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The detection of a branched alkyl molecule in the high-mass star forming protocluster Sgr B2(N) permitted by the advent of ALMA revealed a new dimension of interstellar chemistry. Astrochemical simulations subsequently predicted that beyond…

Astrophysics of Galaxies · Physics 2022-06-29 A. Belloche , R. T. Garrod , O. Zingsheim , H. S. P. Müller , K. M. Menten

We report the discovery of propylene (also called propene, CH_2CHCH_3) with the IRAM 30-m radio telescope toward the dark cloud TMC-1. Propylene is the most saturated hydrocarbon ever detected in space through radio astronomical techniques.…

We report the first interstellar identification of protonated acetylene, C2H3+, a fundamental hydrocarbon, in the z=0.89 molecular absorber toward the gravitationally lensed quasar PKS1830-211. The molecular species is identified from clear…

Astrophysics of Galaxies · Physics 2024-01-19 S. Muller , R. Le Gal , E. Roueff , J. H. Black , A. Faure , M. Guelin , A. Omont , M. Gerin , F. Combes , S. Aalto

Organic molecules are widely present in the dense interstellar medium, and many have been synthesized in the laboratory on Earth under the conditions typical for an interstellar environment. Until now, however, only relatively small…

Biological Physics · Physics 2022-02-25 S. A. Krasnokutski , K. -J. Chuang , C. Jäger , N. Ueberschaar , Th. Henning

Formaldehyde is a key precursor in the formation routes of many complex organic molecules (COMs) in space. It is also an intermediate step in CO hydrogenation sequence that leads to methanol formation on the surface of interstellar grains…

Astrophysics of Galaxies · Physics 2025-02-04 A. F. Punanova , K. Borshcheva , G. S. Fedoseev , P. Caselli , D. S. Wiebe , A. I. Vasyunin

The detection of the amino acid glycine and its amine precursor methylamine on the comet 67P/Churyumov-Gerasimenko by the Rosetta mission provides strong evidence for a cosmic origin of prebiotics on Earth. How and when such complex organic…

Instrumentation and Methods for Astrophysics · Physics 2020-11-17 S. Ioppolo , G. Fedoseev , K. -J. Chuang , H. M. Cuppen , A. R. Clements , M. Jin , R. T. Garrod , D. Qasim , V. Kofman , E. F. van Dishoeck , H. Linnartz

Interstellar absorption lines up to J"=10 in the (2,0) band and up to J"=6 in the (3,0) band of the C$_2$ $A^1\Pi_u$ - $X^1\Sigma^+_g$ system are detected toward star Cernis 52 (BD+31$^o$ 640) in the Perseus molecular complex. The star lies…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-20 Susana Iglesias-Groth

Large interstellar organic molecules are potential precursors of prebiotic molecules. Their formation pathways and chemical relationships with one another and simpler molecules are therefore of great interest. In this paper, we address the…

Solar and Stellar Astrophysics · Physics 2016-03-23 Dawn M. Graninger , Olivia H. Wilkins , Karin I. Oberg

We report matched resolution, imaging spectroscopy of the CO J=3-2 line (with the IRAM Plateau de Bure millimeter interferometer) and of the H-alpha line (with LUCI at the Large Binocular Telescope)in the massive z=1.53 main-sequence galaxy…

The detection of organic molecules with increasing complexity and potential biological relevance is opening the possibility to understand the formation of the building blocks of life in the interstellar medium. One of the families of…

Astrophysics of Galaxies · Physics 2017-02-22 V. M. Rivilla , M. T. Beltrán , J. Martín-Pintado , F. Fontani , P. Caselli , R. Cesaroni

Up to date, only 6 imines have been detected in the interstellar medium. The 3-carbon imine, 2-propanimine ((CH$_3$)$_2$C=NH), is predicted to be the structural isomer with the lowest energy in the C$_3$H$_7$N group, and appears to be a…

Cyanoformaldehyde (HCOCN) molecule has recently been suspected towards the Sagittarius B2(N) by the Green Bank telescope, though a confirmation of this observation has not yet been made. In and around a star forming region, this molecule…

Astrophysics of Galaxies · Physics 2015-06-16 Ankan Das , Liton Majumdar , Sandip K. Chakrabarti , Rajdeep Saha , Sonali Chakrabarti

Carbon chains are sometimes considered as possible carriers of some diffuse interstellar bands. Spectroscopic observations in UV band carried by spectrometer STIS fed with HST, give us the possibility to detect many interstellar molecules.…

Astrophysics · Physics 2007-05-23 Marcin Dyrka , Bogdan Wszołek , Micha l Pawlikowski

Over the past five decades, radio astronomy has shown that molecular complexity is a natural outcome of interstellar chemistry, in particular in star forming regions. However, the pathways that lead to the formation of complex molecules are…

C$_2$H is a representative hydrocarbon that is abundant and ubiquitous in the interstellar medium (ISM). To study its chemical properties, we present Submillimeter Array (SMA) observations of the C$_2$H $N=3-2$ and HC$_3$N $J=30-29$…

Solar and Stellar Astrophysics · Physics 2015-08-06 Xue-Jian Jiang , Hauyu Baobab Liu , Qizhou Zhang , Junzhi Wang , Zhi-Yu Zhang , Juan Li , Yu Gao , Qiusheng Gu

We aim to detect methylamine, CH$_{3}$NH$_{2}$, in a variety of hot cores and use it as a test for the importance of photon-induced chemistry in ice mantles and mobility of radicals. Specifically, CH$_3$NH$_2$ cannot be formed from atom…

Solar and Stellar Astrophysics · Physics 2015-06-23 N. F. W. Ligterink , E. D. Tenenbaum , E. F. van Dishoeck

Proteins perform nearly all cellular functions and constitute most drug targets, making their analysis fundamental to understanding human biology in health and disease. Tandem mass spectrometry (MS$^2$) is the major analytical technique in…

Biomolecules · Quantitative Biology 2025-09-01 Hao Xu , Zhichao Wang , Shengqi Sang , Pisit Wajanasara , Nuno Bandeira

Glycolamide is a glycine isomer and also one of the simplest derivatives of acetamide (e.g., one hydrogen atom is replaced with a hydroxyl group), which is a known interstellar molecule. Using a battery of state of the art rotational…

Astrophysics of Galaxies · Physics 2020-07-29 M. Sanz-Novo , A. Belloche , J. L. Alonso , L. Kolesnikova , R. T. Garrod , S. Mata , H. S. P. Müller , K. M. Menten , Y. Gong

We present narrow-band near-infrared images of a sample of 11 Galactic planetary nebulae (PNe) obtained in the molecular hydrogen (H$_{2}$) 2.122 $\mu$m and Br$\gamma$ 2.166 $\mu$m emission lines and the $K_{\rm c}$ 2.218 $\mu$m continuum.…

Solar and Stellar Astrophysics · Physics 2018-06-13 Xuan Fang , Yong Zhang , Sun Kwok , Chih-Hao Hsia , Wayne Chau , Gerardo Ramos-Larios , Martin A. Guerrero

We report the discovery of very high latitude molecular gas in the edge-on spiral galaxy, NGC 5775. Emission from both the J=1-0 and 2-1 lines of 12CO is detected up to 4.8 kpc away from the mid-plane of the galaxy. NGC 5775 is known to…

Astrophysics · Physics 2009-11-07 S. -W. Lee , E. R. Seaquist , S. Leon , S. Garcia-Burillo , J. A. Irwin