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A linear-scaling algorithm is presented for computing the Hartree-Fock (HF) exchange matrix using concentric atomic density fitting. The algorithm utilizes the stronger distance dependence of the three-center electron repulsion integrals…

Chemical Physics · Physics 2014-10-21 David S. Hollman , Henry F. Schaefer , Edward F. Valeev

We present the first set of results of solving the Hartree-Fock-Bogoliubov equations, which describe the self-consistent mean field theory with pairing interaction. Calculations for even-even nuclei are carried out on a two-dimensional…

Nuclear Theory · Physics 2007-05-23 E. Teran , V. E. Oberacker , A. S. Umar

In the framework of geometric quantization we extend the Bohr-Sommerfeld rules to a full quantization theory which resembles Heisenberg's matrix theory. This extension is possible because Bohr-Sommerfeld rules not only provide an orthogonal…

Symplectic Geometry · Mathematics 2012-07-06 Richard Cushman , Jedrzej Sniatycki

The evaluation of exact (Hartree--Fock, HF) exchange operator is a crucial ingredient for the accurate description of electronic structure in periodic systems through ab initio and hybrid density functional approaches. An efficient…

Chemical Physics · Physics 2020-10-28 Xiao Wang , Cannada A. Lewis , Edward F. Valeev

A translationally invariant formulation of the Hartree-Fock (HF) $\Gamma$-point approximation is presented. This formulation is achieved through introduction of the Minimum Image Convention (MIC) at the level of primitive two-electron…

Materials Science · Physics 2016-08-16 C. J. Tymczak , Valéry T. Weber , Eric Schwegler , Matt Challacombe

Factorization of quantum mechanical Hamiltonians has been a useful technique for some time. This procedure has been given an elegant description by supersymmetric quantum mechanics, and the subject has become well-developed. We demonstrate…

Quantum Physics · Physics 2010-11-09 Micheal S. Berger , Nail S. Ussembayev

The Born-Oppenheimer approximation is widely used to investigate the properties of hydrogen-like systems and doubly heavy hadrons. However, the extent to which this approximation captures the features of such systems within potential models…

High Energy Physics - Phenomenology · Physics 2026-04-16 Zi-Long Man , Hao Zhou , Si-Qiang Luo , Xiang Liu

We explore the possibility to implement random walks in the manifold of Hartree-Fock-Bogoliubov wave functions. The goal is to extend state-of-the-art quantum Monte Carlo approaches, in particular the constrained-path auxiliary-field…

Strongly Correlated Electrons · Physics 2024-09-19 Ettore Vitali , Peter Rosenberg , Shiwei Zhang

Certain integrable hierarchies appearing in random matrix theory, enumerative geometry, and conformal field theory are governed by Virasoro/$W$-algebra constraints and their $W$-representations.Motivated by the Gaussian Hermitian…

Mathematical Physics · Physics 2026-02-05 Lu-Yao Wang

In phase space, we analytically obtain the characteristic functions (CFs) of a forced harmonic oscillator [Talkner et al., Phys. Rev. E, 75, 050102 (2007)], a time-dependent mass and frequency harmonic oscillator [Deffner and Lutz, Phys.…

Statistical Mechanics · Physics 2019-12-25 Yixiao Qian , Fei Liu

Using normalized Hermite functions, we construct bases in the space of square integrable functions on the unit circle ($L^2(\mathcal C)$) and in $l_2(\mathbb Z)$, which are related to each other by means of the Fourier transform and the…

Mathematical Physics · Physics 2021-05-14 Enrico Celeghini , Manuel Gadella , Mariano. A. del Olmo

A mapping technique is used to derive in the context of constituent quark models effective Hamiltonians that involve explicit hadron degrees of freedom. The technique is based on the ideas of mapping between physical and ideal Fock spaces…

High Energy Physics - Phenomenology · Physics 2009-10-31 D. Hadjimichef , G. Krein , S. Szpigel , J. S. da Veiga

Traditional multiconfiguration Hartree-Fock (MCHF) and configuration interaction (CI) methods are based on a single orthonormal orbital basis (OB). For atoms with complicated shell structures, a large OB is needed to saturate all the…

Atomic Physics · Physics 2015-06-12 S. Verdebout , P. Rynkun , P. Jönsson , G. Gaigalas , C. Froese Fischer , M. Godefroid

In this paper we introduce and study several new Hilbert-type operators acting between the weighted Fock spaces. We provide some sufficient and necessary conditions for the boundedness and compactness of certain Hilbert-type operators from…

Functional Analysis · Mathematics 2022-10-04 Jianjun Jin , Shuan Tang , Xiaogao Feng

Classically the Harmonic Oscillator (HO) is the generic example for the use of angle and action variables phi in R mod 2 pi and I > 0. But the symplectic transformation (\phi,I) to (q,p) is singular for (q,p) = (0,0). Globally {(q,p)} has…

Quantum Physics · Physics 2008-11-26 H. A. Kastrup

We study the relationships among the various forms of the $q$ oscillator algebra and consider the conditions under which it supports a Hopf structure. We also present a generalization of this algebra together with its corresponding Hopf…

High Energy Physics - Theory · Physics 2009-10-28 C. H. Oh , K. Singh

Beyond mean-field methods are very successful tools for the description of large-amplitude collective motion for even-even atomic nuclei. The state-of-the-art framework of these methods consists in a Generator Coordinate Method based on…

Nuclear Theory · Physics 2014-10-22 B. Bally , B. Avez , M. Bender , P. -H. Heenen

We introduce a canonical operator-theoretic construction associated to a finite geometric lattice, in which a simple nonassociative ``diamond product'' on the lattice basis gives rise to a family of creation operators indexed by atoms and a…

Combinatorics · Mathematics 2026-04-13 Thomas Sinclair

We present the implementation of a variational finite element solver in the HelFEM program for benchmark calculations on diatomic systems. A basis set of the form $\chi_{nlm}(\mu,\nu,\phi)=B_{n}(\mu)Y_{l}^{m}(\nu,\phi)$ is used, where…

Chemical Physics · Physics 2019-08-19 Susi Lehtola

Recent results in quantitative homogenisation of the wave equation with rapidly oscillating coefficients are discussed from the operator-theoretic perspective, which views the solution as the result of applying the operator of hyperbolic…

Analysis of PDEs · Mathematics 2025-04-03 Kirill Cherednichenko , Yi-Sheng Lim