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Reaction coordinates (RCs) are the few essential coordinates of a protein that control its functional processes, such as allostery, enzymatic reaction, and conformational change. They are critical for understanding protein function and…

Biological Physics · Physics 2024-09-02 Ao Ma , Huiyu Li

Reaction coordinates (RCs) are low-dimensional representations of complex dynamical systems that capture their long-term dynamics. In this work, we focus on the criteria of lumpability and decomposability, previously established for…

Numerical Analysis · Mathematics 2024-09-16 Zhicheng Zhang , Ling Guo , Hao Wu

Rare but critical events in complex systems, such as protein folding, chemical reactions, disease progression, and extreme weather or climate phenomena, are governed by complex, high-dimensional, stochastic dynamics. Identifying an optimal…

Chemical Physics · Physics 2026-03-04 Polina V. Banushkina , Sergei V. Krivov

Finding optimal reaction coordinates and predicting accurate kinetic rates for activated processes are two of the foremost challenges of molecular simulations. We introduce an algorithm that tackles the two problems at once: starting from a…

Statistical Mechanics · Physics 2023-10-30 Line Mouaffac , Karen Palacio-Rodriguez , Fabio Pietrucci

Identifying reaction coordinates(RCs) is an active area of research, given the crucial role RCs play in determining the progress of a chemical reaction. The choice of the reaction coordinate is often based on heuristic knowledge. However,…

Chemical Physics · Physics 2024-01-17 Abhijit Gupta

The bottleneck in enhanced sampling lies in finding collective variables (CVs) that can effectively accelerate protein conformational changes. True reaction coordinates (tRCs) that can predict the committor are considered the optimal CVs,…

Chemical Physics · Physics 2024-12-06 Huiyu Li , Ao Ma

We present flow matching for reaction coordinates (FMRC), a novel deep learning algorithm designed to identify optimal reaction coordinates (RC) in biomolecular reversible dynamics. FMRC is based on the mathematical principles of…

Machine Learning · Computer Science 2024-12-25 Mingyuan Zhang , Zhicheng Zhang , Hao Wu , Yong Wang

Reaction coordinates are widely used throughout chemical physics to model and understand complex chemical transformations. We introduce a definition of the natural reaction coordinate, suitable for condensed phase and biomolecular systems,…

Statistical Mechanics · Physics 2017-03-08 Robert T. McGibbon , Brooke E. Husic , Vijay S. Pande

Understanding kinetics including reaction pathways and associated transition rates is an important yet difficult problem in numerous chemical and biological systems especially in situations with multiple competing pathways. When these…

Computational Physics · Physics 2021-09-22 Sun-Ting Tsai , Zachary Smith , Pratyush Tiwary

The phase response curve (PRC) is an important measure representing the interaction between oscillatory elements. To understand synchrony in biological systems, many research groups have sought to measure PRCs directly from biological cells…

Quantitative Methods · Quantitative Biology 2015-08-03 Kazuhiko Morinaga , Ryota Miyata , Toru Aonishi

We consider complex dynamical systems showing metastable behavior but no local separation of fast and slow time scales. The article raises the question of whether such systems exhibit a low-dimensional manifold supporting its effective…

Dynamical Systems · Mathematics 2019-07-10 Andreas Bittracher , Péter Koltai , Stefan Klus , Ralf Banisch , Michael Dellnitz , Christof Schütte

Across many disciplines, chemical reaction networks (CRNs) are an established population model defined as a system of coupled nonlinear ordinary differential equations. In many applications, for example, in systems biology and epidemiology,…

Systems and Control · Electrical Eng. & Systems 2023-01-23 Kim G. Larsen , Daniele Toller , Mirco Tribastone , Max Tschaikowski , Andrea Vandin

Organisms have to keep track of the information in the environment that is relevant for adaptive behaviour. Transmitting information in an economical and efficient way becomes crucial for limited-resourced agents living in high-dimensional…

Artificial Intelligence · Computer Science 2024-09-16 Miguel de Llanza Varona , Christopher L. Buckley , Beren Millidge

Reservoir computers (RCs) provide a computationally efficient alternative to deep learning while also offering a framework for incorporating brain-inspired computational principles. By using an internal neural network with random, fixed…

Neural and Evolutionary Computing · Computer Science 2025-04-18 Keshav Srinivasan , Dietmar Plenz , Michelle Girvan

Random features (RFs) are a popular technique to scale up kernel methods in machine learning, replacing exact kernel evaluations with stochastic Monte Carlo estimates. They underpin models as diverse as efficient transformers (by…

Machine Learning · Statistics 2024-10-04 Isaac Reid , Stratis Markou , Krzysztof Choromanski , Richard E. Turner , Adrian Weller

Dynamical systems with a distributed yet interconnected structure, like multi-rigid-body robots or large-scale multi-agent systems, introduce valuable sparsity into the system dynamics that can be exploited in an optimal control setting for…

Robotics · Computer Science 2021-04-08 Roshan Pradhan , Shuo Yang , Frank Dellaert , Howie Choset , Matthew Travers

We consider a communication problem in which an update of the source message needs to be conveyed to one or more distant receivers that are interested in maintaining specific linear functions of the source message. The setting is one in…

Information Theory · Computer Science 2018-08-07 N. Prakash , Muriel Medard

In the study of rare events in complex systems with many degrees of freedom, a key element is to identify the reaction coordinates of a given process. Over recent years, a number of methods and protocols have been developed to extract the…

Chemical Physics · Physics 2015-10-27 Wenjin Li , Ao Ma

Measurements acquired from distributed physical systems are often sparse and noisy. Therefore, signal processing and system identification tools are required to mitigate noise effects and reconstruct unobserved dynamics from limited sensor…

Machine Learning · Computer Science 2025-09-08 Omid Sedehi , Manish Yadav , Merten Stender , Sebastian Oberst

A general method to describe stochastic dynamics of Markov processes is suggested. The method aims to solve three related problems. The determination of an optimal coordinate for the description of stochastic dynamics. The reconstruction of…

Chemical Physics · Physics 2013-12-25 Sergei V. Krivov
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