Related papers: Enantiodiscrimination of chiral molecules via quan…
This review is based on the talk in the conference of "Spectroscopic Studies on Molecular Chirality" held on Dec 20-21 2013. The objects of the present paper are to (1) derive the energy difference between Laevorotatory, or left-handed,…
Chirality is a fundamental molecular property that governs stereospecific behavior in chemistry and biology. Capturing chirality in machine learning models remains challenging due to the geometric complexity of stereochemical relationships…
Controlling the polarization state of electromagnetic radiation enables the investigation of fundamental symmetry properties of matter through chiroptical processes. Many strategies have been developed to reveal structural or dynamical…
We conceived a model experiment for a continuous separation strategy of chiral molecules (enantiomers) without the need of any chiral selector structure or derivatization agents: Micro-particles that only differ by their chirality are shown…
We investigate the two-terminal nonlinear conductance of a Coulomb-blockaded quantum dot attached to chiral edge states. Reversal of the applied magnetic field inverts the system chirality and leads to a different polarization charge. As a…
Detecting and controlling the chirality of materials play an essential role in exploring nature, providing new avenues for material creation, discrimination, and manipulation. In such tasks, chiral reagents are essential in defining or…
We introduce meta-diastereomers, hybrid systems where molecular chirality ($\leq 10$\,nm) and nanoscale chirality ($>100$\,nm) combine to create a new hierarchical chiral state with emergent optical properties. By coupling chiral…
Chirality is probably the most mysterious among all symmetry transformations. Very readily broken in biological systems, it is practically absent in naturally occurring inorganic materials and is very challenging to create artificially.…
Circular Dichroism (CD) can distinguish the handedness of chiral molecules. However, it is typically very weak due to vanishing absorption at low molecular concentrations. Here, we suggest Thermal Circular Dichroism (TCD) for chiral…
Preferential selection of a given enantiomer over its chiral counterpart becomes increasingly relevant in the advent of the next era of medical drug design. In parallel, cavity quantum electrodynamics has grown into a solid framework to…
Chirality, or handedness, is a geometrical property denoting a lack of mirror symmetry. Chirality is ubiquitous in nature and is associated with the non-reciprocal interactions observed in complex systems ranging from biomolecules to…
Understanding the condensed-phase behavior of chiral molecules is important in biology, as well as in a range of technological applications, such as the manufacture of pharmaceuticals. Here, we use molecular dynamics simulations to study a…
Predicting the macroscopic chiral behaviour of cholesteric liquid crystals from the microscopic chirality of the particles is highly non-trivial, even when the chiral interactions are purely entropic in nature. Here we introduce a novel…
Chirality in inorganic nanoparticles and nanostructures has gained increasing scientific interest, because of the possibility to tune their ability to interact differently with left- and right-handed circularly polarized light. In some…
During the early developmental process of organisms, the formation of the left-right laterality requires a subtle mechanism, as it is associated with other principal body axes. Any inherent chiral feature in an egg cell can in principal…
Achiral molecules can be made temporarily chiral by excitation with electric fields, in the sense that an average over molecular orientations displays a net chiral signal [Tikhonov et al., Sci. Adv. 8, eade0311 (2022)]. Here, we go beyond…
Recently, there is a great interest in studying ultrasensitive detection and characterization of biomolecules using plasmonic particles, because they are of considerable importance in biomedical science and pharmaceutics. So far, all the…
We investigate the real-time dynamics of the chiral magnetic effect in quantum electrodynamics (QED) and quantum chromodynamics (QCD). We consider a field configuration of parallel (chromo)electric and (chromo)magnetic fields with a weak…
The chiral algebra of tetrahedral molecules, derived from Fischer projections, is discussed in the framework of quantum mechanics. A quantum chiral algebra is obtained whose operators, acting as rotations or inversions, commute with the…
In condensed matter physics, a broad spectrum of physical characteristics, such as chirality, axiality, and polarity, arises as a direct consequence of the underlying symmetry of the system. We here theoretically investigate the effective…