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Recent years have seen significant developments in the study of strong light-matter coupling including the control of chemical reactions by altering the vibrational normal modes of molecules. In the vibrational strong coupling regime the…

Quantum Physics · Physics 2021-08-27 John Bonini , Johannes Flick

The prototypical system constituted by a two-level atom interacting with a quantized single-mode electromagnetic field is described by the quantum Rabi model (QRM). The QRM is potentially valid at any light-matter interaction regime,…

We describe a qualitatively new regime of cavity quantum electrodynamics, the super strong coupling regime. This regime is characterized by atom-field coupling strengths of the order of the free spectral range of the cavity, resulting in a…

Quantum Physics · Physics 2009-11-13 D. Meiser , P. Meystre

Strong and ultra-strong light-matter coupling are remarkable phenomena of quantum electrodynamics occurring when the interaction between a matter excitation and the electromagnetic field cannot be described by usual perturbation theory.…

Quantum Physics · Physics 2016-10-19 Simon Huppert , Angela Vasanelli , Giulia Pegolotti , Yanko Todorov , Carlo Sirtori

Traditionally, strong-field physics explores phenomena in matter (atoms, molecules, and solids) driven by an extremely strong laser field nonperturbatively. However, even in the complete absence of an external electromagnetic field,…

Mesoscale and Nanoscale Physics · Physics 2019-03-15 Motoaki Bamba , Xinwei Li , Junichiro Kono

A major trend within the field of cavity QED is to boost the interaction strength between the cavity field and the atomic internal degrees of freedom of the trapped atom by decreasing the mode volume of the cavity. In such systems, it is…

Quantum Physics · Physics 2018-08-29 Lukas Neumeier , Darrick E. Chang

We present an efficient perturbative method to obtain both static and dynamic polarizabilities and hyperpolarizabilities of complex electronic systems. This approach is based on the solution of a frequency dependent Sternheimer equation,…

Materials Science · Physics 2009-11-13 Xavier Andrade , Silvana Botti , Miguel A. L. Marques , Angel Rubio

Quantum-matter theory (QMT), based on the Schr\"odinger or Dirac equations, is firmly established for both intra- and intermolecular interactions. However, there are two key issues with QMT. First, its applicability to large molecular…

Chemical Physics · Physics 2026-03-19 Reza Karimpour , Matteo Gori , Alexandre Tkatchenko

The ability to achieve ultra-strong coupling between light and matter promises to bring about new means to control material properties, new concepts for manipulating light at the atomic scale, and fundamentally new insights into quantum…

Quantum Physics · Physics 2019-05-22 Nicholas Rivera , Johannes Flick , Prineha Narang

The Born--Oppenheimer approximation is the standard tool for the study of molecular systems. It is founded on the observation that the energy scale of the electron dynamics in a molecule is larger than that of the nuclei. A very similar…

High Energy Physics - Phenomenology · Physics 2018-01-31 Nora Brambilla , Gastão Krein , Jaume Tarrús Castellà , Antonio Vairo

Intense light-matter interaction largely relies on the use of high-power light sources, creating fields comparable to, or even stronger than, the field keeping the electrons bound in atoms. Under such conditions, the interaction induces…

Quantum Physics · Physics 2025-10-23 P. Stammer , J. Rivera-Dean , P. Tzallas , M. F. Ciappina , M. Lewenstein

Dynamically probing systems of ultrastrongly coupled light and matter by advanced coherent control has been recently proposed as a unique tool for detecting peculiar quantum features of this regime. Coherence allows in principle on-demand…

Quantum Physics · Physics 2021-05-26 A. Ridolfo , J. Rajendran , L. Giannelli , E. Paladino , G. Falci

The rapidly developing and converging fields of polaritonic chemistry and quantum optics necessitate a unified approach to predict strongly-correlated light-matter interactions with atomic-scale resolution. Combining concepts from both…

Quantum Physics · Physics 2018-09-19 Johannes Flick , Prineha Narang

We demonstrate for the first time that a functional-renormalization-group aided density-functional theory (FRG-DFT) describes well the characteristic features of the excited states as well as the ground state of an interacting many-body…

Nuclear Theory · Physics 2019-03-08 Takeru Yokota , Kenichi Yoshida , Teiji Kunihiro

This article reviews theoretical methods developed in the last decade to understand cavity quantum electrodynamics in the ultrastrong-coupling regime, where the strength of the light-matter interaction becomes comparable to the photon…

Quantum Physics · Physics 2020-06-05 Alexandre Le Boité

Multimode cavity-QED systems can be leveraged to explore a wide range of physical phenomena; however, a complex multimode environment makes systematic characterization of light-matter interactions challenging. Here we present a general…

The interaction between quantum light and matter is being intensively studied for systems that are enclosed in high-$Q$ cavities which strongly enhance the light-matter coupling. However, for many applications, cavities with lower…

Quantum Physics · Physics 2022-06-29 H. Rose , O. V. Tikhonova , T. Meier , P. R. Sharapova

Polaritonic chemistry relies on the strong light-matter interaction phenomena for altering the chemical reaction rates inside optical cavities. To explain and to understand these processes, the development of reliable theoretical models is…

Chemical Physics · Physics 2022-09-14 Fabijan Pavošević , Angel Rubio

We study light-mediated interactions between spatially separated molecules using real-time quantum electrodynamical time-dependent density functional theory based on the Pauli-Fierz Hamiltonian. An ultrashort delta-kick excitation…

Chemical Physics · Physics 2026-01-22 Yetmgeta Aklilu , Tiany Yang , Cody Covington , Kalman Varga

Since the photon box gedanken experiments of several of the founding fathers of modern physics, considerable progress has been made in differentiating the quantum and classical worlds. In this pursuit, the cavity as an open quantum system…

Quantum Physics · Physics 2014-12-02 Nathan D. Poulin