Related papers: Deuterium fractionation as a multi-phase component…
We use spectra and maps of the $J=1-0$ and $J=2-1$ DCO$^{+}$, DCN, DNC, $\rm N_2D^+$ lines and $1_{11}-1_{01}$ ortho- and para-NH$_{2}$D lines, obtained with the IRAM-30m telescope, as well as observations of their hydrogenated…
Clouds of high infrared extinction are promising sites of massive star/cluster formation. A large number of cloud cores discovered in recent years allows investigation of possible evolutionary sequence among cores in early phases. We have…
Deuterium fractionation is known to enhance the [DCO+]/[HCO+] abundance ratio over the D/H elemental ratio of about 1e-5 in the cold and dense gas typically found in pre-stellar cores. We report the first detection and mapping of very…
The chemical evolution in high-mass star-forming regions is still poorly constrained. Studying the evolution of deuterated molecules allows to differentiate between subsequent stages of high-mass star formation regions due to the strong…
Deuterium fractionation provides a window to the thermal history of volatiles in the solar system and protoplanetary disks. While evidence of active molecular deuteration has been observed towards a handful of disks, it remains unclear…
Star formation in the central molecular zone (CMZ) is suppressed with respect to that of the Galactic disk, and this is likely related to its high turbulent environment. This turbulence impedes the potential detection of prestellar cores.…
High levels of deuterium fractionation in gas-phase molecules are usually associated with cold regions, such as prestellar cores. Significant fractionation ratios are also observed in hot environments such as hot cores or hot corinos, where…
We investigate deuterium chemistry coupled with the nuclear spin-state chemistry of H$_2$ and H$_3^+$ in protoplanetary disks. Multiple paths of deuterium fractionation are found; exchange reactions with D atoms, such as HCO$^+$ + D, are…
We present the results of our studies of deuterated molecules (DCN, DNC, DCO$^+$, N$_2$D$^+$ and NH$_2$D) in regions of high-mass star formation, which include a survey of such regions with the 20-m Onsala radio telescope and mapping of…
The Central Molecular Zone (CMZ) at the center of our Galaxy is the best template to study star formation processes under extreme conditions, similar to those in high-redshift galaxies. We observed on-the-fly maps of para-H$_{2}$CO…
Deuterium fractionation is dependent on various physical and chemical parameters. Thus, the formation location and thermal history of material in the solar system is often studied by measuring its D/H ratio. This requires knowledge about…
We present the results of a single-pointing survey of 207 dense cores embedded in Planck Galactic Cold Clumps distributed in five different environments ($\lambda$ Orionis, Orion A, B, Galactic plane, and high latitudes) to identify dense…
Observations of low mass protostars which probe small enough size scales to be within likely CO depletion regions show the highest [NH2D]/[NH3] ratios yet measured, of 4--33%. These molecular D/H ratios are higher than those measured on…
In this work, we study deuterium fractionation in four starless cores in the low-mass star-forming region L1688 in the Ophiuchus molecular cloud. We study how the deuterium fraction ($R_D$) changes with environment, compare deuteration of…
Deuterium was primarily created during the Big Bang Nucleosynthesis (BBN). This fact, alongside its fractionation reactions resulting in enhanced abundances of deuterated molecules, means that these abundances can be used to better…
Using an absorption line from the metastable (J, K) = (3, 3) level of H3+ together with other lines of H3+ and CO observed along several sightlines, we have discovered a vast amount of high temperature (T ~ 250 K) and low density (n ~ 100…
We present sensitive observations of NH2D at 110.153599 GHz toward 50 Galactic massive star-forming regions with IRAM 30-m telescope. The NH2D transition is detected toward 36 objects, yielding a detection rate of 72%. Column densities of…
The physical and chemical properties of cold and dense molecular clouds are key to understanding how stars form. Using the IRAM 30 m and NRO 45 m telescopes, we carried out a Multiwavelength line-Imaging survey of the 70 $\mu$m dark and…
The distributions of deuterated molecules in protoplanetary disks are expected to depend on the molecular formation pathways. We use observations of spatially resolved DCN emission from the disk around TW Hya, acquired during ALMA Science…
Deuterium fractionation in molecular ions, in particular HCO+, has been extensively used to estimate the degree of ionization in molecular clouds. This paper reviews recent work on ionization degree in homogeneous clouds. We will show that…