Related papers: The C60:C60+ ratio in diffuse and translucent inte…
The C60 molecule has been recently detected in a wide range of astrophysical environments through its four active intramolecular vibrational modes (T1u) near 18.9, 17.4, 8.5, and 7.0 microns. The strengths of the mid-infrared emission bands…
Buckminsterfullerene (C60) was recently detected through its infrared emission bands in the interstellar medium (ISM), including in the proximity of massive stars, where physical conditions could favor the formation of the cationic form,…
The Diffuse Interstellar Bands (DIBs) are absorption features seen in the spectra of astronomical objects, that arise in the interstellar medium. Today more than 500 DIBs have been observed mostly in the optical and near-infrared…
The laboratory gas phase spectrum recently published by Campbell et al. has reinvigorated attempts to confirm the presence of the C$_{60}^+$ cation in the interstellar medium, thorough an analysis of the spectra of hot, reddened stars. This…
In the early 90s, C60+ was proposed as the carrier of two diffuse interstellar bands (DIBs) at 957.7 and 963.2 nm, but a firm identification still awaits gas-phase spectroscopic data. Neutral C60, on the other hand, was recently detected…
We present here the 7.0-8.7 micron spectrum of the bright reflection nebula NGC 7023. Our observations are made with the Short Wavelength Spectrometer (SWS) on the European satellite Infrared Space Observatory (ISO). The vibrational bands…
In 2015, Campbell et al. (Nature 523, 322) presented spectroscopic laboratory gas phase data for the fullerene cation, C$_{60}^+$, that coincide with reported astronomical spectra of two diffuse interstellar band (DIB) features at 9633 and…
We present very high signal-to-noise ratio absorption-line observations of CN and CH+ along 13 lines of sight through diffuse molecular clouds. The data are examined to extract precise isotopologic ratios of 12CN/13CN and 12CH+/13CH+ in…
High quality archival spectra of interstellar absorption from C I toward 9 stars, taken with the Goddard High Resolution Spectrograph on the Hubble Space Telescope, were analyzed. Our sample was supplemented by two sight lines, 23 Ori and…
Based on gas-phase laboratory spectra at 6 K, Campbell et al. (2015) confirmed that the diffuse interstellar bands (DIBs) at 9632.7 and 9577.5A are due to absorption by the fullerene ion C60+. They also reported the detection of two other,…
Emission of fullerenes in their infrared vibrational bands has been detected in space near hot stars. The proposed attribution of the diffuse interstellar bands at 9577 and 9632 \AA\ to electronic transitions of the buckminsterfullerene…
We present high-resolution (FWHM ~ 0.3-1.5 km/s) spectra of interstellar Ca I absorption toward 30 Galactic stars. Comparisons of the column densities of Ca I, Ca II, K I, and other species -- for individual components identified in the…
The nature of the Local Interstellar Cloud (LIC) is highly constrained by the combination of in situ heliospheric and line-of-sight data towards nearby stars. We present a new interpretation of the LIC components of the absorption line data…
Due to recent advances in laboratory spectroscopy, the first optical detection of a very large molecule has been claimed in the diffuse interstellar medium (ISM): C60+ (ionized Buckminsterfullerene). Confirming the presence of this molecule…
Using archival, high-resolution far-ultraviolet HST/STIS spectra of 34 Galactic O and B stars, we measure CI column densities and compare them with measurements from the literature of CO and H_2 with regard to understanding the presence of…
We have observed that C$_{60}^+$ ions isolated in cryogenic matrixes show pronounced near-IR photoluminescence upon excitation in the near-IR range. By contrast UV photoexcitation does not lead to measurable luminescence. After the recent…
Diffuse interstellar clouds show large abundances of H_3^+ which can be maintained only by a high ionization rate of H_2. Cosmic rays are the dominant ionization mechanism in this environment, so the large ionization rate implies a high…
Recent advances in laboratory spectroscopy lead to the claim of ionized Buckminsterfullerene (C60+) as the carrier of two diffuse interstellar bands (DIBs) in the near-infrared. However, irrefutable identification of interstellar C60+…
We report the first detection of C$^{15}$N in diffuse molecular gas from a detailed examination of CN absorption lines in archival VLT/UVES spectra of stars probing local diffuse clouds. Absorption from the C$^{15}$N isotopologue is…
Ionized carbon is the main gas-phase reservoir of carbon in the neutral diffuse interstellar medium and its 158 micron fine structure transition [CII] is the most important cooling line of the diffuse interstellar medium (ISM). We combine…