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Using the results of x-ray and neutron diffraction experiments, we show that the ferroelectric polarization, in ~22 nm particles of BiFeO3, exhibits a jump by ~30% around the magnetic transition point T_N (~635 K) and a suppression by ~7%…

Materials Science · Physics 2011-08-18 S. Goswami , Dipten Bhattacharya , P. Choudhury , B. Ouladdiaf , T. Chatterji

Magnetoelectric coupling in the polycrystalline antiferromagnets CuFe0.95Rh0.05O2 and CuFeO2 has been investigated. For both samples, electric polarization was observed in the absence of an applied external magnetic field demonstrating that…

Materials Science · Physics 2009-05-27 B. Kundys , A. Maignan , D. Pelloquin , Ch. Simon

Our measured dielectric constant and mechanical response of multiferroic BiFeO3 indicate four phase transitions below room temperature. Features correlate with those reported at 50K (from a peak in the zero-field-cooled magnetic…

Materials Science · Physics 2008-06-23 S. A. T. Redfern , C. Wang , J. W. Hong , G. Catalan , J. F. Scott

Magnetic and/or dielectric behaviors have been studied for YBaCuFeO5, LuBaCuFeO5 and TmBaCuFeO5, which are known as members of oxygen-defect ordered perovskite systems RBaCuFeO5 (R=lanthanides Ln and other trivalent elements) and have two…

Strongly Correlated Electrons · Physics 2010-09-21 Yuji Kawamura , Takahiro Kai , Erika Satomi , Yukio Yasui , Yoshiaki Kobayashi , Masatoshi Sato

We report multiferroic behavior in double perovskite Y2CoMnO6 with ferroelectric transition temperature Tc = 80K. The origin of ferroelectricity is associated with magnetic ordering of Co2+ and Mn4+ moments in a up-up-down-down arrangement.…

Materials Science · Physics 2015-06-15 G. Sharma , J. Saha , S. Patnaik

Magnetic and dielectric properties of the hexagonal triangular lattice antiferromagnet 2H-AgFeO2 have been studied by neutron diffraction, magnetic susceptibility, specific heat, pyroelectric current, and dielectric constant measurements.…

Strongly Correlated Electrons · Physics 2019-03-05 Noriki Terada , Dmitry D. Khalyavin , Pascal Manuel , Yoshihiro Tsujimoto , Alexei A. Belik

Sm$_2$Ti$_2$O$_7$, a member of rare-earth titanate pyrochlores, exhibits dipolar-octupolar antiferromagnetism below $T_N$ = 0.35 K. We observed two ferroelectric transitions at 182 ($T_{FE1}$) and 52 K ($T_{FE2}$), significantly higher than…

Materials Science · Physics 2024-07-30 S. Mukherjee , O. Ivashko , S. Majumdar , A. Kumar , S. Giri

We present direct evidence of above room temperature magneto-electricity in single-phase Li0.05Ti0.02Ni0.93O with above-ambient antiferromagnetic ordering. Temperature-hysteresis in warming/cooling heat-flow thermograms establishes a…

Materials Science · Physics 2015-09-15 Jitender Kumar , Pankaj K. Pandey , A. M. Awasthi

Apart from being so far the only known binary multiferroic compound, CuO has a much higher transition temperature into the multiferroic state, 230 K, than any other known material in which the electric polarization is induced by spontaneous…

The magnetic, dielectric and structural properties of type-I multiferroic KNiPO$_4$ have been investigated by neutron powder diffraction, magnetization, dielectric and high temperature synchrotron-XRD measurements. Below the N\'{e}el…

Strongly Correlated Electrons · Physics 2022-07-15 Alexandre Pages , Jian-Rui Soh , Marjaneh Jafari Fesharaki , Henrik M. Ronnow , Hossein Ahmadvand

The layered cuprate Bi$_{2}$CuO$_{4}$ is investigated using magnetic, dielectric and pyroelectric measurements. This system is observed to be an improper multiferroic, with a robust ferroelectric state being established near the magnetic…

Strongly Correlated Electrons · Physics 2017-03-06 Jitender Kumar , Soumendra Nath Panja , Amit Kumar Naiya , Sunil Nair

Dielectric and magnetic properties of Eu0.5Ba0.25Sr0.25TiO3 are investigated between 10 K and 300 K in the frequency range from 10 Hz to 100 THz. A peak in permittivity revealed near 130 K and observed ferroelectric hysteresis loops prove…

Materials Science · Physics 2012-10-12 Veronica Goian , Stanislav Kamba , Premysl Vanek , Maxim Savinov , Christelle Kadlec , Jan Prokleska

We report the discovery of linear magnetoelectric effect in the well-known green phase compound, Sm2BaCuO5, which crystallizes in the centrosymmetric orthorhombic (Pnma) structure. Magnetization and specific heat measurements reveal the…

Strongly Correlated Electrons · Physics 2019-10-02 Premakumar Yanda , N. V. Ter-Oganessian , A. Sundaresan

We report remarkable multiferroic effects in polycrystalline Bi2Fe4O9. High-resolution X-ray diffraction shows that this compound has orthorhombic structure. Magnetic measurements confirm an antiferromagnetic transition around 260 K. A…

Materials Science · Physics 2009-11-13 A. K. Singh , S. D. Kaushik , Brijesh Kumar , A. Venimadhav , P. K. Mishra , V. Siriguri , S. Patnaik

Solid solution BiFe1-xCoxO3 shows anti-ferromagnetic order and pyroelectric order, simultaneously. It has been known that BiFe1-xCoxO3 exhibits a structural phase transition between monoclinic and tetragonal phases as x increases. This…

Materials Science · Physics 2021-12-15 Hiroshi Katsumoto , Kunihiko Yamauchi , Tamio Oguchi

Competing interactions and geometric frustration provide favourable conditions for exotic states of matter. Such competition often causes multiple phase transitions as a function of temperature and can lead to magnetic structures that break…

Single-crystal samples of LiCu2O2 with spin 1/2 Cu2+ chains of edge-sharing CuO4 square planes (ribbon chains), have been characterized by X-ray diffraction, thermogravimetric analysis, and magnetic measurements. Neither the atomic…

Materials Science · Physics 2015-05-13 Yukio Yasui , Kenji Sato , Yoshiaki Kobayashi , Masatoshi Sato

We report observation of magneto-electric and magneto-dielectric couplings in ceramic Co3TeO6. Temperature dependent DC magnetization and dielectric constant measurements together indicate coupling between magnetic order and electronic…

Materials Science · Physics 2013-09-26 Harishchandra Singh , Haranath Ghosh , A. K. Sinha , M. N. Singh , G. Sharma , S. Patnaik , S. K. Deb

Magnetic dc susceptibility between 1.5 and 800 K, ac susceptibility and magnetization, thermodynamic properties, temperature dependence of radio and audio-wave dielectric constants and conductivity, contact-free dielectric constants at…

Materials Science · Physics 2010-07-22 Jun Lu , A. Günther , F. Schrettle , F. Mayr , S. Krohns , P. Lunkenheimer , A. Pimenov , V. D. Travkin , A. A. Mukhin , A. Loidl

The geometrically frustrated magnet Ni3V2O8 undergoes a series of competing magnetic ordering at low temperatures. Most importantly, one of the incommensurate phases has been reported to develop a ferroelectric correlation caused by spin…

Materials Science · Physics 2009-06-26 A. K. Singh , D. Jain , V. Ganesan , A. K. Nigam , S. Patnaik