Related papers: Successive H-atom addition to solid OCS on compact…
Hydroxyl ($\rm OH$) is known to form efficiently in cold gas ($T\sim 100$K) along with the molecule $\rm H_2$ and can be used as an efficient tracer of the diffuse molecular gas in the interstellar medium (ISM). Using a simple formalism…
Formation of interstellar complex organic molecules is currently thought to be dominated by the barrierless coupling between radicals on the interstellar icy grain surfaces. Previous standard DFT results on the reactivity between CH$_3$ and…
Interstellar formamide (NH2CHO) has recently attracted significant attention due to its potential role as a molecular building block in the formation of precursor biomolecules relevant for the origin of life. Its formation, whether on the…
Aims. We present a new sub-grid model, HYACINTH -- HYdrogen And Carbon chemistry in the INTerstellar medium in Hydro simulations -- for computing the non-equilibrium abundances of ${\rm H_2}$ and its carbon-based tracers, namely ${\rm CO}$,…
Atomic carbon ([CI]) is a key species in the carbon chemistry of the interstellar medium (ISM). Using the Submillimeter Wave Astronomy Satellite (SWAS), we conducted a [CI]($^3$P$_1$--$^3$P$_0$) 492 GHz survey covering approximately 4…
This review paper summarizes the state-of-the-art in laboratory based interstellar ice chemistry. The focus is on atom addition reactions, illustrating how water, carbon dioxide and methanol can form in the solid state at astronomically…
Ice chemistry in the dense, cold interstellar medium (ISM) is probably responsible for the formation of interstellar complex organic molecules (COMs). Recent laboratory experiments performed at T=4 K have shown that irradiation of CO:N2 ice…
Helium rich subdwarf O stars (sdOs) are hot compact stars in a pre-white dwarf evolutionary state. Most of them have effective temperatures and surface gravities in the range Teff = 40,000-50,000 K and log g = 5.5-6.0. Their atmospheres are…
We present numerical computations and analytic scaling relations for interstellar ion-molecule gas phase chemistry down to very low metallicities ($ 10^{-3} \times$ solar), and/or up to high driving ionization rates. Relevant environments…
Condensation of H 2 in the interstellar medium (ISM) has long been seen as a possibility, either by deposition on dust grains or thanks to a phase transition combined with self-gravity. H 2 condensation might explain the observed low…
We use a 1D thermochemical and photochemical kinetics model to predict the disequilibrium stratospheric chemistries of warm and hot Jupiters (800 < T < 1200 K). Thermal chemistry and vertical mixing are generally more important than…
The Herschel Space Observatory's recent detections of water vapor in the cold, dense cloud L1544 allow a direct comparison between observations and chemical models for oxygen species in conditions just before star formation. We explain a…
Sulfur-bearing molecules are central to interstellar chemistry, yet their observed abundances in the gas phase remain far below cosmic expectations in dense interstellar regions. Mixed N-S-O species such as thionylimide (HNSO) are…
The rotational transitions of carbon monoxide (CO) are the primary means of investigating the density and velocity structure of the molecular interstellar medium. Here we study the lowest four rotational transitions of CO towards…
The composition of the protoplanetary disc is linked to the composition of the host star, where a higher overall metallicity of the host star provides more building blocks for planets. However, most planet formation simulations only link…
The reaction between atomic oxygen and molecular hydrogen is an important one in astrochemistry as it regulates the abundance of the hydroxyl radical and serves to open the chemistry of oxygen in diverse astronomical environments. However,…
AIM: We have recently developed a microscopic Monte Carlo approach to study surface chemistry on interstellar grains and the morphology of ice mantles. The method is designed to eliminate the problems inherent in the rate-equation formalism…
After a quarter century since the detection of the last interstellar carboxylic acid, acetic acid (CH$_3$COOH), we report the discovery of a new one, the cis-trans form of carbonic acid (HOCOOH), toward the Galactic Center molecular cloud…
Water is a key ingredient for the emergence of life as we know it. Yet, its destruction and reformation in space remains unprobed in warm gas. Here, we detect the hydroxyl radical (OH) emission from a planet-forming disk exposed to external…
The presence of SiS in space seems to be restricted to a few selected types of astronomical environments. It is long known to be present in circumstellar envelopes around evolved stars and it has also been detected in a handful of…