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From the high vibrational dipolar strength offered by molecular liquids, we demonstrate that a molecular vibration can be ultra-strongly coupled to multiple IR cavity modes, with Rabi splittings reaching $24\%$ of the vibration frequencies.…

It is usually considered that the spectrum of an optical cavity coupled to an atomic medium does not exhibit a normal-mode splitting unless the system satisfies the strong coupling condition, meaning the Rabi frequency of the coherent…

Quantum Physics · Physics 2017-01-06 Y. -H. Lien , G. Barontini , M. Scheucher , M. Mergenthaler , J. Goldwin , E. A. Hinds

Hybrid molecular-plasmonic nanostructures have demonstrated their potential for surface enhanced spectroscopies, sensing or quantum control at the nanoscale. In this work, we investigate the strong coupling regime and explicitly describe…

Quantum Physics · Physics 2017-07-05 H. Varguet , B. Rousseaux , D. Dzsotjan , H. Jauslin , S. Guerin , G. Colas des Francs

We extend the model of exciton-plasmon materials to include a ro-vibrational structure of molecules using wave-packet propagations on electronic potential energy surfaces. The new model replaces conventional two-level emitters with more…

Mesoscale and Nanoscale Physics · Physics 2017-08-18 Maxim Sukharev , Eric Charron

Strongly coupled plasmon-exciton systems offer promising applications in nanooptics. The classification of the coupling regime is currently debated both from experimental and theoretical perspectives. We present a method to unambiguously…

Mesoscale and Nanoscale Physics · Physics 2023-07-19 Felix Stete , Wouter Koopman , Matias Bargheer

Magnons and plasmons are two very different types of collective modes, acting on the spin and charge degrees of freedom, respectively. At first sight, the formation of hybrid plasmon-magnon polaritons in heterostructures of plasmonic and…

Mesoscale and Nanoscale Physics · Physics 2023-06-05 A. T. Costa , M. I. Vasilevskiy , J. Fernández-Rossier , N. M. R. Peres

Room temperature cavity quantum electrodynamics with molecular materials in optical cavities offers exciting prospects for controlling electronic, nuclear and photonic degrees of freedom for applications in physics, chemistry and materials…

Quantum Physics · Physics 2025-01-15 Felipe Herrera , William L. Barnes

Light-matter interactions can occur when an ensemble of molecular resonators is placed in a confined electromagnetic field. In the strong coupling regime the rapid exchange of energy between the molecules and the electromagnetic field…

Mesoscale and Nanoscale Physics · Physics 2020-08-10 Philip A. Thomas , Wai Jue Tan , Henry A. Fernandez , William L. Barnes

In this technical note we calculate the strength of the expected Rabi splitting for a molecular resonance. By way of an example we focus on the molecular resonance associated with the C=O bond, specifically the stretch resonance at…

Chemical Physics · Physics 2023-07-07 William Leslie Barnes

Molecular complexes are held together via a variety of bonds, but they all share the common feature that their individual entities are in contact. In this work, we introduce and demonstrate the concept of a \textit{molecular optical bond},…

Mesoscale and Nanoscale Physics · Physics 2025-01-03 Jahangir Nobakht , André Pscherer , Jan Renger , Stephan Götzinger , Vahid Sandoghdar

The physics of electrons, photons, and their plasmonic interactions changes greatly when one or more dimensions are reduced down to the nanometer scale. For example, graphene shows unique electrical, optical, and plasmonic properties, which…

Strong interactions between surface plasmons in ultra-compact nanocavities and excitons in two dimensional materials have attracted wide interests for its prospective realization of polariton devices at room temperature. Here, we propose a…

Rabi-like splitting and self-referenced refractive index sensing in hybrid plasmonic-1D photonic crystal structures have been theoretically demonstrated. The coupling between Tamm plasmon and cavity photon modes are tuned by incorporating a…

Optics · Physics 2022-09-09 S. Jena , R. B. Tokas , S. Thakur , D. V. Udupa

We investigate the conditions yielding plasmon-exciton strong coupling at the single emitter level in the gap between two metal nanoparticles. A quasi-analytical transformation optics approach is developed that makes possible a thorough…

Mesoscale and Nanoscale Physics · Physics 2016-09-07 Rui-Qi Li , D. Hernangómez-Pérez , F. J. García-Vidal , A. I. Fernández-Domínguez

Peculiar ring gap modes on the surface of disk close to the metallic thin film are excited in the visible light regime. We apply plasmon hybridization method to illustrate the ring gap modes arising from the interaction between localized…

Optics · Physics 2021-02-02 Guodong Zhu , Linhong Qv , Yangzhe Guo , Yurui Fang

Achieving and controlling strong light-matter interactions in many-body systems is of paramount importance both for fundamental understanding and potential applications. In this paper we demonstrate both experimentally and theoretically how…

Mesoscale and Nanoscale Physics · Physics 2016-12-26 Pierre Fauche , Christian Gebhardt , Maxim Sukharev , Renaud A. L. Vallee

We explore theoretically how nonlocal corrections in the description of the metal affect the strong coupling between excitons and plasmons in typical examples where nonlocal effects are anticipated to be strong, namely small metallic…

Mesoscale and Nanoscale Physics · Physics 2018-01-18 Christos Tserkezis , Martijn Wubs , N. Asger Mortensen

Cooperative coupling between optical emitters and light fields is one of the outstanding goals in quantum technology. It is both fundamentally interesting for the extraordinary radiation properties of the participating emitters and has many…

Atomic Physics · Physics 2014-12-10 Christian Stehle , Claus Zimmermann , Sebastian Slama

An emitter in the vicinity of a metal nanostructure is quenched by its decay through non-radiative channels, leading to the belief in a zone of inactivity for emitters placed within $<$10nm of a plasmonic nanostructure. Here we demonstrate…

We present an experimental demonstration of strong coupling between a surface plasmon propagating on a planar silver substrate, and the lowest excited state of CdSe nanocrystals. Variable-angle spectroscopic ellipsometry measurements…

Materials Science · Physics 2009-12-16 D. E. Gómez , K. C. Vernon , T. J. Davis , T. L. Nguyen , P. Mulvaney