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The mechanisms underlying the enhancement of magnetic anisotropies (MAs) of Sm ions, owing to valence electrons at the Sm site and the screened nuclear charges of ligands, are clarified using a detailed analysis of crystal fields (CF). In…

Materials Science · Physics 2022-01-12 Takuya Yoshioka , Hiroki Tsuchiura , Pavel Novák

We report here a comprehensive study of the AFM structures of the Eu and Mn magnetic sublattices as well as the interplay between Eu and Mn magnetism in this compound by using both polarized and non-polarized single-crystal neutron…

Metallic Mn-based alloys with a nearest-neighbor Mn-Mn distance greater than 0.4 nm exhibit large, well-localized magnetic moments. Here we investigate the magnetism of tetragonal Au4Mn with a Curie temperature of 385 K, where manganese has…

The anisotropy splitting in the ground state of the single-molecule magnet [Mn4O3Br(OAc)3(dbm)3] is studied by inelastic neutron scattering as a function of hydrostatic pressure. This allows a tuning of the anisotropy and thus the energy…

Strongly Correlated Electrons · Physics 2009-11-10 Andreas Sieber , Gregory Chaboussant , Roland Bircher , Colette Boskovic , Hans U. Guedel , George Christou , Hannu Mutka

The presence of macroscopic phase separation into superconducting and magnetic phases in LaFeAsO$_{1-x}$F$_x$ (LFAOF) and CaFe$_{1-x}$Co$_x$AsF (CFCAF) is demonstrated by muon spin rotation (muSR) measurement across their phase boundaries…

Superconductivity · Physics 2009-04-01 S. Takeshita , R. Kadono

Modeling blocking temperature in molecular magnets has been a long standing problem in the field of molecular magnetism. We investigate this problem using a kinetic Monte Carlo (kMC) approach on an assembly of 100,000 short molecular…

Strongly Correlated Electrons · Physics 2021-06-23 Sumit Haldar , S. Ramasesha

Analysis of neutron diffraction, dc magnetization, ac magnetic susceptibility, heat capacity, and electrical resistivity for DyRuAsO in an applied magnetic field are presented at temperatures near and below those at which the structural…

Strongly Correlated Electrons · Physics 2015-06-22 Michael A. McGuire , V. Ovidiu Garlea , Andrew F. May , Brian C. Sales

We conducted a systematic angular dependence study of nonlinear magnetoresistance in NiFe/Pt bilayers at variable temperature and field using the Wheatstone bridge method. We successfully disentangled magnon magnetoresistance from other…

Mesoscale and Nanoscale Physics · Physics 2019-10-02 Yanjun Xu , Yumeng Yang , Ziyan Luo , Yihong Wu

We present the magnetic properties of three recently synthesized binuclear molecular complexes [NiNd], [NiGd] and [ZnGd] investigated by dc magnetization and proton nuclear magnetic resonance (NMR) measurements. The high-temperature…

Mesoscale and Nanoscale Physics · Physics 2011-12-01 P. Khuntia , M. Mariani , A. V. Mahajan , A. Lascialfari , F. Borsa , T. D. Pasatoiu , M. Andruh

We present a microscopic theory of single molecule magnets. From our exact single-ion spin matrix elements for four arbitrary spins, we study the single-ion anisotropy of equal spins exhibiting $T_d$, $D_{2d}$, or $C_{4v}$ molecular group…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 Richard A. Klemm , Dmitri V. Efremov

The balance between the orbital and spin magnetic moments in a magnetic system is the heart of many intriguing phenomena. Here, we show experimental evidence of a large orbital moment, which competes with its spin counterpart in a…

We report an unusual canted magnetism due to 3d and 4f electrons, occupying two different crystallographic sites, with its consequence to electric dipole order. This is based on neutron powder diffraction measurements on Tb2BaNiO5…

SmN is a ferromagnetic semiconductor with the unusual property of an orbital-dominant magnetic moment that is largely cancelled by an antiparallel spin contribution, resulting in a near-zero net moment. However, there is a basic gap in the…

Materials Science · Physics 2016-03-02 J. F. McNulty , B. J. Ruck , H. J. Trodahl

The magnetic ground state of double perovskite Sr2DyRuO6 has been investigated using muon spin rotation and relaxation (muSR), neutron powder diffraction (NPD) and inelastic neutron scattering (INS), in addition to heat capacity and…

Strongly Correlated Electrons · Physics 2020-03-19 D. T. Adroja , Shivani Sharma , C. Ritter , A. D. Hillier , C. V. Tomy , R. Singh , R. I. Smith , M. Koza , A. Sundaresan , S. Langridge

To identify the possible mechanism of coercivity (Hc) degradation of Nd-Fe-B sintered magnets, we study the roles of the exchange field acting on the 4f electrons in Nd ions and theoretically investigate how the variation of the exchange…

Materials Science · Physics 2015-06-23 Ryo Sasaki , Daisuke Miura , Akimasa Sakuma

We investigated the magnetic phase diagram of single crystals of SrNdFeO$_{4}$ by measuring the magnetic properties, the specific heat and the dielectric permittivity. The system has two magnetically active ions, Fe$^{3+}$ and Nd$^{3+}$.…

Materials Science · Physics 2015-06-05 J. M. Hwang , E. S. Choi , H. D. Zhou , Y. Xin , J. Lu , P. Schlottmann

The development of new-generation permanent magnets is based on experimental efforts and innovative theoretical tools for modeling magnetic properties. Magnetocrystalline anisotropy energy (MAE) - one of the main intrinsic properties of…

SmN is ferromagnetic below 27 K, and its net magnetic moment of 0.03 Bohr magnetons per formula unit is one of the smallest magnetisations found in any ferromagnetic material. The near-zero moment is a result of the nearly equal and…

Dimers are the smallest chemical objects that show magnetic anisotropy. We focus on 3$d$ and 4$d$ transition metal dimers that have magnetic ground states in most cases. Some of these magnetic dimers have a considerable barrier against…

Atomic and Molecular Clusters · Physics 2008-04-09 Daniel Fritsch , Klaus Koepernik , Manuel Richter , Helmut Eschrig

The dimeric form of the single-molecule magnet [Mn$_4$O$_3$Cl$_4$(O$_2$CEt)$_3$(py)$_3$]$_2$ recently revealed interesting phenomena: no quantum tunneling at zero field and tunneling before magnetic field reversal. This is attributed to…