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The hyperpolarisation of nuclear spins within target molecules is a critical and complex challenge in magnetic resonance imaging (MRI) and nuclear magnetic resonance (NMR) spectroscopy. Hyperpolarisation offers enormous gains in signal and…

We report a versatile method to efficiently polarize single nuclear spins in diamond, which is based on optical pumping of a single NV color center and mediated by a level-anti crossing in its excited state. A nuclear spin polarization…

Nuclear electric resonance (NER) is based on nuclear magnetic resonance mediated by spatial oscillations of electron spin domains excited by a radio frequency (RF) electric field, and it allows us to investigate the spatial distribution of…

Mesoscale and Nanoscale Physics · Physics 2012-10-25 S. Watanabe , G. Igarashi , N. Kumada , Y. Hirayama

We polarize nuclear spins in a GaAs double quantum dot by controlling two-electron spin states near the anti-crossing of the singlet (S) and m_S=+1 triplet (T+) using pulsed gates. An initialized S state is cyclically brought into resonance…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 J. R. Petta , J. M. Taylor , A. C. Johnson , A. Yacoby , M. D. Lukin , C. M. Marcus , M. P. Hanson , A. C. Gossard

We study a mechanism by which nuclear hyperpolarization due to the polarization transfer from a microwave-pulse-controlled electron spin is suppressed. From analytical and numerical calculations of the unitary dynamics of multiple nuclear…

Quantum Physics · Physics 2024-03-12 Kento Sasaki , Eisuke Abe

Direct dynamic nuclear polarization of 1H nuclei in frozen water and water-ethanol mixtures is demonstrated using silicon nanoparticles as the polarizing agent. Electron spins at dangling-bond sites near the silicon surface are identified…

Mesoscale and Nanoscale Physics · Physics 2014-01-14 M. C. Cassidy , C. Ramanathan , D. G. Cory , J. W. Ager , C. M. Marcus

It is demonstrated that the time evolution of the electron-nuclear polarization transfer process during pulsed dynamic nuclear polarization (DNP) can be reversed on a microsecond timescale, leading to the observation of DNP echoes. The DNP…

Chemical Physics · Physics 2024-06-28 Nino Wili , Anders B. Nielsen , José P. Carvalho , Niels Chr. Nielsen

The magnetic interactions between the spin of an unpaired electron and the surrounding nuclear spins can be exploited to gain structural information, to reduce nuclear relaxation times as well as to create nuclear hyperpolarization via…

The SpinQuest experiment at Fermilab employs a dynamically polarized solid ammonia target to probe the spin structure of the proton, requiring stable, optimized microwave-driven Dynamic Nuclear Polarization (DNP) under high radiation…

Instrumentation and Detectors · Physics 2026-04-28 Vibodha Bandara , Jordan D. Roberts , Dustin Keller

Repeated injection of spin polarized carriers in a quantum dot leads to the polarization of nuclear spins, a process known as dynamic nuclear spin polarization (DNP). Here, we report the first observation of p-shell carrier assisted DNP in…

Mesoscale and Nanoscale Physics · Physics 2016-03-23 C. F. Fong , Y. Ota , E. Harbord , S. Iwamoto , Y. Arakawa

Dynamic nuclear polarization enables the hyperpolarization of nuclear spins beyond the thermal-equilibrium Boltzmann distribution. However, it is often unclear why the experimentally measured hyperpolarization is below the theoretical…

Chemical Physics · Physics 2023-12-13 Gevin von Witte , Aaron Himmler , Sebastian Kozerke , Matthias Ernst

Dissolution Dynamic Nuclear Polarisation (dDNP) increases the sensitivity of magnetic resonance experiments by $>10^4$-fold, permitting isotopically-labelled molecules to be transiently visible in MRI scans. dDNP requires a source of…

Dynamic nuclear polarization (DNP) enhances the intensity of NMR signals by transferring polarization from electron spins to nuclei via microwave irradiation. Pulsed DNP methods offer more control on the spin dynamics than conventional…

Chemical Physics · Physics 2026-01-07 Lorenzo Niccoli , Gian-Marco Camenisch , Matías Chávez , Matthias Ernst

Color-center-hosting semiconductors are emerging as promising source materials for low-field dynamic nuclear polarization (DNP) at or near room temperature, but hyperfine broadening, susceptibility to magnetic field heterogeneity, and…

Quantum Physics · Physics 2022-06-01 J. Henshaw , D. Pagliero , P. R. Zangara , B. Franzoni , A. Ajoy , R. Acosta , J. A. Reimer , A. Pines , C. A. Meriles

Dynamic nuclear polarization via contact with electronic spins has emerged as an attractive route to enhance the sensitivity of nuclear magnetic resonance (NMR) beyond the traditional limits imposed by magnetic field strength and…

We introduce an alternate route to dynamically polarize the nuclear spin host of nitrogen-vacancy (NV) centers in diamond. Our approach articulates optical, microwave and radio-frequency pulses to recursively transfer spin polarization from…

Quantum Physics · Physics 2014-12-18 Daniela Pagliero , Abdelghani Laraoui , Jacob D. Henshaw , Carlos A. Meriles

The control of nuclear spins in quantum dots is essential to explore their many-body dynamics and exploit their prospects for quantum information processing. We present a unique combination of dynamic nuclear spin polarization and…

Mesoscale and Nanoscale Physics · Physics 2015-12-16 Florian Forster , Max Mühlbacher , Dieter Schuh , Werner Wegscheider , Geza Giedke , Stefan Ludwig

The dynamics of the coupled electron-nuclear spin system is studied in an ensemble of singly-charged (In,Ga)As/GaAs quantum dots (QDs) using periodic optical excitation at 1 GHz repetition rate. In combination with the electron-nuclei…

Mesoscale and Nanoscale Physics · Physics 2021-08-11 E. Evers , N. E. Kopteva , I. A. Yugova , D. R. Yakovlev , M. Bayer , A. Greilich

Spontaneous nuclear polarization is predicted in double quantum dots in the spin-blocked electron transport regime. The polarization results from an instability of the zero-polarization state when singlet and triplet electron energy levels…

Mesoscale and Nanoscale Physics · Physics 2010-08-23 M. S. Rudner , L. S. Levitov

Low thermal polarization of nuclear spins is a primary sensitivity limitation for nuclear magnetic resonance. Here we demonstrate optically pumped (microwave-free) nuclear spin polarization of $^{13}\mathrm{C}$ and $^{15}\mathrm{N}$ in…

Mesoscale and Nanoscale Physics · Physics 2017-08-09 Ben L. Green , Ben G. Breeze , Gregory J. Rees , John V. Hanna , Jyh-Pin Chou , Viktor Ivády , Adam Gali , Mark E. Newton