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Icy interstellar dust grains are a source of complex organic molecule (COM) production, although their formation mechanisms are debated. Laboratory experiments show that atomic C deposited onto interstellar ice analogs can react with…

Astrophysics of Galaxies · Physics 2025-10-27 Sydney A. Willis , Serge A. Krasnokutski , Nathaniel J. Morin , Robin T. Garrod

We have performed experimental investigations of methanol formation via the reactions of low energy $CH_{3}^{+}$ ions with an amorphous solid water (ASW) surface around 10 K. A newly developed experimental apparatus enabled irradiation of…

Astrophysics of Galaxies · Physics 2023-04-27 Y. Nakai , W. M. C. Sameera , K. Furuya , H. Hidaka , A. Ishibashi , N. Watanabe

Because of their importance in biological systems, in our understanding of the solar system and in other applications, seven heterocycles; furan, imidazole, pyridine, pyrimidine, pyrrole, quinoline and isoquinoline have been astronomically…

Astrophysics of Galaxies · Physics 2019-06-17 Emmanuel E. Etim , Edidiong J. Inyang , Onumashi A. Ushie , Idaresit Mbakara , Chrysanthus Andrew , Usman Lawal

Alcohol consumption has been shown to influence cardiovascular mechanisms in humans, leading to observable alterations in the plasma metabolomic profile. Regression models are commonly employed to investigate these effects, treating…

Methodology · Statistics 2024-04-18 Yifan Yang , Chixiang Chen , Hwiyoung Lee , Ming Wang , Shuo Chen

We report the first interstellar identification of protonated acetylene, C2H3+, a fundamental hydrocarbon, in the z=0.89 molecular absorber toward the gravitationally lensed quasar PKS1830-211. The molecular species is identified from clear…

Astrophysics of Galaxies · Physics 2024-01-19 S. Muller , R. Le Gal , E. Roueff , J. H. Black , A. Faure , M. Guelin , A. Omont , M. Gerin , F. Combes , S. Aalto

The interactions between jets of high-energy nuclei and nuclei of the surrounding medium are studied. Such interactions could be initiated by jets from active galactic nuclei interacting with surrounding cool clouds. The resulting nuclear…

Astrophysics · Physics 2009-10-31 M. A. Famiano , J. Vandegriff , R. N. Boyd , T. Kajino , P. Osmer

We sought to determine which are the main hydrogenation paths of acetaldehyde (CH3CHO). As a partially unsaturated molecule, CH3CHO can have links with more hydrogenated species, like ethanol (C2H5OH) or with more unsaturated ones, like…

Astrophysics of Galaxies · Physics 2025-02-26 Germán Molpeceres , Thanh Nguyen , Yasuhiro Oba , Naoki Watanabe

The first detection of gas-phase methanol in a protoplanetary disk (TW Hya) is presented. In addition to being one of the largest molecules detected in disks to date, methanol is also the first disk organic molecule with an unambiguous ice…

Complex organic molecules (COMs) have been detected in a variety of environments, including cold prestellar cores. Given the low temperature of these objects, these last detections challenge existing models. We report here new observations…

Solar and Stellar Astrophysics · Physics 2015-06-23 Charlotte Vastel , Cecilia Ceccarelli , Bertrand Lefloch , Raphael Bachiller

Glycolaldehyde is a key molecule in the formation of biologically relevant molecules such as ribose. We report its detection with the Plateau de Bure interferometer towards the Class 0 young stellar object NGC1333 IRAS2A, which is only the…

Solar and Stellar Astrophysics · Physics 2015-03-18 Audrey Coutens , Magnus V. Persson , Jes K. Jørgensen , Susanne F. Wampfler , Julie M. Lykke

Glycoaldehyde, ethylene glycol, and methyl formate are complex organic molecules that have been observed in dark molecular clouds. Because there is no efficient gas-phase route to produce these species, it is expected that a low-temperature…

Solar and Stellar Astrophysics · Physics 2020-02-12 M. A. J. Simons , T. Lamberts , H. M. Cuppen

The galaxy formation process in the $\Lambda$-Cold Dark Matter scenario can be constrained from the analysis of stars in the Milky Way's halo system. We examine the variation of chemical abundances in distant halo stars observed by the…

Despite the detection of numerous interstellar complex organic molecules (iCOMs) for decades, it is still a matter of debate whether they are synthesized in the gas-phase or on the icy surface of interstellar grains. In the past, molecular…

Chemical Physics · Physics 2022-11-22 F. Vazart , C. Ceccarelli , D. Skouteris , N. Balucani

Interstellar objects are interlopers from other planetary systems, and their volatile compositions provide a glimpse into planet formation around their host star. We present near-infrared spectra of the coma of interstellar object 3I/ATLAS…

Aqueous mixtures of 1-propanol have been investigated by high-energy synchrotron X-ray diffraction upon cooling. X-ray weighted total scattering structure factors of 6 mixtures, from 8 mol% to 89 mol% alcohol content, as well as that of…

Chemical Physics · Physics 2021-08-25 Ildikó Pethes , László Pusztai , Koji Ohara , László Temleitner

As crucial additives and intermediate, alcohols, ethers, and aldehydes play a significant role in the combustion process. However, the chemistry of NOXhydrocarbon interactions and the rate rules governing these interactions remain largely…

The coexistence curves of the liquid-liquid equilibria (LLE) for systems of 2-phenoxyethanol (2PhEE) with heptane, octane, cyclohexane, methylcyclohexane or ethylcyclohexane have been determined by the method of the critical opalescence…

At low concentrations of methanol in ethanol-methanol binary system, the molecular interactions are seen to be uniquely complex. It is observed that the ethanol aggregates are not strictly hydrogen-bonded complexes; dispersion forces also…

Chemical Physics · Physics 2016-11-21 K Nilavarasi , Thejus R Kartha , V Madhurima

Chemical polarity governs various mechanical, chemical and thermodynamic properties of dielectrics. Polar liquids have been amply studied, yet the basic mechanisms underpinning their dielectric properties remain not fully understood, as…

Chemical Physics · Physics 2020-12-15 V. G. Artemov , A. Ryzhov , E. Carlsen , P. O. Kapralov , H. Ouerdane