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We introduce highly local basis sets for electronic structure which are very efficient for correlation calculations near the complete basis set limit. Our approach is based on gausslets, recently introduced wavelet-like smooth orthogonal…

Chemical Physics · Physics 2019-02-20 Steven R. White , E. Miles Stoudenmire

In this paper we use techniques in Fock spaces theory and compute how the Segal-Bargmann transform acts on special wave functions obtained by multiplying superoscillating sequences with normalized Hermite functions. It turns out that these…

Mathematical Physics · Physics 2023-04-25 Daniel Alpay , Fabrizio Colombo , Kamal Diki , Irene Sabadini , Daniele C. Struppa

A systematic study of 160 heavy and super-heavy nuclei is performed in the Hartree-Fock-Bogoliubov approach with the finite range and density dependent Gogny force with the D1S parameter set. We show calculations in several approximations:…

Nuclear Theory · Physics 2015-06-04 M. Warda , J. L. Egido

In this paper it is investigated how to find a matrix representation of operators on a Hilbert space with Bessel sequences, frames and Riesz bases. In many applications these sequences are often preferable to orthonormal bases (ONBs).…

Functional Analysis · Mathematics 2008-04-09 Peter Balazs

In this paper, we analyze the iteration-complexity of Generalized Forward--Backward (GFB) splitting algorithm, as proposed in \cite{gfb2011}, for minimizing a large class of composite objectives $f + \sum_{i=1}^n h_i$ on a Hilbert space,…

Optimization and Control · Mathematics 2014-02-11 Jingwei Liang , Jalal M. Fadili , Gabriel Peyré

The series expansion formulae are established for the one- and two-center charge densities over complete orthonormal sets of exponential type orbitals introduced by the author. Three-center overlap integrals of appearing in these relations…

Chemical Physics · Physics 2009-02-04 I. I. Guseinov

Analytical Hartree-Fock gradients with respect to the cell parameter have been implemented in the electronic structure code CRYSTAL, for the case of one and two-dimensional periodicity. As in most molecular codes, Gaussian type orbitals are…

Computational Physics · Physics 2007-05-23 K. Doll , R. Dovesi , R. Orlando

The equilibrium properties of an open harmonic oscillator are considered in three steps: First the creation and destruction operators are generalized for open dynamics and the creation operator is used to construct coherent states. The…

Quantum Physics · Physics 2020-06-24 Janos Polonyi

We analyze perturbations of the harmonic oscillator type operators in a Hilbert space H, i.e. of the self-adjoint operator with simple positive eigenvalues $\mu_k$ satisfying $\mu_{k+1}-\mu_k \geq \Delta >0$. Perturbations are considered in…

Spectral Theory · Mathematics 2023-08-24 Boris Mityagin , Petr Siegl

We explore the computation of high-harmonic generation spectra by means of Gaussian basis sets in approaches propagating the time-dependent Schr{\"o}dinger equation. We investigate the efficiency of Gaussian functions specifically designed…

The wave functions of a quantum isotropic harmonic oscillator in N-space modified by barriers at the coordinate hyperplanes can be expressed in terms of certain generalized spherical harmonics. These are associated with a product-type…

Classical Analysis and ODEs · Mathematics 2009-11-07 Charles F. Dunkl

The variational inclusion of spin-orbit coupling in self-consistent field (SCF) calculations requires a generalised two-component framework, which permits the single-determinant wave function to completely break spin symmetry. The…

Chemical Physics · Physics 2023-03-29 Shadan Ghassemi Tabrizi , R. Rodríguez-Guzmán , Carlos A. Jiménez-Hoyos

In this note we present a notion of harmonic oscillator on the Heisenberg group $\mathbf{H}_n$ which forms the natural analogue of the harmonic oscillator on $\mathbb{R}^n$ under a few reasonable assumptions: the harmonic oscillator on…

Analysis of PDEs · Mathematics 2020-05-26 David Rottensteiner , Michael Ruzhansky

The general tensorial form of the orbit-orbit interaction operator in the formalism of second quantization is presented. Such an expression is needed to calculate both diagonal and off-diagonal matrix elements with respect to…

Atomic Physics · Physics 2007-05-23 G. Gaigalas

A recent characterisation of Fock-adapted contraction operator stochastic cocycles on a Hilbert space, in terms of their associated semigroups, yields a general principle for the construction of such cocycles by approximation of their…

Functional Analysis · Mathematics 2007-05-23 J. Martin Lindsay , Stephen J. Wills

Energy level statistics of Hermitian random matrices $\hat H$ with Gaussian independent random entries $H_{i\geq j}$ is studied for a generic ensemble of almost diagonal random matrices with $ <|H_{ii}|^{2} > \sim 1$ and $<|H_{i\neq j}|^{2}…

Disordered Systems and Neural Networks · Physics 2016-08-31 Oleg Yevtushenko , Vladimir Kravtsov

We formulate a Hartree-Fock-LAPW method for electronic band structure calculations. The method is based on the Hartree-Fock-Roothaan approach for solids with extended electron states and closed core shells where the basis functions of…

Materials Science · Physics 2016-08-31 A. V. Nikolaev , P. N. Dyachkov

Given a critical quantum spin chain described by a conformal field theory (CFT) at long distances, it is crucial to understand the universal conformal data. One most important ingredient is the operator product expansion (OPE) coefficients,…

Strongly Correlated Electrons · Physics 2023-04-26 Yuhan Liu , Yijian Zou , Shinsei Ryu

Recently isotropic basis functions of $N$ unit vector arguments were presented; these are of significant use in measuring the N-Point Correlation Functions (NPCFs) of galaxy clustering. Here we develop the generating function for these…

Instrumentation and Methods for Astrophysics · Physics 2024-11-20 Zachary Slepian , Jessica Chellino , Jiamin Hou

The Generator Coordinate Method (GCM) in the Gaussian Overlap Approximation (GOA) is applied to a description of the nuclear quadrupole collective states. The full five-dimensional quadrupole tensor is used as a set of the generator…

Nuclear Theory · Physics 2015-06-04 Stanisław G. Rohoziński
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