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X-ray photoelectron diffraction is used to directly probe the intra-cell polar atomic distortion and tetragonality associated with ferroelectricity in ultrathin epitaxial PbTiO3 films. Our measurements, combined with ab-initio calculations,…

(Abridged) Life is distinctly homochiral. The origins of this homochirality are under active debate. Recently, propylene-oxide has been detected in the gas-phase interstellar medium (ISM) (McGuire et al. 2016). The enantiomeric composition…

Astrophysics of Galaxies · Physics 2022-10-19 Boy Lankhaar

Chiral perovskites owing to their broken mirror symmetry exhibit selective absorption of circularly polarized light manifesting a strong circular dichroism (CD). CD spectroscopy has been a key technique to understand chiral perovskites and…

Materials Science · Physics 2026-02-10 Reshna Shrestha , Wanyi Nie

The calculations presented here reveal that an electron probe carrying orbital angular momentum is just a particular case of a wider class of electron beams that can be used to measure electron magnetic circular dichroism (EMCD) with atomic…

Materials Science · Physics 2015-06-22 Jan Rusz , Juan-Carlos Idrobo , Somnath Bhowmick

Light interaction with rotating nanostructures gives rise to phenemona as varied as optical torques and quantum friction. Here we reveal that circular dichroism of rotating optically-isotropic particles has an unexpectedly strong dependence…

Mesoscale and Nanoscale Physics · Physics 2019-08-14 Deng Pan , Hongxing Xu , F. Javier García de Abajo

Weyl semimetals are a three dimensional gapless topological phase in which bands intersect at arbitrary points -- the Weyl nodes -- in the Brillouin zone. These points carry a topological quantum number known as the \emph{chirality} and…

Strongly Correlated Electrons · Physics 2015-03-05 Pavan Hosur , Xiao-Liang Qi

Direct observation of organic molecular nanocrystals and their evolution using electron microscopy is extremely challenging, due to their radiation sensitivity and complex structure. Here, we introduce 4D-scanning confocal electron…

Materials Science · Physics 2022-06-15 Mingjian Wu , Christina Harreiss , Colin Ophus , Erdmann Spiecker

An efficient first principles approach to calculate X-ray magnetic circular dichroism (XMCD) and X-ray natural circular dichroism (XNCD) is developed and applied in the near edge region at the K-and L1-edges in solids. Computation of…

Four-dimensional imaging of charge migration is crucial to the understanding of several ubiquitous processes in nature. The present work focuses on imaging of charge migration in an oriented epoxypropane: a chiral molecule. A linearly…

Chemical Physics · Physics 2021-11-24 Sucharita Giri , Jean Christophe Tremblay , Gopal Dixit

We suggest that electromagnetic chirality, generally displayed by 3D or 2D complex chiral structures, can occur in 1D patterned composites whose components are achiral. This feature is highly unexpected in a 1D system which is geometrically…

Optics · Physics 2015-08-05 Carlo Rizza , Andrea Di Falco , Michael Scalora , Alessandro Ciattoni

Electron transmission through chiral molecules induced by circularly polarized light can be very different for mirror-image structures, a peculiar fact given that the electronic energy spectra of the systems are identical. We propose that…

Chemical Physics · Physics 2009-11-13 Spiros S. Skourtis , David N. Beratan , Ron Naaman , Abraham Nitzan , David H. Waldeck

Photoelectron momentum distributions (PMDs) from atoms and molecules undergo qualitative changes as laser parameters are varied. We present a model to interpret the shape of the PMDs. The electron's motion is guided by a fictitious particle…

Chaotic Dynamics · Physics 2018-09-19 Jonathan Dubois , Simon Berman , Cristel Chandre , Turgay Uzer

Here, we evaluate multislice electron ptychography as a tool to carry out depth-resolved atomic resolution characterization of point defects, using silicon carbide as a case study. Through multislice electron scattering simulations and…

Materials Science · Physics 2025-05-15 Aaditya Bhat , Colin Gilgenbach , Junghwa Kim , Michael Xu , Menglin Zhu , James M. LeBeau

We study the origin of dichroic effects in elastic scattering of high energy electrons by hydrogen atoms in the presence of a two-color bicircular laser field of commensurate frequencies, in the domain of moderate intensities below 10…

Atomic Physics · Physics 2023-09-27 Gabriela Buica

We demonstrate that an effect phenomenologically analogous to circular dichroism can arise even for dielectric and isotropic chiral spherical particles. By analyzing the polarimetry of light scattered from a chiral, lossless microsphere…

Photoelectron angular distributions (PADs) of oriented polar molecules in response to different polarized lasers are systematically investigated. It is found that the PADs of polar CO molecules show three distinct styles excited by…

Chemical Physics · Physics 2013-03-05 Xiaosong Zhu , Qingbin Zhang , Weiyi Hong , Peixiang Lu , Zhizhan Xu

Circular dichroism (CD) of photoemission from a surface state on Bi(111) is considered within an {\it ab initio} one-step theory of photoemission. The symmetry of the azimuthal distribution of CD for different spin directions is discussed…

Materials Science · Physics 2024-08-26 E. E. Krasovskii

Photoinduced force microscopy (PiFM) enables nanoscale visualization of optical responses by directly detecting photoinduced forces without relying on luminescence. In molecular assemblies, intermolecular polarization coupling can generate…

Optics · Physics 2026-05-21 Masayoshi Fujii , Mamoru Tamura , Hidemasa Yamane , Hajime Ishihara

We use the $R$-matrix with time-dependence method to study detachment from F$^-$ in circularly-polarized laser fields of infrared wavelength. By decomposing the photoelectron momentum distribution into separate contributions from detached…

Atomic Physics · Physics 2019-11-04 G. S. J. Armstrong , D. D. A. Clarke , A. C. Brown , H. W. van der Hart

A uniaxial chiral metamaterial is constructed by double-layered four "U" split ring resonators mutually twisted by 90 degrees. It shows a giant optical activity and circular dichroism. The retrieval results reveal that a negative refractive…