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We demonstrate optical cycling and sub-Doppler laser cooling of a cryogenic buffer-gas beam of calcium monohydride (CaH) molecules. We measure vibrational branching ratios for laser cooling transitions for both excited electronic states A…

Atomic Physics · Physics 2022-08-24 S. F. Vázquez-Carson , Q. Sun , J. Dai , D. Mitra , T. Zelevinsky

We propose a general method to cool the translational motion of molecules. Our method is an extension of single photon atomic cooling which was successfully implemented in our laboratory. Requiring a single event of absorption followed by a…

Chemical Physics · Physics 2015-05-13 Edvardas Narevicius , S. Travis Bannerman , Mark G. Raizen

Ultracold polyatomic molecules offer intriguing new opportunities in cold chemistry, precision measurements, and quantum information processing, thanks to their rich internal structure. However, their increased complexity compared to…

Chemical reactions can be surprisingly efficient at ultracold temperatures ( < 1mK) due to the wave nature of atoms and molecules. The study of reactions in the ultracold regime is a new research frontier enabled by cooling and trapping…

Atomic Physics · Physics 2017-01-16 Lee R. Liu , Jessie T. Zhang , Yichao Yu , Nicholas R. Hutzler , Yu Liu , Till Rosenband , Kang-Kuen Ni

We present an optical approach to compensating for spatially varying ac-Stark shifts that appear on atomic ensembles subject to strong optical control or trapping fields. The introduction of an additional weak light field produces an…

Atomic Physics · Physics 2019-03-06 Ashby P. Hilton , Christopher Perrella , Andre N. Luiten , Philip S. Light

We investigate the effect of far-off-resonant trapping light on ultracold bosonic RbCs molecules. We use kHz-precision microwave spectroscopy to measure the differential AC Stark shifts between the ground and first excited rotational levels…

Polyatomic molecules provide complex internal structures that are ideal for applications in quantum information science, quantum simulation, and precision searches for physics beyond the Standard Model. A key feature of polyatomic molecules…

Laser cooling to sub-Doppler temperatures by optical molasses is thought to be inhibited in atoms with unresolved, near-degenerate hyperfine structure in the excited state. We demonstrate that such cooling is possible in one to three…

Atomic Physics · Physics 2014-03-24 Paul Hamilton , Geena Kim , Trinity Joshi , Biswaroop Mukherjee , Daniel Tiarks , Holger Müller

Polyatomic molecules are projected to be powerful tools in searches for physics beyond the Standard Model (BSM), including new CP-violating (CPV) interactions and ultralight dark matter (UDM) particles. Certain degrees of freedom present in…

The development of the magneto-optical trap revolutionized the fields of atomic and quantum physics by providing a simple method for the rapid production of ultracold, trapped atoms. A similar technique for producing a diverse set of dense,…

Atomic Physics · Physics 2014-04-17 Matthew T. Hummon , Mark Yeo , Benjamin K. Stuhl , Alejandra L. Collopy , Yong Xia , Jun Ye

In this paper, we use steady-state measurements to obtain evidence of radiation trapping in an optically thick a cloud of cold rubidium atoms. We investigate the fluorescence properties of our sample, pumped on opened transitions. The…

Atomic Physics · Physics 2015-06-11 Quentin Baudouin , Nicolas Mercadier , Robin Kaiser

We consider a laser cooling and trapping of alkaline-earth and similar atoms in a bichromatic field resonant to a closed optical transition $^1S_0 \to \, ^1P_1$ or $^1S_0 \to \, ^3P_1$. It is shown that new kinetic effects emerge compared…

Atomic Physics · Physics 2026-03-05 O. N. Prudnikov , V. I. Yudin , R. Ya. Ilenkov , A. V. Taichenachev

Trapping ultracold molecules in conservative traps is essential for applications -- such as quantum state-controlled chemistry, quantum simulations, and quantum information processing. These applications require high densities or…

Atomic Physics · Physics 2022-11-29 Juliana J. Park , Yu-Kun Lu , Alan O. Jamison , Wolfgang Ketterle

Femtosecond coherent multidimensional spectroscopy is demonstrated for an ultracold gas. For this, a setup for phase modulation spectroscopy is used to probe the $3^2\mathrm{S}_{1/2} - 2^2\mathrm{P}_{1/2, 3/2}$ transition in an 800…

Atomic Physics · Physics 2023-01-16 Friedemann Landmesser , Tobias Sixt , Katrin Dulitz , Lukas Bruder , Frank Stienkemeier

Controlling the internal degrees of freedom is a key challenge for applications of cold and ultracold molecules. Here, we demonstrate rotational-state cooling of trapped methyl fluoride molecules (CH3F) by optically pumping the population…

We report a magneto-optical trap of strontium monohydroxide (SrOH) containing 2000(600) molecules at a temperature of 1.2(3) mK. The lifetime is 91(9) ms, which is limited by decay to optically unaddressed vibrational states. This provides…

Laser cooling is a powerful method to control molecules for applications in precision measurement, as well as quantum information, many-body physics, and fundamental chemistry. However, many optically-active metal centers in valence states…

Atomic Physics · Physics 2019-08-05 Matthew J. O'Rourke , Nicholas R. Hutzler

Diatomic molecules are promising systems for quantum science applications due to their complex energy structures and strong dipole-dipole interactions. Achieving ultracold temperatures is essential for these applications, but the complexity…

Atomic Physics · Physics 2025-11-21 Dongkyu Lim , Eunmi Chae

Ultracold molecular gases are promising as an avenue to rich many-body physics, quantum chemistry, quantum information, and precision measurements. This richness, which flows from the complex internal structure of molecules, makes the…

Atomic Physics · Physics 2015-06-18 A. M. Jayich , A. C. Vutha , M. T. Hummon , J. V. Porto , W. C. Campbell

Ultracold ground state dipolar 40K-87Rb molecules have recently been produced in a loose harmonic trap by employing a magnetic field sweep across a Feshbach resonance followed by stimulated Raman adiabatic passage [K.-K. Ni et al., Science…