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Dynamic Nuclear Polarization (DNP) is to date the most effective technique to increase the nuclear polarization up to a factor $100,000$ opening disruptive perspectives for medical applications. In DNP, the nuclear spins are driven to an -…

Strongly Correlated Electrons · Physics 2015-08-26 Andrea De Luca , Alberto Rosso

Dynamic nuclear polarisation (DNP) refers to a class of techniques used to increase the signal in nuclear magnetic resonance measurements by transferring spin polarisation from ensembles of highly polarised electrons to target nuclear…

Quantum Physics · Physics 2020-12-24 L. T. Hall , D. A. Broadway , A. Stacey , D. A. Simpson , J-P. Tetienne , L. C. L. Hollenberg

Dynamic nuclear polarization (DNP) is a promising strategy for generating a significantly increased non-thermal spin polarization in nuclear magnetic resonance (NMR) applications thereby circumventing the need for strong magnetic fields.…

Quantum Physics · Physics 2015-07-15 Alexander Karabanov , Daniel Wisniewski , Igor Lesanovsky , Walter Köckenberger

Dynamic nuclear polarization (DNP) is an out-of-equilibrium method for generating non-thermal spin polarization which provides large signal enhancements in modern diagnostic methods based on nuclear magnetic resonance. A particular instance…

Dynamic nuclear polarization (DNP) is an attractive method for initializing nuclear spins that are strongly coupled to optically active electron spins because it functions at room temperature and does not require strong magnetic fields. In…

Dynamic nuclear polarization transfers spin polarization from electrons to nuclei. We have achieved this by a new method, simultaneously exciting transitions of electronic and nuclear spins. The efficiency of this technique improves with…

Quantum Physics · Physics 2008-09-11 G. W. Morley , K. Porfyrakis , A. Ardavan , J. van Tol

We study the role of dipolar interactions in the standard protocol used to achieve dynamic nuclear polarization (DNP). In the so-called spin-temperature regime, where the interactions establish an effective thermodynamic behavior in the…

Strongly Correlated Electrons · Physics 2016-07-13 Andrea De Luca , Inés Rodríguez Arias , Markus Müller , Alberto Rosso

We report achieving enhanced nuclear magnetization in a magnetic resonance force microscope experiment at 0.6 tesla and 4.2 kelvin using the dynamic nuclear polarization (DNP) effect. In our experiments a microwire coplanar waveguide…

Dynamic nuclear polarization (DNP) is used in nuclear magnetic resonance (NMR) to transfer polarization from electron spins to nuclear spins. The resulting nuclear polarization enhancement can, in theory, be two or three orders of magnitude…

Quantum Physics · Physics 2015-10-14 Sarah Sheldon , David G. Cory

Dynamical nuclear polarisation (DNP) is an important technique that uses polarisation transfer from electron to nuclear spins to achieve nuclear hyperpolarisation. As the electron spin of the nitrogen vacancy (NV) centres in diamond can be…

Coupled electron-nuclear spins represent a promising quantum system, where the optically induced electron spin polarization can be dynamically transferred to nuclear spins via the hyperfine interaction. Most experiments on dynamic nuclear…

Materials Science · Physics 2026-01-13 A. N. Anisimov , A. V. Poshakinskiy , G. V. Astakhov

In pulsed dynamic nuclear polarization (DNP), enhancement of the polarization of bulk nuclei requires the repeated application of a microwave pulse sequence. So far, analysis of a one-time transfer of electron spin polarization to a…

Chemical Physics · Physics 2025-07-24 Shebha Anandhi Jegadeesan , Yujie Zhao , Graham M. Smith , Ilya Kuprov , Guinevere Mathies

We have explored the manifold physical scenario emerging from a model of Dynamic Nuclear Polarization (DNP) via thermal mixing under the hypothesis of highly effective electron-electron interaction. When the electron and nuclear reservoirs…

Statistical Mechanics · Physics 2017-09-13 Sonia Colombo Serra , Alberto Rosso , Fabio Tedoldi

In dynamic nuclear polarization (DNP) experiments, the compound is driven out-of-equilibrium by microwave (MW) irradiation of the radical electron spins. Their stationary state has been recently probed via electron double resonance (ELDOR)…

Strongly Correlated Electrons · Physics 2017-02-28 Filippo Caracciolo , Marta Filibian , Pietro Carretta , Alberto Rosso , Andrea De Luca

There has been much renewed interest in dynamic nuclear polarization (DNP), particularly in the context of solid state biomolecular NMR and more recently dissolution DNP techniques for liquids. This paper reviews the role of spin diffusion…

Other Condensed Matter · Physics 2009-04-01 Chandrasekhar Ramanathan

Highly sensitive nuclear spin detection is crucial in many scientific areas including nuclear magnetic resonance spectroscopy (NMR), imaging (MRI) and quantum computing. The tiny thermal nuclear spin polarization represents a major obstacle…

Polarization transfers are crucial building blocks in magnetic resonance experiments, i.e., they can be used to polarize insensitive nuclei and correlate nuclear spins in multidimensional NMR spectroscopy. The polarization can be…

Chemical Physics · Physics 2022-08-24 Zhenfeng Pang , Sheetal Jain , Chen Yang , Xueqian Kong , Kong Ooi Tan

Dynamic nuclear polarization (DNP) is an important method to enhance the limited sensitivity of nuclear magnetic resonance (NMR). Using the existing mechanisms such as Overhauser DNP (ODNP) is still difficult to achieve significant…

Chemical Physics · Physics 2025-03-31 Maria Grazia Concilio , Yiwen Wang , Linjun Wang , Xueqian Kong

We propose a new, more efficient, and potentially cost effective, solid-state nuclear spin hyperpolarization method combining the Cross Effect mechanism and electron spin optical hyperpolarization in rotating solids. We first demonstrate…

Quantum Physics · Physics 2022-01-25 Frederic Mentink-Vigier , Vinayak Rane , Thierry Dubroca , Krishnendu Kundu

Dynamic nuclear polarization (DNP) of molecules in a solution at room temperature has potential to revolutionize nuclear magnetic resonance spectroscopy and imaging. The prevalent methods for achieving DNP in solutions are typically most…

Chemical Physics · Physics 2016-03-02 Qiong Chen , Ilai Schwarz , Fedor Jelezko , Alex Retzker , Martin B Plenio
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