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We present a systematic and comparative study of the structural and electronic properties of Cu-based ternary and quaternary semiconductors using first-principles electronic structure approaches. The important role that Cu d electrons play…

Materials Science · Physics 2015-05-28 Yubo Zhang , Xun Yuan , Xiudong Sun , Bi-Ching Shih , Peihong Zhang , Wenqing Zhang

We present a comprehensive first-principles study of the electronic structure of 51 semiconducting monolayer transition metal dichalcogenides and -oxides in the 2H and 1T hexagonal phases. The quasiparticle (QP) band structures with…

Materials Science · Physics 2015-06-10 Filip Anselm Rasmussen , Kristian Sommer Thygesen

In the effective-mass approximation, the step-like crystal potential of a wurtzite semiconductor heterostucture should be supplemented by Dirac delta-function heterointerface terms. They stem from the difference in the Bloch functions of…

Mesoscale and Nanoscale Physics · Physics 2015-05-05 Eduard Takhtamirov

Hubbard-corrected density functional theory, denoted by DFT+U method, was developed to enable correct prediction of insulating properties for strongly-correlated electron systems. UO$_2$ is an example having O-$2p$, U-$6d$, and U-$5f$…

Strongly Correlated Electrons · Physics 2023-02-28 Mahmoud Payami

Employing density functional theory based calculations, we investigate structural, vibrational and strain-dependent electronic properties of an ultra-thin CdTe crystal structure that can be de- rived from its bulk counterpart. It is found…

Mesoscale and Nanoscale Physics · Physics 2017-11-15 Fadil Iyikanat , Baris Akbali , Jun Kang , R. Tugrul Senger , Yusuf Selamet , Hasan Sahin

Electronic structure and transport characteristics of coupled CdS and ZnSe quantum dots are studied using density functional theory and non equilibrium Greens function method respectively. Our investigations show that in these novel coupled…

Mesoscale and Nanoscale Physics · Physics 2021-08-03 Simon Liebing , Torsten Hahn , Jens Kortus , Bidisa Das , Arup Chakraborty , Indra Dasgupta

Despite the large number of theoretical III-V semiconductor studies reported every year, our atomistic understanding is still limited. The limitations of the theoretical approaches to yield accurate structural and electronic properties on…

Preparation of solid solutions represents an effective means to improve the photocatalytic properties of semiconductor-based materials. Nevertheless, the effects of site-occupancy disorder on the mixing stability and electronic properties…

Materials Science · Physics 2018-12-11 Joel Shenoy , Judy N. Hart , Ricardo Grau-Crespo , Neil L. Allan , Claudio Cazorla

We report comprehensive study of physical properties of the binary superconductor compound SnAs. The electronic band structure of SnAs was investigated using both angle-resolved photoemission spectroscopy (ARPES) in a wide binding energy…

Spin-current density functional theory (SCDFT) is a formally exact framework designed to handle the treatment of interacting many-electron systems including spin-orbit coupling at the level of the Pauli equation. In practice, robust and…

A comparative study by FP-LAPW calculations based on DFT within LDA, PBE-GGA, EV$_{ex}$-PW$_{co}$-GGA, and EV$_{ex}$-GGA-LDA$_{co}$ schemes is introduced for the structural and electronic properties of ScN in RS, ZB, WZ, and CsCl phases.…

Materials Science · Physics 2011-07-05 R. Mohammad , S. Katircioglu

For semiconductors used in photovoltaic devices, the effective mass approximation allows calculation of important material properties from first-principles calculations, including optical properties (e.g. exciton binding energies), defect…

Materials Science · Physics 2019-03-06 Lucy D. Whalley , Jarvist M. Frost , Benjamin J. Morgan , Aron Walsh

We report the electronic structure of monoclinic CuO as obtained from first principles calculations utilizing density functional theory plus effective Coulomb interaction (DFT + U) method. In contrast to standard DFT calculations taking…

Strongly Correlated Electrons · Physics 2014-02-19 C. E. Ekuma , V. I. Anisimov , J. Moreno , M. Jarrell

We present a symmetry-based calculation of the electronic structure of a compound semiconductor quantum dot (QD) in the sp^3s* tight-binding model including the spin-orbit interaction. The Hamiltonian matrix is diagonalized exactly for CdTe…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 J. Perez-Conde , A. K. Bhattacharjee

Using angle-resolved photoemission spectroscopy (ARPES) and low-energy electron diffraction (LEED), together with density-functional theory (DFT) calculation, we report the formation of charge density wave (CDW) and its interplay with the…

Strongly Correlated Electrons · Physics 2020-11-24 Peng Li , Baijiang Lv , Yuan Fang , Wei Guo , Zhongzheng Wu , Yi Wu , Cheng-Maw Cheng , Dawei Shen , Yuefeng Nie , Luca Petaccia , Chao Cao , Zhu-An Xu , Yang Liu

First principles linear combinations of Gaussian type orbitals-fitting function (LCGTO-FF) electronic structure calculations are used to study thickness dependencies in the surface energies and work functions of ultra-thin (111) films of…

Strongly Correlated Electrons · Physics 2009-11-10 A. K. Ray , J. C. Boettger

We present {\it ab initio} total energy and band structure calculations based on Density Funtional Theory (DFT) within the Local Density Aproximation (LDA) on group-V mixing effects in the optoelectronic material…

Materials Science · Physics 2009-11-10 A. A. Leitão , R. B. Capaz

Atomic effective pseudopotentials enable atomistic calculations at the level of accuracy of density functional theory for semiconductor nanostructures with up to fifty thousand atoms. Since they are directly derived from ab-initio…

Materials Science · Physics 2024-03-14 Surender Kumar , Hanh Bui , Gabriel Bester

The electronic structure and magnetic properties of CaCr$\mathrm{O}_3$ have been calculated by two methods, including hybrid-exchange density-function theory and density-functional theory + $U$. The computed densities of states from both of…

Strongly Correlated Electrons · Physics 2015-05-13 Wei Wu

Traditional CdS buffer layer in selenium-free Cu(In,Ga)S2 solar cells leads to reduced open-circuit voltage because of a negative conduction band offset at the Cu(In,Ga)S2/CdS interface. Reducing this loss necessitates the substitution of…

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