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Halide perovskites have emerged as one of the most interesting materials for optoelectronic applications due to their favorable properties, such as defect-tolerance and long charge carrier lifetimes, which are attributed to their dynamic…

Materials Science · Physics 2023-11-20 Julia Wiktor , Erik Fransson , Dominik Kubicki , Paul Erhart

A new superconductor (Na0.25K0.45)Ba3Bi4O12, having an A-site-ordered double perovskite structure, with a maximum Tc ~ 27 K has very recently been discovered through hydrothermal synthesis at 593 K. The structural, elastic, electronic, and…

Perovskite oxides have been extensively studied for their wide range of compositions and structures, as well as their valuable properties for various applications. Expanding from single perovskite ABO$_3$ to double perovskite…

Materials Science · Physics 2024-03-01 Yateng Wang , Bianca Baldassarri , Jiahong Shen , Jiangang He , Chris Wolverton

The outstanding optoelectronics and photovoltaic properties of metal halide perovskites, including high carrier motilities, low carrier recombination rates, and the tunable spectral absorption range are attributed to the unique electronic…

Materials Science · Physics 2020-08-14 Shuxia Tao , Xi Cao , Peter Bobbert

The spectacular performance of halide perovskites in optoelectronic devices is rooted in their tolerance to defects. Previous studies showed that defects in these materials generate shallow electronic states. However, how these shallow…

Materials Science · Physics 2025-05-20 Frederico P. Delgado , Frederico Simões , Leeor Kronik , Waldemar Kaiser , David A. Egger

Double perovskites R2NiMnO6 (R= Rare earth element) (RNMO) are a significant class of materials owing to their Multifunctional properties with structural modifications. In particular, multifunctional double perovskite oxides La2NiMnO6…

Materials Science · Physics 2023-04-18 Suresh Chandra Baral , P. Maneesha , E. G. Rini , Somaditya Sen

Lead-halide perovskites have demonstrated astonishing increases in power conversion efficiency in photovoltaics over the last decade. The most efficient perovskite devices now outperform industry-standard multi-crystalline silicon solar…

Applied Physics · Physics 2023-02-20 Yi-Teng Huang , Sean R. Kavanagh , David O. Scanlon , Aron Walsh , Robert L. Z. Hoye

Detailed structural measurements were conducted on a new perovskite, ScMnO3, and on orthorhombic LuMnO3. Complementary density functional theory (DFT) calculations were carried out, and predict that ScMnO3 possesses E-phase magnetic order…

Strongly Correlated Electrons · Physics 2015-06-19 T. Yu , T. A. Tyson , H. Y. Chen , A. M. M. Abeykoon , Y. -S. Chen , K. H. Ahn

Critical to the development of improved solid oxide fuel cell (SOFC) technology are novel compounds with high oxygen reduction reaction (ORR) catalytic activity and robust stability under cathode operating conditions. Approximately 2145…

Materials Science · Physics 2019-01-10 Ryan Jacobs , Tam Mayeshiba , John Booske , Dane Morgan

The weighted density approximation, its implementation and its application to ferroelectric materials is discussed. Calculations are presented for several perovskite oxides and related materials. In general the weighted density…

Materials Science · Physics 2009-10-31 I. I. Mazin , D. J. Singh

Perovskite materials, known for their structural versatility and multifunctional properties, continue to draw interest for advanced electronic and optoelectronic applications. In this study, we investigate the elastic and strain--engineered…

Halide perovskites have been extensively studied as materials of interest for optoelectronic applications. There is a major emphasis on ways to tailor the stability, defect behavior, electronic band structure, and optical absorption in…

Materials Science · Physics 2023-09-29 Jiaqi Yang , Arun Mannodi-Kanakkithodi

There have been a large number of papers on bismuth ferrite (BiFeO3) over the past few years, trying to exploit its room-temperature magnetoelectric multiferroic properties. Although these are attractive, BiFeO3 is not the ideal…

Perovskite materials have become ubiquitous in many technologically relevant applications, ranging from catalysts in solid oxide fuel cells to light absorbing layers in solar photovoltaics. The thermodynamic phase stability is a key…

Materials Science · Physics 2018-06-05 Wei Li , Ryan Jacobs , Dane Morgan

This work presents a machine learning approach to predict novel perovskite oxide materials in the Pr-Al-O and Pr-Sc-O compound families with the potential for photoluminescence applications. The predicted materials exhibit a large bandgap…

Materials Science · Physics 2023-06-22 Upendra Kumar , Hyeon Woo Kim , Sobhit Singh , Hyunseok Ko , Sung Beom Cho

The thermoelectric properties of halide perovskites $\mathrm{CsMI_3}$ (M=Sn and Pb) are investigated from a combination of first-principles calculations and semiclassical Boltzmann transport theory by considering both the electron and…

Materials Science · Physics 2016-05-31 San-Dong Guo , Jian-Li Wang

Wide bandgap semiconductors (WBGs) are predicted to be the potential materials for energy generation and storing. In this work, we used density functional theory (DFT) that incorporates generalized gradient approximation (GGA) and…

Building on the extensive exploration of metal oxide and metal halide perovskites, metal nitride perovskites represent a largely unexplored class of materials. We report a multi-tier computational screening of this chemical space. From a…

Materials Science · Physics 2023-09-19 Bastien F. Grosso , Daniel W. Davies , Bonan Zhu , Aron Walsh , David O. Scanlon

Lead-free perovskite materials have emerged as key players in optoelectronics, showcasing exceptional optical and electronic properties, alongside being environmentally friendly and non-toxic elements. Recently, among studied perovskite…

Materials Science · Physics 2024-11-14 Surajit Adhikari , Ayan Chakravorty , Priya Johari

Perovskite photovoltaic technologies are approaching commercial deployment, yet single junction and tandem architectures both still have significant room to improve power conversion efficiency and stability. The ability to perform rapid…