Related papers: First CH$_{3}$D detection in Class 0/I proto-brown…

Observations of CH$^+$ are used to trace the physical properties of diffuse clouds, but this requires an accurate understanding of the underlying CH$^+$ chemistry. Until this work, the most uncertain reaction in that chemistry was…

Deuterated interstellar molecules frequently have abundances relative to their main isotopologues much higher than the overall elemental D-to-H ratio in the cold dense interstellar medium. The H$_3^+$ and its isotopologues play a key role…

Methyl isocyanate (CH$_{3}$NCO) belongs to a select group of interstellar molecules considered to be relevant precursors in the formation of larger organic compounds, including those with peptide bonds. The molecule has only been detected…

We report a reanalysis of a near-pristine absorption system, located at a redshift z_abs=2.52564 toward the quasar Q1243+307, based on the combination of archival and new data obtained with the HIRES echelle spectrograph on the Keck…

Abundant carbon-chain species have been observed towards lukewarm corinos L1527, B228, and L483. These carbon-chain species are believed to be synthesized in the gas phase after CH$_4$ desorbs from the dust grain surface at the temperature…

The nitrogen chemical evolution during star and planet formation is still not fully understood. Ammonia (NH$_3$) is a key specie in the understanding of the molecular evolution in star-forming clouds and nitrogen isotope fractionation. In…

The detection of Keplerian rotation is rare among Class 0 protostellar systems. We have investigated the high-density tracer HCN as a probe of the inner disk in a Class 0 proto-brown dwarf candidate. Our ALMA high angular resolution…

Tracing dust in small dense molecular cores is a powerful tool to study the conditions required for ices to form during the pre-stellar phase. To study these environments, five molecular cores were observed: three with ongoing low-mass star…

The abundance of CH+ and OH and excitation are predicted to be enhanced by the presence of vibrationally excited H2 or hot gas (~500-1000 K) in PDRs with high incident FUV radiation field. The excitation may also originate in dense gas…

Context: Dimethyl sulfide (DMS; CH$_3$SCH$_3$) is an organosulfur compound that has been suggested as a potential biosignature in exoplanetary atmospheres. In addition to its tentative detections toward the sub-Neptune planet K2-18b, DMS…

JWST/NIRSpec observations of Makemake reveal a chemically complex surface and evidence of gaseous CH$_4$. Our spectral modeling indicates a surface composition consisting of CH$_4$, CH$_3$D, and possibly CH$_3$OH, combined with aggregates…

We present observations of HDCO and H2CO emission toward a sample of 15 Class 0 protostars in the Orion A and B clouds. Of these, eleven protostars are Herschel-identified PACS Bright Red Sources (PBRS) and four are previously identified…

The deuterium fractionation, Dfrac, has been proposed as an evolutionary indicator in pre-protostellar and protostellar cores of low-mass star-forming regions. We investigate Dfrac, with high angular resolution, in the cluster environment…

We present the first detection of carbon monoxide (CO) in a damped Lyman-alpha system (DLA) at z_abs =2.41837 toward SDSS J143912.04+111740.5. We also detected H_2 and HD molecules. The measured total column densities (in log units) of H I,…

The chemical composition of planets is inherited from that of the protoplanetary disk at the time of planet formation. Increasing observational evidence suggests that planet formation occurs in less than 1 Myr. This motivates the need for…

CH2 transitions between 68 and 71 GHz were first detected toward the Orion-KL and W51 Main SFRs. Given their upper level energies of 225 K, they were thought to arise in dense, hot molecular cores near newly formed stars. However, this has…

Aims. Excitation of far-infrared and submillimetric molecular lines may originate from nonreactive collisions, chemical formation, or far infrared, near-infrared, and optical fluorescences. As a template, we investigate the impact of each…

CO is thought to be the main reservoir of volatile carbon in protoplanetary disks, and thus the primary initial source of carbon in the atmospheres of forming giant planets. However, recent observations of protoplanetary disks point towards…

For understanding carbon erosion and redeposition in nuclear fusion devices, it is important to understand the transport and chemical break-up of hydrocarbon molecules in edge plasmas, often diagnosed by emission of the CH A^2\Delta -…

We have observed the low-mass protostellar source, IRAS 15398$-$3359, at a resolution of 0.$''$2-0.$''$3, as part of the Atacama Large Millimeter/Submillimeter Array Large Program FAUST, to examine the presence of a hot corino in the…