Related papers: Internal Stark effect of single-molecule fluoresce…
The interplay between the oxidation state and the optical properties of molecules plays a key role for applications in displays, sensors or molecular-based memories. The fundamental mechanisms occurring at the level of a single-molecule…
A scanning tunneling microscope (STM) can do more than atomic imaging and manipulation. Its tunneling current can also be used for the excitation of light, converting electron energy to photon energy. STM based single-molecule…
The local interaction of charges and light in organic solids is the basis of distinct and fundamental effects. We here observe, at the single molecule scale, how a focused laser beam can locally shift by hundreds-time their natural…
Two-dimensional crystals and their heterostructures unlock access to a class of photonic devices, bringing nanophotonics from the nanometer scale down to the atomic level where quantum effects are relevant. Single-photon emitters (SPEs) are…
Colloidal semiconductor quantum dots are robust emitters implemented in numerous prototype and commercial optoelectronic devices. However, active fluorescence color tuning, achieved so far by electric-field induced Stark effect, has been…
The Stark effect provides a powerful method to shift the spectra of molecules, atoms and electronic transitions in general, becoming one of the simplest and most straightforward way to tune the frequency of quantum emitters by means of a…
The optical Stark effect is a tell-tale signature of coherent light-matter interaction in excitonic systems, wherein an irradiating light beam tunes exciton transition frequencies. Here we show that, when excitons are placed in a…
Single photon emitters (SPEs) are critical building blocks needed for quantum science and technology. For practical applications, large-scale room-temperature solid-state platforms are required. Color centers in layered hexagonal boron…
An applied field can modulate optical signals by resonance shifting via the Stark effect. The optical Stark effect (OSE) uses ultrafast light in the transparency region of a material to shift resonances with speeds limited by the pulse…
Demonstrating the quantum-confined Stark effect (QCSE) in silicon nanocrystals (NCs) embedded in oxide has been rather elusive, unlike the other materials. Here, the recent experimental data from ion-implanted Si NCs is unambiguously…
Scanning tunneling microscopy (STM) can be used to detect inelastic spin transitions in magnetic nano-structures comprising only a handful of atoms. Here we demonstrate that STM can uniquely identify the electrostatic spin crossover effect,…
The influence of the tip-substrate bias induced electrical field in a scanning tunneling spectroscopy experiment on colloidal InAs nanocrystals has been studied. Calculating the Stark induced splitting of the degenerate 1P_e state…
Ionic thermoelectricity in nanochannels has received increasing attention because of its advantages such as high Seebeck coefficient and low cost. However, most studies have focused on dilute simple electrolytes that neglect the effects of…
In conventional optical Stark-shift spectroscopy, molecules are exposed to spatially homogeneous static electric fields that shift the energies of their spectral lines. These shifts are attributed to the molecular electronic properties,…
Luminescence of open-shell 3d metal complexes is often quenched due to ultrafast intersystem crossing (ISC) and cooling into a dark metal-centered excited state. We demonstrate successful activation of fluorescence from individual nickel…
We report a quantitative low-temperature Scanning Tunneling Spectroscopy (STS)study on the Ag(111) surface state over an unprecedented range of currents (50 pA to 6 $\mu$A)through which we can tune the electric field in the tunnel junction…
Spectral diffusion (SD) represents a substantial obstacle towards implementation of solid-state quantum emitters as a source of indistinguishable photons. By performing high-resolution emission spectroscopy for individual colloidal quantum…
Electrostatic force microscopy at cryogenic temperatures is used to probe the electrostatic interaction of a conductive atomic force microscopy tip and electronic charges trapped in localized states in an insulating layer on a…
We present a theoretical variational approach, based on the effective mass approximation (EMA), to study the quantum-confinement Stark effects for spherical semiconducting quantum dots in the strong confinement regime of interactive…
The interactions between the excited states of a single chromophore with static and dynamic electric fields confined to a plasmonic cavity of picometer dimensions are investigated in a joint experimental and theoretical effort. In this…