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By studying the dielectric properties of the geometrically frustrated spinel CdV2O4, we observe ferroelectricity developing at the transition into the collinear antiferromagnetic ground state. In this multiferroic spinel, ferroelectricity…

Measurements of ferroelectric polarization and dielectric constant were done on $R$Mn$_2$O$_5$ ($R$=Tb, Dy, and Ho) with applied hydrostatic pressures of up to 18 kbar. At ambient pressure, distinctive anomalies were observed in the…

Strongly Correlated Electrons · Physics 2009-11-13 C. R. dela Cruz , B. Lorenz , Y. Y. Sun , Y. Wang , S. Park , S-W. Cheong , M. M. Gospodinov , C. W. Chu

Neutron diffraction measurements on multiferroic LuFe2O4 show changes in the antiferromagnetic (AFM) structure characterized by wavevector q = (1/3 1/3 1/2) as a function of electric field cooling procedures. The increase of intensity from…

Strongly Correlated Electrons · Physics 2011-11-09 A. M. Mulders , M. Bartkowiak , J. R. Hester , E. Pomjakushina , K. Conder

We investigate the electronic structure and the ferroelectric properties of the recently discovered multiferroic ScFeO$_3$ by means of ab-initio calculations. The $3d$ manifold of Fe in the half-filled configuration naturally favors an…

Electronic ferroelectricity from charge ordering (CO) is currently a significant issue that has been extensively investigated in the charge/spin frustrated LuFe2O4 system. Chemical substitution and structural layer intercalation have been…

Strongly Correlated Electrons · Physics 2008-03-17 H. X. Yang , Y. Zhang , C. Ma , H. F. Tian , Y. B. Qin , Y. G. Zhao , J. Q. Li

The magnetic, thermodynamic, and pyroelectric properties of LiFeP$_2$O$_7$ single crystals are investigated with emphasis on the magnetoelectric interaction of the electrical polarization with the magnetic order parameter. The magnetic…

Strongly Correlated Electrons · Physics 2012-09-13 K. -C. Liang , W. Zhang , B. Lorenz , Y. Y. Sun , P. S. Halasyamani , C. W. Chu

The van der Waals (vdW) layered multiferroics, which host simultaneous ferroelectric and magnetic orders, have attracted attention not only for their potentials to be utilized in nanoelectric devices and spintronics, but also offer…

Magnetic and dielectric properties on a polycrystalline La0.7Bi0.3CrO3 have been investigated. A canted antiferromagnetic (CAF) phase transition giving weak ferromagnetism at TN = 230K has been observed. M-H at 10K shows non-saturating…

Strongly Correlated Electrons · Physics 2014-03-17 Aga Shahee , Dhirendra kumar , N. P. Lalla

Due to the strong coupling between magnetism and ferroelectricity, $(\mathrm{ND}_4)_2\mathrm{FeCl}_5\cdot\mathrm{D}_2\mathrm{O}$ exhibits several intriguing magnetic and electric phases. In this letter, we include high-order onsite spin…

Materials Science · Physics 2021-08-25 Shaozhi Li , Randy S. Fishman

The correlation between static magnetoelectric coupling and magnetic structure was investigated in $TbMn_{0.98}Fe_{0.02}O_{3}$ with magnetic field up to 8 T and down to 2 K. Single-crystal neutron diffraction experiments reveal a…

LuFe2O4 often is considered as a prototypical multiferroic with polar order arising from the electronic degrees of freedom only ("electronic ferroelectricity"). In the present work, we check the intrinsic nature of the dielectric response…

Strongly Correlated Electrons · Physics 2012-08-31 A. Ruff , S. Krohns , F. Schrettle , V. Tsurkan , P. Lunkenheimer , A. Loidl

We have investigated the magnetic and dielectric properties of orthorhombic Eu$_{1-y}$Y$_y$MnO$_3$ ($0\leq y\leq 0.6$) single crystals without the presence of the 4$f$ magnetic moments of the rare-earth ions. In $y\geq 0.2$, the…

Strongly Correlated Electrons · Physics 2015-05-28 Mitsuru Akaki , Masaaki Hitomi , Mizuaki Ehara , Daisuke Akahoshi , Hideki Kuwahara

The thermodynamic, magnetic, dielectric, and magnetoelectric properties of HoFe$_3$(BO$_3$)$_4$ and Ho$_{0.5}$Nd$_{0.5}$Fe$_3$(BO$_3$)$_4$ are investigated. Both compounds show a second order Ne\'{e}l transition above 30 K and a first order…

Strongly Correlated Electrons · Physics 2009-09-24 R. P. Chaudhury , F. Yen , B. Lorenz , Y. Y. Sun , L. N. Bezmaternykh , V. L. Temerov , C. W. Chu

We report the low-temperature coexistence in NdFe3(BO3)4 of an incommensurate magnetic phase with a strained commensurate magnetic phase that is primarily at the surface of the crystal. Increasing the temperature or magnetic field decreases…

Materials Science · Physics 2015-06-16 Christie S. Nelson , Leonard N. Bezmaternykh , Irina A. Gudim

A ferroelectric transition occurring simultaneously with helical spin order has been found in both the polycrystalline and single crystal samples of LiCuVO4. The system has Cu2+ spins (s=1/2) of the CuO2 chains formed of edge-sharing CuO4…

Strongly Correlated Electrons · Physics 2015-06-25 Yutaka Naito , Kenji Sato , Yukio Yasui , Yusuke Kobayashi , Yoshiaki Kobayashi , Masatoshi Sato

We report a ferroelectric order at ~ 98 K for NiFe2O4, which carries an inverse spinel structure with a centrosymmetric Fd3m structure at room temperature. The value of spontaneous electric polarization is considerably high as ~ 0.29…

Materials Science · Physics 2019-05-10 J. K. Dey , A. Chatterjee , S. Majumdar , A. -C. Dippel , O. Gutowski , M. v. Zimmermann , S. Giri

Magnetoelectric multiferroics in which ferroelectricity and magnetism coexist have attracted extensive attention because they provide great opportunities for the mutual control of electric polarization by magnetic fields and magnetization…

Materials Science · Physics 2013-04-25 Fen Wang , Tao Zou , Li-Qin Yan , Yi Liu , Young Sun

We have investigated the spontaneous polarization in Fe$_3$O$_4$ thin films by using dynamic and static pyroelectric measurements. The magnetic and dielectric behavior of Fe$_3$O$_4$ thin films grown on Nb:SrTiO$_3$(001) substrates was…

Materials Science · Physics 2012-10-09 R. Takahashi , H. Misumi , M. Lippmaa

The spin-driven component of electric polarization in a single crystal of multiferroic BiFeO$_{3}$ was experimentally investigated in pulsed high magnetic fields up to 41 T. Sequential measurements of electric polarization for various…

Strongly Correlated Electrons · Physics 2020-01-08 Shiro Kawachi , Shin Miyahara , Toshimitsu Ito , Atsushi Miyake , Nobuo Furukawa , Jun-ichi Yamaura , Masashi Tokunaga

The structural and polar properties of BiFeO3 at finite temperature are investigated using an atomistic shell model fitted to first-principles calculations. Molecular Dynamics simulations show a direct transition from the low-temperature…

Materials Science · Physics 2015-06-23 M. Graf , M. Sepliarsky , S. Tinte , M. G. Stachiotti