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The atomic configuration of phases and their interfaces is fundamental to materials design and engineering. Here, we unveil a transition metal oxide interface, whose formation is driven by energetic influences - epitaxial tensile strain…

The spin-orbit coupling and electron correlation in perovskite SrIrO3 (SIO) strongly favor new quantum states and make SIO very attractive for next generation quantum information technology. In addition, the small electronic band-width…

Materials Science · Physics 2019-07-18 A. K. Jaiswal , R. Schneider , R. Singh , D. Fuchs

Perovskite chalcogenides have emerged as a new class of semiconductors with tunable band gap in the visible-infrared region. High quality thin films are critical to understand the fundamental properties and realize the potential…

Materials Science · Physics 2022-10-27 M. Surendran , B. Zhao , G. Ren , S. Singh , A. Avishai , H. Chen , J. Han , M. Kawasaki , R. Mishra , J. Ravichandran

Phase change materials (PCMs) that exhibit volatile resistive switching are promising for emulating neuronal oscillators. Charge transfer insulators, such as ReNiO3 (where Re represents rare earth metals like Pr, Nd, Sm, Eu...), form a…

Materials Science · Physics 2024-10-31 Prashanth S , Binoy Krishna De , Shubham Kumar Parate , Kartick Biswas , Pavan Nukala

In all archetypical reported (001)-oriented perovskite heterostructures, it has been deduced that the preferential occupation of two-dimensional electron gases is in-plane $d_\textrm{xy}$ state. In sharp contrast to this, the investigated…

The interfacial behavior of quantum materials leads to emergent phenomena such as two dimensional electron gases, quantum phase transitions, and metastable functional phases. Probes for in situ and real time surface sensitive…

Hybrid oxide molecular beam epitaxy (hMBE), a thin-film deposition technique in which transition metal cations are delivered using a metal-organic precursor, has emerged as the state-of-the-art approach to the synthesis of electronic-grade…

Layered ruthenates are prototype materials with strong structure-property correlations. We report the structural and physical properties of double-layered perovskite Sr3(Ru1-xMnx)2O7 single crystals with 0<=x<=0.7. Single crystal x-ray…

Strongly Correlated Electrons · Physics 2012-05-01 Biao Hu , Gregory T. McCandless , V. O. Garlea , S. Stadler , Yimin Xiong , Julia Y. Chan , E. W. Plummer , R. Jin

The durability of passivable metals and alloys is often limited by the stability of the surface oxide film, the passive film, providing self-protection against corrosion in aggressive environments. Improving this stability requires to…

Materials Science · Physics 2019-07-26 Li Ma , Frederic Wiame , Vincent Maurice , Philippe Marcus

Strain engineering of perovskite oxide thin films has proven to be an extremely powerful method for enhancing and inducing ferroelectric behavior. In ferroelectric thin films and superlattices, the polarization is intricately linked to…

We report on the synthesis of ultrathin films of highly distorted EuNiO3 (ENO) grown by interrupted pulse laser epitaxy on YAlO3 (YAO) substrates. Through mapping the phase space of nickelate thin film epitaxy, the optimal growth…

Strongly Correlated Electrons · Physics 2014-04-25 D. J. Meyers , E. J. Moon , M. Kareev , I. C. Tung , B. A. Gray , Jian Liu , M. J. Bedzyk , J. W. Freeland , J. Chakhalian

The burgeoning fields of spintronics and topological electronics require materials possessing a unique combination of properties: ferromagnetism, metallicity, and chemical stability. SrRuO3 (SRO) stands out as a compelling candidate due to…

The 5$d$ series semimetallic Dirac nodal-line perovskite SrIrO$_3$ presents a promising system to study the interplay between spin-orbit coupling and electron-electron interactions in the epitaxial thin film geometry. The competition…

Materials Science · Physics 2024-06-05 Wesley Surta , Saeed Almalki , Ya-Xun Lin , Tim Veal , Marita O'Sullivan

We investigated the electronic structure of multiferroic hexagonal RMnO3 (R = Gd, Tb, Dy, and Ho) thin films using both optical spectroscopy and first-principles calculations. Using artificially stabilized hexagonal RMnO3, we extended the…

Strongly Correlated Electrons · Physics 2010-05-17 W. S. Choi , D. G. Kim , S. S. A. Seo , S. J. Moon , D. Lee , J. H. Lee , H. S. Lee , D. -Y. Cho , Y. S. Lee , P. Murugavel , Jaejun Yu , T. W. Noh

This study examines the application of transition metal-doped SrTiO3 in photovoltaic technologies, such as photocatalysis. The core objective is to evaluate how different dopants influence the structural and electronic characteristics of…

Materials Science · Physics 2024-10-15 Zdeněk Jansa , Lucie Prušáková , Štěpánka Jansová , Pavel Calta , Pavol Šutta , Ján Minár

We report first-principles density-functional pseudopotential calculations on the atomic structures, electronic properties, and band offsets of BaO/BaTiO$_3$ and SrO/SrTiO$_3$ nanosized heterojunctions grown on top of a silicon substrate.…

Materials Science · Physics 2009-11-07 Javier Junquera , Magali Zimmer , Pablo Ordejon , Philippe Ghosez

The rich phase diagram of bulk Pr$_{1-x}$Ca$_{x}$MnO$_3$ resulting in a high tunability of physical properties gave rise to various studies related to fundamental research as well as prospective applications of the material. Importantly, as…

Atomically-abrupt interfaces in transition metal oxide (TMO) heterostructures could host a variety of exotic condensed matter phases that may not be found in the bulk materials at equilibrium. A critical step in the development of such…

Thin films and heterostructures of hexagonal manganites as promising multiferroic materials have attracted a considerable interest recently. We report structural transformations of high quality epitaxial h-TMO/YSZ(111) films, analyzed by…

Strongly Correlated Electrons · Physics 2020-09-23 R. Mandal , M. Hirsbrunner , V. Roddatis , L. Schüler , U. Roß , S. Merten , V. Moshnyaga

The interface of complex oxide heterostructures sets the stage for various electronic and magnetic phenomena. Many of these collective effects originate from the precise structural arrangement at the interface that in turn governs local…

Mesoscale and Nanoscale Physics · Physics 2021-03-17 Max Burian , Bill Francesco Pedrini , Nazaret Ortiz Hernandez , Hiroki Ueda , C. A. F. Vaz , Milan Radovic , Urs Staub