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The properties of amorphous solid water at and near the calorimetric glass transition temperature, $T_{g}$, of 136 K have been debated for years. One hypothesis is that water turns into a "true" liquid at $T_{g}$ (i.e., it becomes ergodic)…

Soft Condensed Matter · Physics 2025-03-03 Greg A. Kimmel , Megan K. Dunlap , Kirill Gurdumov , R. Scott Smith , Loni Kringle , Bruce D. Kay

By confining water in nanopores, so narrow that the liquid cannot freeze, it is possible to explore its properties well below its homogeneous nucleation temperature TH ~ 235 K. In particular, the dynamical parameters of water can be…

Soft Condensed Matter · Physics 2007-05-23 Sow-Hsin Chen , Francesco Mallamace , Chung-Yuan Mou , Matteo Broccio , Carmelo Corsaro , Antonio Faraone , Li Liu

For a deeply supercooled liquid just above its glass transition temperature, we present a simple thermodynamic model, where the deeply supercooled liquid is assumed to be a mixture of solid-like and liquid-like micro regions. The mole…

Statistical Mechanics · Physics 2012-10-17 Hiroshi Matsuoka

Monte Carlo simulations within the grand canonical ensemble are used to obtain the joint distribution of density and energy fluctuations $p_L(\rho,u)$ for two model fluids: a decorated lattice gas and a polymer system. In the near critical…

Condensed Matter · Physics 2009-10-22 Nigel B. Wilding , Marcus Mueller

A few years ago it was showed that some systems that have very similar local structure, as quantified by the pair correlation function, exhibit vastly different slowing down upon supercooling [L. Berthier and G. Tarjus, Phys. Rev. Lett.…

Soft Condensed Matter · Physics 2015-06-17 Elijah Flenner , Hannah Staley , Grzegorz Szamel

The vapor-liquid critical behavior of intrinsically asymmetric fluids is studied in finite systems of linear dimensions, $L$, focusing on periodic boundary conditions, as appropriate for simulations. The recently propounded ``complete''…

Statistical Mechanics · Physics 2009-11-10 Young C. Kim , Michael E. Fisher

Recent cutting-edge experiments have provided {\it in situ} structure characterization and measurements of the pressure ($P$), density ($\bar{\rho}$) and temperature ($T$) of shock compressed silicon in the 100 GPa range of pressures and…

Materials Science · Physics 2024-12-12 M. W. C. Dharma-wardana , Dennis D. Klug , Hannah Poole , G. Gregori

Many successful theories of liquids near the melting temperature assume that small length scale density fluctuations follow Gaussian statistics. In this paper I present numerical investigations of fluctuations in the supercooled viscous…

Statistical Mechanics · Physics 2019-03-07 Ulf R. Pedersen

Small angle neutron scattering (SANS) is used to measure the density of heavy water contained in 1-D cylindrical pores of mesoporous silica material MCM-41-S-15, with pores of diameter of 15+-1 A. In these pores the homogenous nucleation…

Soft Condensed Matter · Physics 2009-11-13 Dazhi Liu , Yang Zhang , Chia-Cheng Chen , Chung-Yuan Mou , Peter H Poole , Sow-Hsin Chen

We study the exciton gas-liquid transition in GaAs/AlGaAs coupled quantum wells. Below a critical temperature, Tc=4.8K, and above a threshold laser power density the system undergoes a phase transition into a liquid state. We determine the…

Mesoscale and Nanoscale Physics · Physics 2018-02-14 Subhradeep Misra , Michael Stern , Arjun Joshua , Vladimir Umansky , Israel Bar-Joseph

Water can be vitrified if it is cooled at rates exceeding $3*10^5$ K/s. This makes it possible to outrun crystallization in so-called no man's land, a range of deeply supercooled temperatures where water crystallizes rapidly. One would…

The relation between liquid-liquid phase transitions and waterlike density anomalies in core-softened potentials of fluids was investigated in an exactly solvable one dimensional lattice model and a in a three dimensional fluid with…

Soft Condensed Matter · Physics 2015-03-11 Marco Aurélio A. Barbosa , Evy Salcedo , Marcia Barbosa

The density fluctuations of quantum vortex lines are measured in a turbulent flow of superfluid He, at temperatures corresponding to superfluid fraction of 16%, 47% and 81%. The probe is a micro-fabricated second sound resonator that allows…

Fluid Dynamics · Physics 2021-08-11 Eric Woillez , Jérôme Valentin , Philippe-E Roche

A phenomenological criterion for the superfluid transition is proposed, which is similar to the Lindemann criterion for the crystal melting. Then we derive a new formula for the critical temperature, relating $T_{\lambda}$ to the mean…

Statistical Mechanics · Physics 2009-10-31 Sergey M. Apenko

Thermal stability of hydrogenated amorphous Si/Ge multilayers has been investigated by Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and Small-Angle X-Ray Diffraction (SAXRD) techniques. Amorphous H-Si/Ge…

Materials Science · Physics 2009-02-11 A. Csik , M. Serenyi , Z. Erdelyi , A. Nemcsics , C. Cserhati , G. A. Langer , D. L. Beke , C. Frigeri , A. Simon

Using experiments and theory, we show that light scattering by inhomogeneities in the index of refraction of a fluid can drive a large-scale flow. The experiment uses a near-critical, phase-separated liquid, which experiences large…

An undercooled liquid is unstable. The driving force of the glass transition at Tg is a change of the undercooled-liquid Gibbs free energy. The classical Gibbs free energy change for a crystal formation is completed including an enthalpy…

Disordered Systems and Neural Networks · Physics 2015-06-19 Robert Felix Tournier

One of water's unsolved puzzles is the question of what determines the lowest temperature to which it can be cooled before freezing to ice. The supercooled liquid has been probed experimentally to near the homogeneous nucleation temperature…

Soft Condensed Matter · Physics 2011-12-08 Emily B. Moore , Valeria Molinero

The thermodynamic behavior of a fluid near a vapor-liquid and, hence, asymmetric critical point is discussed within a general ``complete'' scaling theory incorporating pressure mixing in the nonlinear scaling fields as well as corrections…

Statistical Mechanics · Physics 2009-11-07 Young C. Kim , Michael E. Fisher , G. Orkoulas

In this experiment liquid water is subject to an inhomogeneous electric field (${\nabla}^2 E_a {\approx} 10^{10} \frac{V}{m^2}$ ) using a high voltage (20 kV) point-plane electrode system. With interferometry it was found that the…

Mesoscale and Nanoscale Physics · Physics 2016-06-29 Adam D. Wexler , Sandra Drusová , Jakob Woisetschläger , Elmar C. Fuchs
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