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Metal halide perovskite semiconductors have outstanding optoelectronic properties. Although these perovskites are defect-tolerant electronically, defects hamper their long-term stability and cause degradation. Density functional theory…

Materials Science · Physics 2021-09-02 Haibo Xue , Geert Brocks , Shuxia Tao

Accelerating the experimental cycle for new materials development is vital for addressing the grand energy challenges of the 21st century. We fabricate and characterize 75 unique halide perovskite-inspired solution-based thin-film materials…

Like single perovskites, halide double perovskites (HDP) have truly emerged as efficient optoelectronic materials since they display superior stability and are free of toxicity. However, challenges still exist due to either wide and…

Materials Science · Physics 2023-09-13 Mayank Gupta , Susmita Jana , B. R. K. Nanda

First principles study of structural, elastic, and electronic properties of the cubic perovskitetype BaHfO$_3$ has been performed using the plane wave ultrasoft pseudo-potential method based on density functional theory with revised…

Materials Science · Physics 2008-09-23 Hongsheng Zhao , Aimin Chang , Yunlan Wang

Antiperovskite derivatives have recently emerged as promising lead-free alternatives to halide perovskites for optoelectronic applications. Here, using a comprehensive first-principles calculations including density functional perturbation…

Materials Science · Physics 2026-04-03 Surajit Adhikari , Aftab Alam , Priya Johari

Metal halide perovskites (MHPs) combine extraordinary optoelectronic properties with chemical and mechanical properties not found in their semiconductor counterparts. For instance, they exhibit optoelectronic properties on par with…

Applied Physics · Physics 2023-04-20 Bryan A. Rosales , Kelly Schutt , Joseph J. Berry , Lance M. Wheeler

The ability to extract material parameters of perovskite from quantitative experimental analysis is essential for rational design of photovoltaic and optoelectronic applications. However, the difficulty of this analysis increases…

Chalcogenide perovskites have emerged as non-toxic and stable photovoltaic materials, acting as an alternative to lead halide hybrid perovskites having similar optoelectronic properties. In the present work, we report the electronic and…

Materials Science · Physics 2021-06-03 Manish Kumar , Arunima Singh , Deepika Gill , Saswata Bhattacharya

The need for faster and more miniaturised electronics is challenging scientists to develop novel forms of electronics based on quantum degrees of freedom different from electron charge. In this fast-developing field, often referred to as…

Materials Science · Physics 2023-03-10 Mario Cuoco , Angelo Di Bernardo

Owing to the energy shortages and various severe adverse effects of traditional fossil fuel power generation mechanisms, photovoltaic and thermoelectric materials are considered as the potential candidates for building non-traditional,…

Materials Science · Physics 2022-08-09 Syed Zuhair Abbas Shah , Shanawer Niaz , Tabassum Nasir , James Sifuna

The perovskite oxides are known to be susceptible to structural distortions over a long wavelength when compared to their parent cubic structures. From an ab initio simulation perspective, this requires accurate calculations including many…

Computational Physics · Physics 2022-02-16 Jack S. Baker , Tsuyoshi Miyazki , David R. Bowler

The reliability with Machine Learning (ML) techniques in novel materials discovery often depend on the quality of the dataset, in addition to the relevant features used in describing the material. In this regard, the current study presents…

Materials Science · Physics 2023-12-19 Ericsson Tetteh Chenebuah , David Tetteh Chenebuah

Transition-metal perovskite oxides exhibit moderately correlated metallic phases, several of which exhibit a $T^2$ resistivity scaling up to temperatures far exceeding the regime where Fermi-liquid electron-electron scattering is expected…

Materials Science · Physics 2026-04-02 Jennifer Coulter , Fabian B. Kugler , Harrison LaBollita , Antoine Georges , Cyrus E. Dreyer

Organic molecular crystals are ideally placed to become next-generation piezoelectric materials due to their diverse chemistries that can be used to engineer tailor-made solid-state assemblies. Using crystal engineering principles, and…

Materials Science · Physics 2024-12-11 Shubham Vishnoi , Geetu Kumari , Robert Guest , Pierre-André Cazade , Sarah Guerin

It has been shown that oxide ceramics containing multiple transition and/or rare-earth elements in equimolar ratios have a strong tendency to crystallize in simple single phase structures, stabilized by the high configurational entropy. In…

Materials Science · Physics 2019-03-27 Ralf Witte , Abhishek Sarkar , Robert Kruk , Benedikt Eggert , Richard A. Brand , Heiko Wende , Horst Hahn

Chalcogenide perovskites such as BaZrS3 are promising candidates for next generation optoelectronics such as photodetectors and solar cells. Compared to widely studied polycrystalline thin films, single crystals of BaZrS3 with minimal…

The performance of perovskite solar cells recently exceeded 15% solar-to-electricity conversion efficiency for small-area devices. The fundamental properties of the active absorber layers, hybrid organic-inorganic perovskites formed from…

Materials Science · Physics 2013-10-11 Federico Brivio , Alison B. Walker , Aron Walsh

In this work, theoretical investigation of cubic Pm-3m phase RbGeO3 germanate perovskite using plain wave basis, density function theory (DFT) is conducted. DFT modelling calculations, clearly shows that this perovskite exhibits…

Materials Science · Physics 2023-10-31 Abhay Singh

Double perovskite halides are emerging as promising materials for a wide range of applications, particularly in renewable energy technologies such as solar cell devices, thereby contributing to addressing global energy demands. In this…

Materials Science · Physics 2026-04-10 Huda A. Alburaih , Sikander Azam , N. A. Noor , A. Laref , Sohail Mumtaz

Prediction of the electronic structure of functional materials is essential for the engineering of new devices. Conventional electronic structure prediction methods based on density functional theory (DFT) suffer from not only high…

Materials Science · Physics 2023-01-10 Junfei Zhang , Yueqi Li , Xinbo Zhou