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We explore computationally the formation of tri-layer superlattices as an alternative approach for combining ferroelectricity with magnetism to form magnetoelectric multiferroics. We find that the contribution to the superlattice…

Materials Science · Physics 2011-11-09 Alison J. Hatt , Nicola A. Spaldin

We fabricated ultrathin ferroelectric/correlated electron oxide heterostructures composed of the ferroelectric Pb(Zr0.2Ti0.8)O3 and the correlated electron oxide (CEO) La0.8Sr0.2MnO3 on SrTiO3 substrates by pulsed laser epitaxy. The hole…

Materials Science · Physics 2012-07-25 Lu Jiang , Woo Seok Choi , Hyoungjeen Jeen , Takeshi Egami , Ho Nyung Lee

Using density-functional theory, we demonstrate that the formal layer charges of the metallic samarium nickelate electrode influence the spontaneous ferroelectric polarization of the barium titanate in SmNiO$_3$/BaTiO$_3$ capacitors. We…

Materials Science · Physics 2024-11-18 Edith Simmen , Nicola A. Spaldin

The effect of Sr doping in BaTiO3 (BTO) with nominal compositions Ba0.80Sr0.20TiO3 (BSTO) have been explored in its structural, lattice vibration, dielectric, ferroelectric and electrocaloric properties. The temperature dependent dielectric…

Materials Science · Physics 2020-03-02 Satish Yadav , Mohit Chandra , R. Rawat , Vasant Sathe , A. K. Sinha , Kiran Singh

We have studied ferroelectricity and photovoltaic effects in atomic layer deposited (ALD) 40-nm thick SnTiO$_{x}$ films deposited directly onto p-type (001)Si substrate. These films showed well-saturated, square and repeatable hysteresis…

First-principles calculations were performed to investigate the ferroelectric properties of barium titanate and bismuth ferrite, as well as phonon dispersion of BaTiO3, using density functional theory and density functional perturbation…

Materials Science · Physics 2014-12-08 Hong-Jian Feng

We provide a fundamental insight into the microscopic mechanisms of the ageing processes. Using large scale molecular dynamics simulations of the prototypical ferroelectric material PbTiO3, we demonstrate that the experimentally observed…

Materials Science · Physics 2017-11-01 J. B. J. Chapman , R. E. Cohen , A. V. Kimmel , D. M. Duffy

Motivated by an experimental report of iridate superlattices, we performed first-principle electronic structure calculations for SrIrO$_3$/SrTiO$_3$. Heterostructuring causes SrIrO$_3$ to become Sr$_2$IrO$_4$-like, and the system has the…

Strongly Correlated Electrons · Physics 2014-07-01 Kang-Hwan Kim , Heung-Sik Kim , Myung Joon Han

We have developed first-principles models, based on a general parametrization of the full potential-energy surface, to investigate the lattice-dynamical properties of perovskite oxides. We discuss the application of our method to prototypic…

Materials Science · Physics 2012-04-17 Jacek C. Wojdeł , Patrick Hermet , Mathias P. Ljungberg , Philippe Ghosez , Jorge Íñiguez

Lead free, silicon compatible materials showing large electromechanical responses comparable to, or better than conventional relaxor ferroelectrics, are desirable for various nanoelectromechanical devices and applications. Defect-engineered…

Ferroelectrics are attractive candidate materials for environmentally friendly solid state refrigeration free of greenhouse gases. Their thermal response upon variations of external electric fields is largest in the vicinity of their phase…

Materials Science · Physics 2016-05-20 G. G. Guzmán-Verri , P. B. Littlewood

Ferroelectric films usually have phase states and physical properties very different from those of bulk ferroelectrics. Here we propose free-standing ferroelectric-elastic multilayers as a bridge between these two material systems. Using a…

Materials Science · Physics 2011-10-18 S. Prokhorenko , N. A. Pertsev

Dielectric materials with tunable permittivity are highly desirable for wireless communication, radar technology. However, the tunability of dielectric properties in the microwave frequency range and higher is an immense challenge for…

Materials Science · Physics 2014-11-07 Ke Bi , Ji Zhou , Xiaoming Liu

SrTiO$_3$ is a unique example of a system which exhibits both quantum paraelectricity and superconductivity. Thus, it is expected that the superconducting state is closely related to the intrinsic ferroelectric instability. Indeed, recent…

Superconductivity · Physics 2019-09-05 Shota Kanasugi , Youichi Yanase

Heterostructures consisting of PbZr0.2Ti0.8O3 and PbZr0.4Ti0.6O3 films grown on a SrTiO3 (100) substrate with a SrRuO3 bottom electrode were prepared by pulsed laser deposition. Using the additional interface provided by the ferroelectric…

Materials Science · Physics 2009-03-27 Ludwig Geske , I. B. Misirlioglu , Ionela Vrejoiu , Marin Alexe , Dietrich Hesse

The size effect in ferroelectrics is treated as a competition between the geometrical symmetry of the ferroelectric sample and its crystalline symmetry. The manifestation of this competition is shown to be polarization rotation, which is…

Mesoscale and Nanoscale Physics · Physics 2010-08-09 Jin Wang , Alexander K. Tagantsev , Nava Setter

The effective mass is one of the main factors for enlarging the Seebeck coefficient and electronic conductivity of SrTiO3-based thermoelectric materials [1,2]. The goal of this paper is to clarify, how superlattices can change the effective…

Materials Science · Physics 2008-08-14 Wilfried Wunderlich , Hiromichi Ohta , Kunichi Koumoto

Hydrostatic pressure and oxygen vacancies usually have deleterious effects on ferroelectric materials because both tend to reduce their polarization. In this work we use first-principles calculations to study an important class of…

Materials Science · Physics 2021-12-15 Chengliang Xia , Yue Chen , Hanghui Chen

Materials tuned to the neighbourhood of a zero temperature phase transition often show the emergence of novel quantum phenomena. Much of the effort to study these new effects, like the breakdown of the conventional Fermi-liquid theory of…

Strongly Correlated Electrons · Physics 2014-05-06 S. E. Rowley , L. J. Spalek , R. P. Smith , M. P. M. Dean , G. G. Lonzarich , J. F. Scott , S. S. Saxena

We describe length and time rescaling across the paraelectric to ferroelectric phase transition in BaTiO$_3$. Small ferroelectric clusters are unable to grow in the paraelectric phase and exist for a short period of time only. The onset of…

Materials Science · Physics 2009-01-30 Marek Pasciak , Salah Eddine Boulfelfel , Stefano Leoni
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