Related papers: Successive H-atom addition to solid OCS on compact…
The chemical inventory of protoplanetary midplanes is the basis for forming planetesimals. Among them, solid-state reactions based on CO/CO$_2$ toward molecular complexity on interstellar dust grains have been studied in theoretical and…
The CH$_3$O and CH$_2$OH radicals can be important precursors of complex organic molecules (COMs) in interstellar dust. The COMs presumably originating from these radicals were abundantly found in various astronomical objects. Because each…
A prevailing theory for the interstellar production of complex organic molecules (COMs) involves formation on warm dust-grain surfaces, via the diffusion and reaction of radicals produced through grain-surface photodissociation of stable…
The formation of molecular hydrogen (H$_2$) and carbon monoxide (CO) is sensitive to the volume and column density distribution of the turbulent interstellar medium. In this paper, we study H$_2$ and CO formation in a large set of…
The radicals HCO and CH$_3$ on carbon monoxide ice surfaces were simulated using density functional theory. Their binding energy on amorphous CO ice shows broad distributions, with approximative average values of 500 K for HCO and 200 K for…
Recent interstellar detections include a significant number of molecules containing vinyl (C2H3) and ethyl (C2H5) groups in their structure. For several of these molecules, there is not a clear experimental or theoretical evidence that…
Sulphur-bearing species play crucial roles in interstellar chemistry, yet their precise characterisation remains challenging. Here, we present laboratory experiments aimed at extending the high-resolution spectroscopy of protonated carbonyl…
Hydrogen sulfide (H2S) is a prototype molecular system and a sister molecule of water. The phase diagram of solid H2S at high pressures remains largely unexplored arising from the challenges in dealing with the looser S-H bond and larger…
The properties of the first-discovered interstellar object (ISO), 1I/2017 (`Oumuamua), differ from both Solar System asteroids and comets, casting doubt on a protoplanetary disk origin. In this study, we investigate the possibility that it…
Context: In the laboratory, hydrogen peroxide (HOOH) was proven to be an intermediate product in the solid-state reaction scheme that leads to the formation of water on icy dust grains. When HOOH desorbs from the icy grains, it can be…
We perform a complete census of molecular ions with an abundance larger than 1e-10 in the protostellar shock L1157-B1 by means of an unbiased high-sensitivity survey obtained with the IRAM-30m and Herschel/HIFI. By means of an LVG radiative…
In recent years the chemistry of sulfur in the interstellar medium has experienced a renewed interest due to the detection of a large variety of molecules containing sulfur. Here we report the first identification in space of a new…
Nearby spiral galaxies show an extremely tight correlation between tracers of molecular hydrogen (H_2) in the interstellar medium (ISM) and tracers of recent star formation, but it is unclear whether this correlation is fundamental or…
Context. Recent Monte Carlo simulations and laboratory studies of interstellar ices have proposed an alternative pathway involving the radical-molecule H-atom abstraction reaction in the overall mechanism of methanol (CH3OH) formation in…
UV irradiation of simple ices is proposed to efficiently produce complex organic species during star- and planet-formation. Through a series of laboratory experiments, we investigate the effects of the H2O concentration, the dominant ice…
The formation of water molecules from the reaction between ozone (O3) and D-atoms is studied experimentally for the first time. Ozone is deposited on non-porous amorphous solid water ice (H2O), and D-atoms are then sent onto the sample held…
Methanol (CH3OH) is thought to form on interstellar ice dust via successive hydrogenation reactions. The reaction between CH3 and OH radicals could also conceivably generate methanol at temperatures above approximately 20 K, at which…
Water (H2O) ice is ubiquitous component of the universe, having been detected in a variety of interstellar and Solar System environments where radiation plays an important role in its physico-chemical transformations. Although the radiation…
Investigating how formamide forms in the interstellar medium is a hot topic in astrochemistry, which can contribute to our understanding of the origin of life on Earth. We have constructed a QM/MM model to simulate the hydrogenation of…
Context. Carbon monoxide (CO) is arguably the most important molecule for interstellar organic chemistry. Its binding to amorphous solid water (ASW) ice regulates both diffusion and desorption processes. Accurately characterizing the CO…