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There are several approximations to the exchange-correlation functional in density-functional theory that accurately predict total energy-related properties of many-electron systems, such as binding energies, bond lengths, and crystal…

Chemical Physics · Physics 2015-09-30 Eli Kraisler , Tobias Schmidt , Stephan Kümmel , Leeor Kronik

We present results from integral field spectroscopy with the Potsdam multi-Aperture Spectrograph of the head of the Herbig-Haro object HH 202 with a spatial sampling of 1"x1". We have obtained maps of different emission lines, physical…

Astrophysics · Physics 2009-11-13 A. Mesa-Delgado , L. López-Martín , C. Esteban , J. García-Rojas , V. Luridiana

We report the general implementation of the relativistic equation-of-motion coupled-cluster method to calculate double ionization spectra (DI-EOMCC) of atomic and molecular systems. As a first application, this method is employed to…

Atomic Physics · Physics 2014-08-25 Himadri Pathak , Aryya Ghosh , B. K. Sahoo , B. P. Das , Nayana Vaval , Sourav Pal

Ionization energies for the ground state of berylliumlike ions with nuclear charge numbers in the range Z=16-96 are rigorously evaluated. The calculations merge the ab initio QED treatment in the first and second orders of the perturbation…

Atomic Physics · Physics 2015-07-22 A. V. Malyshev , A. V. Volotka , D. A. Glazov , I. I. Tupitsyn , V. M. Shabaev , G. Plunien

We present a detailed study of the ionisation probability of H and H$_{2}^{+}$ induced by a short intense laser pulse. Starting from a Coulomb-Volkov description of the process we derive a multipole-like expansion where each term is…

Atomic Physics · Physics 2013-07-11 Renata Della Picca , Juan Fiol , Pablo Daniel Fainstein

We analyze two-particle binding factors of H2, LiH, and HeH+ molecules/ions with the help of our original exact diagonalization ab intio (EDABI) approach. The interelectronic correlations are taken into account rigorously within the second…

Strongly Correlated Electrons · Physics 2022-08-24 M. Hendzel , M. Fidrysiak , J. Spałek

We compute the ground-state electric dipole polarizability of group-IIIA ions using the perturbed relativistic coupled-cluster (PRCC) theory. To account for the relativistic effects and QED corrections, we use the Dirac-Coulomb-Breit…

Atomic Physics · Physics 2020-01-15 Ravi Kumar , S. Chattopadhyay , B. K. Mani , D. Angom

We report the first results of ab initio relativistic correlation calculation of the effective electric field on the electron, E_eff, in the ground state of the HI$^+$ cation. This value is required for interpretation of the suggested…

Atomic Physics · Physics 2013-05-29 T. A. Isaev , N. S. Mosyagin , A. N. Petrov , A. V. Titov

In this article, the molecular permanent electric dipole moments and components of static dipole polarizabilities for the electronic ground state of singly charged aluminum monohalides are reported. The coupled-cluster method by considering…

Atomic Physics · Physics 2024-06-18 Ankush Thakur , Renu Bala , H. S. Nataraj , V. S. Prasannaa

Relativistic close coupling calculations are reported for unified electronic recombination of (e + C IV) including non-resonant and resonant recombination processes, radiative and dielectronic recombination (RR and DR). Detailed comparison…

Astrophysics · Physics 2008-11-26 Anil K. Pradhan , Guo Xin Chen , Sultana N. Nahar , Hong Lin Zhang

A benchmark study has been carried out on the ground-state potential curve of the hydroxyl anion, OH^{-}, including detailed calibration of both the 1-particle and n-particle basis sets. The CCSD(T) basis set limit overestimates $\omega_e$…

Chemical Physics · Physics 2015-06-26 Jan M. L. Martin

Advanced theoretical techniques that combine the linearized coupled-cluster method, configuration interaction method, and perturbation theory are used to calculate energy levels, ionization potentials, electron affinities, field isotope…

Atomic Physics · Physics 2025-08-05 V. A. Dzuba , V. V. Flambaum , G. K. Vong

This work reports radiative transition rates and electron impact excitation rate coefficients for levels of the n= 3, 4, 5, 6, 7, 8 configurations of Ca II. The radiative data were computed using the Thomas-Fermi-Dirac central potential…

Astrophysics · Physics 2009-11-13 M. Melendez , M. A. Bautista , N. R. Badnell

This paper considers a family of second-order periodic parabolic equations with highly oscillating potentials, which have been considered many times for the time-varying potentials in stochastic homogenization. Following a standard…

Analysis of PDEs · Mathematics 2022-07-20 Yiping Zhang

We calculate the nucleons' electromagnetic polarizabilities in heavy baryon chiral perturbation theory including all terms to order ${\cal O} (q^4)$. The chiral prediction of the electric polarizabilities for the neutron and the proton are…

High Energy Physics - Phenomenology · Physics 2016-08-14 Véronique Bernard , Norbert Kaiser , Armin Schmidt , Ulf-G. Meißner

The delta function gauge of the electromagnetic potential allows semiclassical formulas to be obtained for the probability of exciting a single electron out of the ground state in an ultrarelativistic heavy ion reaction. Exact formulas have…

Atomic Physics · Physics 2008-12-18 A. J. Baltz

Our all-electron fully relativistic Dirac-Fock (DF) and nonrelativistic (NR) Hartree-Fock (HF) SCF molecular calculations for the superheavy tetrahedral (T$_d$) oganesson tetratennesside OgT$_4$ predict atomization energy (Ae) of 7.45 and…

Chemical Physics · Physics 2021-01-15 Gulzari Malli , Martin Siegert , Luiz Guilherme M de Macedo , Walter Loveland

Relativistic calculations of the electronic structure of the superheavy element of the eighth period $-$ eka-francium ($Z=119$) and its homologues, which form the group of alkali metals, are performed in the framework of the…

The first adiabatic exponent profile, noted $\Gamma_1$, computed along adiabatic coordinates $(T, \rho)$ is in the focus of our study. Under conditions of almost fully ionized hydrogen and helium, the $\Gamma_1$ profile is quite sensitive…

Solar and Stellar Astrophysics · Physics 2024-10-08 V. A. Baturin , A. V. Oreshina , G. Buldgen , S. V. Ayukov , V. K. Gryaznov , I. L. Iosilevskiy , A. Noels , R. Scuflaire

The nuclear recoil effect on the $g$ factor of the ground state of highly charged B-like ions is studied to first order in the electron-to-nucleus mass ratio $m/M$. The leading one-electron and two-electron recoil contributions are…

Atomic Physics · Physics 2019-01-02 I. A. Aleksandrov , D. A. Glazov , A. V. Malyshev , V. M. Shabaev , I. I. Tupitsyn
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