonadiabatic quantum dynamics methods at the atomic level are critical for understanding many important processes in real systems. The paper reports latest progress of nonadiabatic field (NaF), a conceptually novel…

Chemical Physics · Physics 2025-04-14 Baihua Wu , Bingqi Li , Xin He , Xiangsong Cheng , Jiajun Ren , Jian Liu

We study a quantized, discrete and drifting version of the Harper Hamiltonian, also called the finite almost Mathieu operator, which resembles the pendulum Hamiltonian but in phase space is confined to a torus. Spacing between pairs of…

Quantum Physics · Physics 2025-10-08 Alice C. Quillen , Nathan Skerrett , Damian R. Sowinski , Abobakar Sediq Miakhel

We introduce an operational framework to analyze non-adiabatic Abelian and non-Abelian, cyclic and non-cyclic, geometric phases in open quantum systems. In order to remove the adiabaticity condition, we generalize the theory of dynamical…

Quantum Physics · Physics 2009-11-13 M. S. Sarandy , E. I. Duzzioni , M. H. Y. Moussa

We consider a periodically driven system where the high-frequency driving protocol consists of a sequence of potentials switched on and off at different instants within a period. We explore the possibility of introducing an adiabatic…

Quantum Physics · Physics 2025-02-26 Ashwin Murali , Tapomoy Guha Sarkar , Jayendra N. Bandyopadhyay

Magnetically trapped neutral atoms can be cooled with the evaporation technique. This is typically done by using a radiofrequency (rf) field that adiabatically couples trapped and untrapped internal atomic states for atoms with kinetic…

Atomic Physics · Physics 2009-10-31 K. -A. Suominen , E. Tiesinga , P. S. Julienne

y formally diagonalizing with accuracy $\hbar$ the Hamiltonian of electrons in a crystal subject to electromagnetic perturbations, we resolve the debate on the Hamiltonian nature of semiclassical equations of motion with Berry-phase…

Other Condensed Matter · Physics 2016-08-16 Pierre Gosselin , Fehrat Ménas , Alain Bérard , Hervé Mohrbach

We present a new non-adiabatic ring polymer molecular dynamics (NRPMD) method based on the spin mapping formalism, which we refer to as the spin-mapping NRPMD (SM-NRPMD) approach. We derive the path-integral partition function expression…

Chemical Physics · Physics 2021-06-02 Duncan Bossion , Sutirtha N. Chowdhury , Pengfei Huo

A new scheme is proposed for modeling molecular nonadiabatic dynamics near metal surfaces. The charge-transfer character of such dynamics is exploited to construct an efficient reduced representation for the electronic structure. In this…

Chemical Physics · Physics 2020-09-24 Zuxin Jin , Joseph E. Subotnik

In this work, we describe various improved implementations of the mapping approach to surface hopping (MASH) for simulating nonadiabatic dynamics. These include time-reversible and piecewise-continuous integrators, which is only formally…

Chemical Physics · Physics 2026-03-31 J. Amira Geuther , Kasra Asnaashari , Jeremy O. Richardson

Appearance of adiabatic geometric phase shift in the context of noncommutative quantum mechanics is studied using an exactly solvable model of 2D simple harmonic oscilator in Moyal plane, where momentum non-commutativity are also considered…

High Energy Physics - Theory · Physics 2020-09-02 Saptarshi Biswas , Partha Nandi , Biswajit Chakraborty

A nonlinear dynamics semi-classical model is used to show that standard quantum spin analysis can be obtained. The model includes a classically driven nonlinear differential equation with dissipation and a semi-classical interpretation of…

Quantum Physics · Physics 2018-11-08 Joshua J. Heiner , David R. Thayer

A first principles quantum formalism to describe the non-adiabatic dynamics of electrons and nuclei based on a second quantization representation (SQR) of the electronic motion combined with the usual representation of the nuclear…

Chemical Physics · Physics 2020-11-06 Sudip Sasmal , Oriol Vendrell

The combined quantum electron-nuclear dynamics is often associated with the Born-Huang expansion of the molecular wave function and the appearance of nonadiabatic effects as a perturbation. On the other hand, native multicomponent…

The nonadiabatic quantum kinetic equations and Dirac-Heisenberg-Wigner formalism for Schwinger pair production in a spatially uniform and time-varying electric field with multiple components are derived and proven to be equivalent. The…

High Energy Physics - Theory · Physics 2025-03-05 Z. L. Li , R. Z. Jiang , Y. J. Li

Quantum molecular dynamics requires an accurate representation of the molecular potential energy surface from a minimal number of electronic structure calculations, particularly for nonadiabatic dynamics where excited states are required.…

Chemical Physics · Physics 2016-08-24 Charles W. Heaps , David A. Mazziotti

Starting from a simple mapping of a generator of local stochastic dynamics to a quantum Hamiltonian, we derive a condition, which allows us to use the quasi-adiabatic evolution and so relate gapped quantum phases with non-equilibrium's.…

Quantum Physics · Physics 2015-12-10 Benoît Descamps , Frank Verstraete