Related papers: A Phase-Space Semiclassical Approach for Modeling …
A systematic perturbation scheme is developed for approximate solutions to the time-dependent Schroedinger equation with a space-adiabatic Hamiltonian. For a particular isolated energy band, the basic approach is to separate kinematics from…
Nonadiabatic coupling between electrons and molecular motion at metal surfaces leads to energy dissipation and dynamical steering effects during chemical surface dynamics. We present a theoretical approach to the scattering of molecules…
Quantum fluctuations driven by non-stoquastic Hamiltonians have been conjectured to be an important and perhaps essential missing ingredient for achieving a quantum advantage with adiabatic optimization. We introduce a transformation that…
In this letter we give a systematic derivation and justification of the semiclassical model for the slow degrees of freedom in adiabatic slow-fast systems first found by Littlejohn and Flynn [5]. The classical Hamiltonian obtains a…
Steering a quantum harmonic oscillator state along cyclic trajectories leads to a path-dependent geometric phase. Here we describe an experiment observing this geometric phase in an electronic harmonic oscillator. We use a superconducting…
We study a 2-qubit nuclear spin system for realizing an arbitrary geometric quantum phase gate by means of non-adiabatic operation. A single magnetic pulse with multi harmonic frequencies is applied to manipulate the quantum states of…
We present an efficient \textit{ab initio} algorithm for quantum dynamics simulations of interacting systems that is based on the conditional decomposition of the many-body wavefunction [Phys. Rev. Lett. 113, 083003 (2014)]. Starting with…
We address the development of geometric phases in classical and quantum magnetic moments (spin-1/2) precessing in an external magnetic field. We show that nonadiabatic dynamics lead to a topological phase transition determined by a change…
In this work, we study the counterdiabatic driving scheme in pseudo- and antipseudo- Hermitian systems. By discussing the adiabatic condition for non-Hermitian system, we show that the adiabatic evolution of state can only be realized in…
A semicalssical method based on surface-hopping techniques is developed to model the dynamics of radiative association with electronic transitions in arbitrary polyatomic systems. It can be proven that our method is an extension of the…
The time evolution of periodically driven non-Hermitian systems is in general non-unitary but can be stable. It is hence of considerable interest to examine the adiabatic following dynamics in periodically driven non-Hermitian systems. We…
We derive a formula of the nonadiabatic noncyclic Pancharatnam phase for a quantum spin-1/2 particle subject to an arbitrary magnetic field. The formula is applied to three specific kinds of magneic fields. (i) For an orientated magnetic…
We present a nonadiabatic classical-trajectory approach that offers the best of both worlds between fewest-switches surface hopping (FSSH) and quasiclassical mapping dynamics. This mapping approach to surface hopping (MASH) propagates the…
We study the dynamics of a two-level system described by a slowly varying Hamiltonian and weakly coupled to the Ohmic environment. We follow the Bloch--Redfield perturbative approach to include the effect of the environment on qubit…
We introduce a self-consistent framework for the analysis of both Abelian and non-Abelian geometric phases associated with open quantum systems, undergoing cyclic adiabatic evolution. We derive a general expression for geometric phases,…
The adiabatic motion of a charged, spinning, quantum particle in a two - dimensional magnetic field is studied. A suitable set of operators generalizing the cinematical momenta and the guiding center operators of a particle moving in a…
Rare nonadiabatic reactions are a key component of many important molecular processes but are challenging to capture with direct dynamical simulations. In this paper, we combine our recently developed mapping approach to surface hopping…
Nonadiabatic molecular dynamics is an effective method for modeling nonradiative decay in electronically excited molecules. Its accuracy depends strongly on the quality of the potential energy surfaces, and its affordability for long…
Quantum computation is an attractive front for many problems that are intractable for computers today. One such problem is nonadiabatic quantum molecular dynamics, where quantized internal states coupling to parameterized modes result in a…
The nonadiabatic geometric quantum computation may be achieved using coupled low-capacitance Josephson juctions. We show that the nonadiabtic effects as well as the adiabatic condition are very important for these systems. Moreover, we find…