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Transition metal dichalcogenide semiconductors represent elementary components of layered heterostructures for emergent technologies beyond conventional opto-electronics. In their monolayer form they host electrons with quantized circular…

The two dimensional layered transition metal dichalcogenides provide new opportunities in future valley based information processing and also provide ideal platform to study excitonic effects. At the center of various device physics toward…

Materials Science · Physics 2017-04-05 Dong Sun , Jiawei Lai , Junchao Ma , Qinsheng Wang , Jing Liu

Electron valleys in transition-metal dichalcogenide monolayers drive novel physics and allow designing multifunctional architectures for applications. We propose to manipulate the electron valleys in these systems for spin/valley filter and…

Mesoscale and Nanoscale Physics · Physics 2021-11-15 Ao Zhang , Kaike Yang , Yun Zhang , Anlian Pan , Mingxing Chen

Monolayer group-VIB transition metal dichalcogenides have recently emerged as a new class of semiconductors in the two-dimensional limit. The attractive properties include: the visible range direct band gap ideal for exploring…

Mesoscale and Nanoscale Physics · Physics 2015-07-30 Hongyi Yu , Xiaodong Cui , Xiaodong Xu , Wang Yao

The selective control of specific momentum valleys lies at the core of valleytronics, a field that has thus far focused primarily on the $\mathbf{K}$ and $\mathbf{K'}$ valleys in transition metal dichalcogenides (TMDs). However, direct…

Strongly Correlated Electrons · Physics 2026-05-05 Youngjae Kim

Recent results on the optical properties of mono- and few-layers of semiconducting transition metal dichalcogenides are reviewed. Experimental observations are presented and discussed in the frame of existing models, highlighting the limits…

Mesoscale and Nanoscale Physics · Physics 2017-09-19 M. Koperski , M. R. Molas , A. Arora , K. Nogajewski , A. O. Slobodeniuk , C. Faugeras , M. Potemski

We study the effect of point-defect chalcogen vacancies on the optical properties of monolayer transition metal dichalcogenides using ab initio GW and Bethe-Salpeter equation calculations. We find that chalcogen vacancies introduce…

Materials Science · Physics 2018-10-24 Sivan Refaely-Abramson , Diana Y. Qiu , Steven G. Louie , Jeffrey B. Neaton

In transition metal dichalcogenides, the valley degree of freedom directly couples valley-polarised excitons - excited by circularly polarised light - to valley-dependent chiral photons, enabling ultrafast light-driven valleytronics.…

Alloyed transition metal dichalcogenides provide an opportunity for coupling band engineering with valleytronic phenomena in an atomically-thin platform. However, valley properties in alloys remain largely unexplored. We investigate the…

Mesoscale and Nanoscale Physics · Physics 2020-01-17 Sean M. Oliver , Joshua Young , Sergiy Krylyuk , Thomas L. Reinecke , Albert V. Davydov , Patrick M. Vora

The band structure of many semiconducting monolayer transition metal dichalcogenides (TMDs) possesses two degenerate valleys, with equal and opposite Berry curvature. It has been predicted that, when illuminated with circularly polarized…

Mesoscale and Nanoscale Physics · Physics 2017-09-19 Nicolas Ubrig , Sanghyun Jo , Marc Philippi , Davide Costanzo , Helmuth Berger , Alexey B. Kuzmenko , Alberto F. Morpurgo

The direct gap interband transitions in transition metal dichalcogenides monolayers are governed by chiral optical selection rules. Determined by laser helicity, optical transitions in either the $K^+$ or $K^-$ valley in momentum space are…

Mesoscale and Nanoscale Physics · Physics 2016-10-26 G. Wang , X. Marie , B. L. Liu , T. Amand , C. Robert , F. Cadiz , P. Renucci , B. Urbaszek

Single layers of transition metal dichalcogenides are two-dimensional direct bandgap semiconductors with degenerate, but inequivalent, `valleys' in the electronic structure that can be selectively excited by polarized light. Coherent…

Materials Science · Physics 2017-07-21 Yen-Jung Chen , Jeffrey D. Cain , Teodor K. Stanev , Vinayak P. Dravid , Nathaniel P. Stern

Breaking space-time symmetries in two-dimensional crystals (2D) can dramatically influence their macroscopic electronic properties. Monolayer transition-metal dichalcogenides (TMDs) are prime examples where the intrinsically broken crystal…

Mesoscale and Nanoscale Physics · Physics 2015-09-04 Edbert J. Sie , James W. McIver , Yi-Hsien Lee , Liang Fu , Jing Kong , Nuh Gedik

Transition-metal dichalcogenides can be easily produced as atomically thin sheets, exhibiting the possibility to optically polarize and read out the valley pseudospin of extremely stable excitonic quasiparticles present in these 2D…

The valley dependent optical selection rules in recently discovered monolayer group-VI transition metal dichalcogenides (TMDs) make possible optical control of valley polarization, a crucial step towards valleytronic applications. However,…

Mesoscale and Nanoscale Physics · Physics 2014-07-31 Rui-Lin Chu , Xiao Li , Sanfeng Wu , Qian Niu , Wang Yao , Xiaodong Xu , Chuanwei Zhang

This work investigates the feasibility of electrical valley filtering for holes in transition metal dichalcogenides. We look specifically into the scheme that utilizes a potential barrier to produce valley-dependent tunneling rates, and…

Mesoscale and Nanoscale Physics · Physics 2020-05-12 Tzu-Chi Hsieh , Mei-Yin Chou , Yu-Shu Wu

Increasing the speed limits of conventional electronics requires innovative approaches to manipulate other quantum properties of electrons besides their charge. An alternative approach utilizes the valley degree of freedom in…

Mesoscale and Nanoscale Physics · Physics 2023-03-29 A. O. Slobodeniuk , P. Koutenský , M. Bartoš , F. Trojánek , P. Malý , T. Novotný , M. Kozák

Optical selection rule fundamentally determines the optical transition between energy states in a variety of physical systems from hydrogen atoms to bulk crystals such as GaAs. It is important for optoelectronic applications such as lasers,…

Materials Science · Physics 2016-04-01 Jun Xiao , Ziliang Ye , Ying Wang , Hanyu Zhu , Yuan Wang , Xiang Zhang

In this letter we study the valley degeneracy splitting of the transition-metal dichalcogenides monolayer by first-principles calculations. The local magnetic moments are introduced into the system when the transition-metal atoms are…

Materials Science · Physics 2016-09-06 Xiaofang Chen , Liangshuai Zhong , Xiao Li , Jingshan Qi

In monolayer transition metal dichalcogenides time-reversal symmetry, combined with space-inversion symmetry, defines the spin-valley degree of freedom. As such, engineering and control of time-reversal symmetry by optical or magnetic…

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