Related papers: First CH$_{3}$D detection in Class 0/I proto-brown…

We present results from the first molecular line survey to search for the fundamental complex organic molecule, methanol (CH$_{3}$OH), in 14 Class 0/I proto-brown dwarfs (proto-BDs). IRAM 30-m observations over the frequency range of 92-116…

Deuterium fractionation can constrain the physical and chemical conditions at the early stage of brown dwarf formation. We present IRAM 30m observations over a wide frequency range of 213-279 GHz of singly and doubly deuterated species of…

The millimeter-wave rotational transition line ($J_K = 1_0 - 0_0$) of deuterated methane CH$_3$D has tentatively been detected toward the low-mass Class 0 protostar IRAS 04368+2557 in L1527 with the Heinrich Hertz Submillimeter Telescope.…

We have conducted the first extensive observational survey of several deuterated species in 16 Class 0/I proto-brown dwarfs (proto-BDs) and 4 Class Flat/Class II brown dwarfs. Observations were obtained with the IRAM 30m telescope in the…

We present results from a study of nitrogen chemistry in Class 0/I proto-brown dwarfs (proto-BDs). We have used the IRAM 30 m telescope to observe the CN (2-1), HCN (3-2), and HNC (3-2) lines in 7 proto-BDs. All proto-BDs show a large…

We present a study of the CO isotopologues and the high-density tracers H$_{2}$CO, HCO$^{+}$, and CS in Class 0/I proto-brown dwarfs (proto-BDs). We have used the IRAM 30m telescope to observe the $^{12}$CO (2-1), $^{13}$CO (2-1), C$^{18}$O…

Iram 30-m Observations towards eight protostellar outflow sources were taken in the 96-\SI{176}{\giga\hertz} range. Transitions of CH$_3$OH and CH$_3$CHO were detected in seven of them. The integrated emission of the transitions of each…

Deuterium fractionation is known to enhance the [DCO+]/[HCO+] abundance ratio over the D/H elemental ratio of about 1e-5 in the cold and dense gas typically found in pre-stellar cores. We report the first detection and mapping of very…

We present a near-infrared study of accretion and outflow activity in 6 Class 0/I proto-brown dwarfs (proto-BDs) using VLT/SINFONI spectroscopy and spectro-imaging observations. The spectra show emission in several [FeII] and H$_{2}$ lines…

Observations with the Short Wavelength Spectrometer (SWS) onboard the {\it Infrared Space Observatory} (ISO) have led to the first detection of the methyl radical ${\rm CH_3}$ in the interstellar medium. The $\nu_2$ $Q-$branch at 16.5…

We use spectra and maps of the $J=1-0$ and $J=2-1$ DCO$^{+}$, DCN, DNC, $\rm N_2D^+$ lines and $1_{11}-1_{01}$ ortho- and para-NH$_{2}$D lines, obtained with the IRAM-30m telescope, as well as observations of their hydrogenated…

Most protoplanetary disks experience a phase in which they are subjected to strong ultraviolet radiation from nearby massive stars. This UV radiation can substantially alter their chemistry by producing numerous radicals and molecular ions.…

The relative abundance of deuterium and hydrogen is a potent tracer of planet formation and evolution. Jupiter and Saturn have protosolar atmospheric D/H ratios, a relic of substantial gas accretion from the nebula, while the atmospheres of…

We present the first extragalactic detections of several CH rotational transitions in the far-infrared (FIR) in four nearby galaxies: NGC 1068, Arp 220, M 82 and NGC 253 using the \textit{Herschel Space Observatory}. The CH lines in all…

We investigate the molecular evolution and D/H abundance ratios that develop as star formation proceeds from a dense-cloud core to a protostellar core, by solving a gas-grain reaction network applied to a 1-D radiative hydrodynamic model…

High levels of deuterium fractionation in gas-phase molecules are usually associated with cold regions, such as prestellar cores. Significant fractionation ratios are also observed in hot environments such as hot cores or hot corinos, where…

We report the first detection in space of the single deuterated isotopologue of methylcyanoacetylene, CH$_2$DC$_3$N. A total of fifteen rotational transitions, with $J$ = 8-12 and $K_a$ = 0 and 1, were identified for this species in TMC-1…

While the abundance of elemental deuterium is relatively low (D/H ~ a few 1E-5), orders of magnitude higher D/H abundance ratios have been found for many interstellar molecules, enhanced by deuterium fractionation. In cold molecular clouds…

The CH$^+$ ion is a key species in the initial steps of interstellar carbon chemistry. Its formation in diverse environments where it is observed is not well understood, however, because the main production pathway is so endothermic (4280…

Despite its importance in the thermal-balance of the gas and in the determination of primeval planetary atmospheres, the chemistry in protoplanetary discs remains poorly constrained with only a handful of detected species. We observed the…