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People are well aware that, inherently, certain small-scale nonchaotic particle movements are not governed by thermodynamics. Usually, such phenomena are studied by kinetic theory and their energy properties are considered "trivial". In…

Statistical Mechanics · Physics 2025-08-05 Yu Qiao , Zhaoru Shang

Non-equilibrium processes in Schottky systems generate by projection onto the equilibrium subspace reversible accompanying processes for which the non-equilibrium variables are functions of the equilibrium ones. The embedding theorem which…

Statistical Mechanics · Physics 2021-07-21 Wolfgang Muschik

We establish the fluctuation theorem in the presence of information exchange between a nonequilibrium system and other degrees of freedom such as an observer and a feedback controller, where the amount of information exchange is added to…

Statistical Mechanics · Physics 2015-06-05 Takahiro Sagawa , Masahito Ueda

Understanding nonequilibrium systems and the consequences of irreversibility for the system's behavior as compared to the equilibrium case, is a fundamental question in statistical physics. Here, we investigate two types of nonequilbrium…

Statistical Mechanics · Physics 2020-10-26 Thomas Martynec , Sabine H. L. Klapp , Sarah A. M. Loos

Stochastic thermodynamics as reviewed here systematically provides a framework for extending the notions of classical thermodynamics like work, heat and entropy production to the level of individual trajectories of well-defined…

Statistical Mechanics · Physics 2015-06-05 Udo Seifert

For macroscopic systems, the second law of thermodynamics establishes an inequality between the amount of work performed on a system in contact with a thermal reservoir, and the change in its free energy. For microscopic systems, this…

Statistical Mechanics · Physics 2010-02-08 Eliran Boksenbojm , Bram Wynants , Christopher Jarzynski

Thermodynamics is based on the notions of energy and entropy. While energy is the elementary quantity governing physical dynamics, entropy is the fundamental concept in information theory. In this work, starting from first principles, we…

Statistical Mechanics · Physics 2017-10-25 Bernhard Altaner

Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…

Statistical Mechanics · Physics 2025-10-31 O. B. Ericok , J. K. Mason

The definition of nonequilibrium entropy is provided for the general nonequilibrium processes by connecting thermodynamics with statistical physics, and the principle of entropy increment in the nonequilibrium processes is also proved in…

Data Analysis, Statistics and Probability · Physics 2007-05-23 Xiaochun Mei

We generalize the second law of thermodynamics in its maximum work formulation for a nonequilibrium initial distribution. It is found that in an isothermal process, the Boltzmann relative entropy (H-function) is not just a Lyapunov function…

Statistical Mechanics · Physics 2015-05-13 H. -H. Hasegawa , J. Ishikawa , K. Takara , D. J. Driebe

Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…

Quantum Physics · Physics 2026-03-26 Gian Paolo Beretta

We assume that markovian dynamics on a finite graph enjoys a gauge symmetry under local scalings of the probability density, derive the transformation law for the transition rates and interpret the thermodynamic force as a gauge potential.…

Statistical Mechanics · Physics 2015-05-30 Matteo Polettini

The second law of nonequilibrium thermodynamics within the open system paradigm (a small system coupled to one or multiple baths) is derived. This is done by showing positivity of entropy production for arbitrary Hamiltonian dynamics for a…

Statistical Mechanics · Physics 2020-08-28 Philipp Strasberg

The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

We consider the entropy production of a strongly coupled bipartite system. The total entropy production can be partitioned into various components, which we use to define local versions of the Second Law that are valid without the usual…

Statistical Mechanics · Physics 2022-09-29 Gavin E. Crooks , Susanne E. Still

The problem of estimating entropy production from incomplete information in stochastic thermodynamics is essential for theory and experiments. Whereas a considerable amount of work has been done on this topic, arguably, most of it is…

Statistical Mechanics · Physics 2024-12-17 Pedro E. Harunari , Carlos E. Fiore , Andre C. Barato

We proved when random-variable fluctuations obey the central limit theorem the equality of the uncertainty relation corresponds to the thermodynamic equilibrium state. The inequality corresponds to the thermodynamic non-equilibrium state.…

Quantum Physics · Physics 2007-05-23 You-gang Feng

There is a long-standing question as to whether and to what extent it is possible to describe nonequilibrium systems in stationary states in terms of global thermodynamic functions. The positive answers have been obtained only for…

Statistical Mechanics · Physics 2022-11-30 Robert Hołyst , Karol Makuch , Anna Maciołek , Paweł J. Żuk

The thermodynamics is studied with the thermodynamic parameter of the lifetime, first-passage time, generalizing the equilibrium thermodynamics. Various ways of describing several stationary nonequilibrium states in the system are…

Statistical Mechanics · Physics 2019-10-21 V. V. Ryazanov

We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…

Statistical Mechanics · Physics 2011-06-13 P. D. Gujrati