Related papers: Deuterium fractionation as a multi-phase component…
The fractionation of nitrogen (N) in star-forming regions is a poorly understood process. To put more stringent observational constraints on the N-fractionation, we have observed with the IRAM-30m telescope a large sample of 66 cores in…
We present new models of the deuterium chemistry in protoplanetary disks, including, for the first time, multiply deuterated species. We use these models to explore whether observations in combination with models can give us clues as to…
Theory predicts, and observations confirm, that the column density ratio of a molecule containing D to its counterpart containing H can be used as an evolutionary tracer in the low-mass star formation process. Since it remains unclear if…
Although ammonia is an abundant molecule commonly observed towards the dense interstellar medium, it has not yet been established whether its main formation route is from gas-phase ion-molecule reactions or grain-surface hydrogen additions…
The abundance of deuterated molecules in a star-forming region is sensitive to the environment in which they are formed. Deuteration fractions therefore provide a powerful tool for studying the physical and chemical evolution of a…
It is an open question why the temperature of molecular gas in the Galactic center region is higher than that of dust. To address this problem, we made simultaneous observations in the NH_3 (J,K) = (1,1), (2,2), and (3,3) lines of the…
Deuterated molecules are a useful diagnostic tool to probe the evolution and the kinematics in the earliest stages of star formation. Due to the low temperatures and high densities in the centre of pre-stellar cores, the deuterium fraction…
The Central Molecular Zone (CMZ) is the largest reservoir of dense molecular gas in the Galaxy and is heavily obscured in the optical and near-IR. We present an overview of the far-IR dust continuum, where the molecular clouds are revealed,…
Using Far Ultraviolet Spectroscopic Explorer and Hubble Space Telescope observations of the QSO PG1259+593, we detect D I Lyman-series absorption in high velocity cloud Complex C, a low-metallicity gas cloud falling onto the Milky Way. This…
H2S is thought to be the main sulphur reservoir in the ice, being therefore a key molecule to understand sulphur chemistry in the star formation process and to solve the missing sulphur problem. The H2S deuterium fraction can be used to…
Molecular deuteration is commonly seen in starless cores and is expected to occur on a timescale comparable to that of the core contraction. Thus, the deuteration serves as a chemical clock, allowing us to investigate dynamical theories of…
Understanding water deuterium fractionation is important for constraining the mechanisms of water formation in interstellar clouds. Observations of HDO and H$_2^{18}$O transitions were carried out towards the high-mass star-forming region…
The Central Molecular Zone (CMZ) is the way station at the heart of our Milky Way Galaxy, connecting gas flowing in from Galactic scales with the central nucleus. Key open questions remain about its 3-D structure, star formation properties,…
Deuteration has been used as a tracer of the evolutionary phases of low- and high-mass star formation. The APEX Telescope Large Area Survey (ATLASGAL) provides an important repository for a detailed statistical study of massive star-forming…
The influence of turbulent mixing on the chemistry of the interstellar medium has so far received little attention. Previous studies of this effect have suggested that it might play an important role in mixing the various phases of the…
We present molecular line mapping of the Giant Molecular Cloud G1.6-0.025, which is located at the high longitude end of the Central Molecular Zone of our Galaxy. We assess the degree of star formation activity in that region using several…
The primordial abundance of deuterium (D/H) yields a measure of the density of baryons in the universe and is an important complement to determinations from cosmic microwave background (CMB) experiments. Indeed, the current small sample of…
We report the detection of D2CO in a sample of starless dense cores, in which we previously measured the degree of CO depletion. The deuterium fractionation is found extremely high, [D2CO]/[H2CO] ~ 1-10 %, similar to that reported in…
The 1.3deg (G1.3) and 1.6deg (G1.6) cloud complexes in the Central Molecular Zone (CMZ) of our Galaxy have been proposed to possibly reside at the intersection region of the X1 and X2 orbits for several reasons. This includes the detection…
An ever growing number of observational and theoretical evidence suggests that the deuterated fraction (column density ratio between a species containing D and its hydrogenated counterpart, Dfrac) is an evolutionary indicator both in the…