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The gate-voltage-induced suppression of critical currents in metallic superconductors observed recently [De Simoni et al., Nat. Nanotechnol. 13, 802 (2018)] has raised crucial questions regarding the nature and mechanism of the electric…

A modified model of metal-semiconductor contacts is applied to analyze the capacitance-voltage and current-voltage characteristics of metal-ferroelectric-metal structures. The ferroelectric polarization is considered as a sheet of surface…

Materials Science · Physics 2007-05-23 L. Pintiliea , I. Boerasu , M. J. M. Gomes , T. Zhao , R. Ramesh , M. Alexe

We have measured the bending-induced polarization of Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystals with compositions at the relaxor-ferroelectric phase boundary. The crystals display very large flexoelectricity, with flexocoupling coefficients an…

Materials Science · Physics 2015-06-18 Jackeline Narvaez , Gustau Catalan

Functional devices with ultrathin ferroelectric layers have been attracted as a promising candidate for next-generation memory and logic device applications. Using the ultrathin ferroelectric layers, particularly approaching the…

The question whether ferroelectricity (FE) may coexist with a metallic or highly conducting state, or rather it must be suppressed by the screening from the free charges, is the focus of a rapidly increasing number of theoretical studies…

Materials Science · Physics 2019-02-20 F. Cordero , F. Trequattrini , F. Craciun , H. T. Langhammer , D. A. B. Quiroga , P. S. Silva

In ABO3 perovskites, oxygen octahedron rotations are common structural distortions that can promote large ferroelectricity in BiFeO3 with an R3c structure [1], but suppress ferroelectricity in CaTiO3 with a Pbnm symmetry [2]. For many…

Materials Science · Physics 2016-04-05 Hongwei Wang , Jianguo Wen , Dean J. Miller , Qibin Zhou , Mohan Chen , Ho Nyung Lee , Karin M. Rabe , Xifan Wu

Ferroelectrics are polar materials whose polarization can be switched by applying electric fields; they offer unique opportunities to develop performant photostrictive materials, i.e., materials that can deform under visible light…

Titanates with the perovskite structure, including ferroelectrics (e.g., BaTiO$_3$) and ferromagnetic ones (e.g., YTiO$_3$), are important functional materials. Recent theoretical studies predicted multiferroic states in strained EuTiO$_3$…

Materials Science · Physics 2015-12-14 Ming An , Huimin Zhang , Yakui Weng , Yang Zhang , Shuai Dong

Ferroelectric materials underlie key optical technologies in optical communications, integrated optics and quantum computing. Yet, there is a lack of a consistent thermodynamic framework to predict the optical properties of ferroelectrics…

In this paper we revisit the theory of negative capacitance, in a (i) standalone ferroelectric, (ii) ferroelectric-dielectric, and (iii) ferroelectric-semiconductor series combination, and show that it is important to minimize the total…

Mesoscale and Nanoscale Physics · Physics 2016-05-24 Kausik Majumdar , Suman Datta , Satyavolu Papa Rao

We formulate a general theory of the dielectric response of a lattice with a structural transition and a polarization instability due to a soft-optic mode coupled to low energy electronic excitations by the electromagnetic fields. the…

Materials Science · Physics 2007-05-23 T. K. Ng , C. M. Varma

The coexistence of superconductivity and ferroelectricity is rare due to their conflicting requirements: superconductivity relies on free charge carriers, whereas ferroelectricity typically occurs in insulating systems. At LaAlO3/KTaO3…

Superconductivity · Physics 2025-06-23 Meng Zhang , Ming Qin , Yanqiu Sun , Siyuan Hong , Yanwu Xie

The correlation between the shift current mechanism for the bulk photovoltaic effect (BPVE) and the structural and electronic properties of ferroelectric perovskite oxides is not well understood. Here, we study and engineer the shift…

Materials Science · Physics 2015-03-03 Fenggong Wang , Steve M. Young , Fan Zheng , Ilya Grinberg , Andrew M. Rappe

We investigate numerically the homogenized permittivities of composites made of low index dielectric inclusions in a ferroelectric matrix under a static electric field. A refined model is used to take into account the coupling between the…

Applied Physics · Physics 2019-09-04 Benjamin Vial , Yang Hao

First principles calculations are used to investigate the effects of epitaxial strain on the structure of the perovskite oxide CaTiO$_3$, with particular focus on the stabilization of a ferroelectric phase related to a polar instability…

Materials Science · Physics 2013-05-29 C. -J. Eklund , C. J. Fennie , K. M. Rabe

In ferroelectrics, complex interactions among various degrees of freedom enable the condensation of topologically protected polarization textures. Known as ferroelectric solitons, these particle-like structures represent a new class of…

Materials Science · Physics 2023-08-02 V. Govinden , P. R. Tong , X. Guo , Q. Zhang , S. Mantri , S. Prokhorenko , Y. Nahas , Y. Wu , L. Bellaiche , H. Tian , Z. Hong , D. Sando , V. Nagarajan

The persistence of ferroelectricity in ultrathin HfO$_2$ films challenges conventional theories, particularly given the paradoxical observation that the out-of-plane lattice spacing increases as the film thickness decreases, a reverse size…

Materials Science · Physics 2026-01-08 Tianyuan Zhu , Jingxuan Li , Zuhuang Chen , Shi Liu

The interactions between electrons and phonons drive a large array of technologically relevant material properties including ferroelectricity, thermoelectricity, and phase-change behaviour. In the case of many group IV-VI, V, and related…

Ferroelectricity is characterized by the presence of spontaneous and switchable macroscopic polarization. Scaling limits of ferroelectricity have been of both fundamental and technological importance, but the probes of ferroelectricity have…

By means of a model Hamiltonian approach we study the role of volume expansion, Hund's coupling and electron correlation in the standard hybridization mechanism for ferroelectricity in cubic CaMnO$_3$, a prototypical non-$d^0$ perovskite.…

Strongly Correlated Electrons · Physics 2015-05-30 Paolo Barone , Sudipta Kanungo , Silvia Picozzi , Tanusri Saha-Dasgupta