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Reducible oxides are widely used catalyst supports that can increase oxidation reaction rates by transferring their lattice oxygen at the metal-support interface. The interfacial oxidation process is typically described in terms of a…

Materials Science · Physics 2021-04-05 Joshua L. Vincent , Peter A. Crozier

An electrode contact-related mechanism for the operational instability of organic electronic devices is proposed and confirmed via observation of a water-induced change in charge-injection barrier eights at the…

Applied Physics · Physics 2020-01-28 Ryo Nouchi

Metal-organic molecular adsorbates on metallic surfaces offer the potential to both generate materials for future (spin-)electronics applications as well as a better fundamental understanding of molecule-substrate interaction, provided that…

Materials Science · Physics 2024-09-17 A. Eschenlohr , R. Shi , J. Chen , P. Zhou , U. Bovensiepen , W. Hübner , G. Lefkidis

In complex transition metal oxide heterostructures of physically dissimilar perovskite compounds, interface phenomena can lead to novel physical properties not observed in either of their constituents. This remarkable feature opens new…

Strongly Correlated Electrons · Physics 2011-12-30 Natalia Pavlenko , Thilo Kopp

We study the dipole layer formed at metal-organic interfaces by means of first-principles calculations. Interface dipoles are monitored by calculating the work function change of Au, Ag, Al, Mg and Ca surfaces upon adsorption of a monolayer…

Materials Science · Physics 2010-03-05 Paul C. Rusu , Gianluca Giovannetti , Christ Weijtens , Reinder Coehoorn , Geert Brocks

The electromagnetic properties of an extremely thin metallic checkerboard drastically change from resonant reflection (transmission) to resonant transmission (reflection) when the local electrical conductivity at the interconnection points…

A central goal of modern materials physics and nanoscience is control of materials and their interfaces to atomic dimensions. For interfaces between polar and non-polar layers, this goal is thwarted by a polar catastrophe that forces an…

Materials Science · Physics 2007-05-23 Naoyuki Nakagawa , Harold Y. Hwang , David A. Muller

The fabrication of novel soft materials is an important scientific and technological challenge. We investigate the response of magnetic ellipsoidal particles adsorbed at fluid-fluid interfaces to external magnetic fields. By exploiting…

Soft Condensed Matter · Physics 2014-10-29 Gary B. Davies , Timm Krueger , Peter V. Coveney , Jens Harting , Fernando Bresme

The perpendicular magnetic anisotropy at the Co/oxide interface in Pt/Co/MOx (MOx = MgOx, AlOx, TbOx) was modified by an electric field using a 10 nm-thick ZrO2 as a solid electrolyte. The large voltage-driven modification of interfacial…

Mesoscale and Nanoscale Physics · Physics 2021-01-04 Aymen Fassatoui , Jose Pena Garcia , Jan Vogel , Laurent Ranno , Anne Bernand-Mantel , Hélène Béa , Sergio Pizzini , Stefania Pizzini

Colour printing based on metallic or dielectric nanostructures has revolutionized colour science due to its unprecedented subwavelength resolution. Evidently, the evolution towards the active control of such structural colours with smart…

Two-dimensional organic porous networks (2DOPNs) have opened new vistas for tailoring the physicochemical characteristics of metallic surfaces. These typically chemically bound nanoporous structures act as periodical quantum wells leading…

In metal/oxide heterostructures, rich chemical, electronic, magnetic and mechanical properties can emerge from interfacial chemistry and structure. The possibility to dynamically control interface characteristics with an electric field…

Materials Science · Physics 2015-06-22 Uwe Bauer , Lide Yao , Satoru Emori , Harry L. Tuller , Sebastiaan van Dijken , Geoffrey S. D. Beach

The interface between liquid water and the Pt(111) metal surface is characterized structurally and thermodynamically via reactive molecular dynamics (MD) simulations within the ReaxFF framework. The formation of a distinct buckled adsorbate…

Chemical Physics · Physics 2021-03-19 Christoph Karsten Jung , Laura Braunwarth , Andrey Sinyavskiy , Timo Jacob

Designing molecular organic semiconductors with distinct frontier orbitals is key for the development of devices with desirable properties. Generating defined organic nanostructures with atomic precision can be accomplished by on-surface…

Charge carrier injection performed in Pr0.7Ca0.3MnO3 (PCMO) hetero-structure junctions exhibits stable without electric fields and dramatic changes in both resistances and interface barriers, which are entirely different from behaviors of…

Strongly Correlated Electrons · Physics 2009-11-13 Guangcheng Xiong , Yuansha Chen , Liping Chen , Guijun Lian

We perform first-principles density functional calculations to elucidate structural, electronic and magnetic properties at the interface of \ce{(0001)Cr2O3-(111)Pt} bilayers. This investigation is motivated by the fact that, despite the…

Materials Science · Physics 2024-05-09 Marlies Reher , Nicola A. Spaldin , Sophie F. Weber

Metasurfaces are artificial thin materials that achieve optical thickness through thin geometrical structure. This feature of metasurfaces results in unprecedented benefits for enhancing the performance of optoelectronic devices. In this…

Optics · Physics 2023-08-14 Ryosuke Nakayama , Sohei Saito , Takuo Tanaka , Wakana Kubo

The electronic properties of interfaces between two different solids can differ strikingly from those of the constituent materials. For instance, metallic conductivity, and even superconductivity, have been recently discovered at interfaces…

Materials Science · Physics 2009-11-13 H. Dias Alves , A. S. Molinari , H. Xie , A. F. Morpurgo

An interface modification of LCMO-BTO superlattices was found to massively influence magnetic and magnetotransport properties. Moreover it determines the crystal structure of the manganite layers, changing it from orthorhombic (Pnma) for…

Strongly Correlated Electrons · Physics 2013-05-29 K. Gehrke , V. Moshnyaga , O. I. Lebedev , D. Kirilenko , G. Van Tendeloo , K. Samwer

Chemical interactions between two surfaces in contact play a crucial role in determining the mechanical and tribological behavior of solid interfaces. These interactions can be quantified via adhesion energy, that is a measure of the…