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Surface-enhanced spectroscopy techniques are the method-of-choice to characterize adsorbed intermediates occurring during electrochemical reactions, which are crucial in realizing a green sustainable future. Characterizing species with low…

Mesoscale and Nanoscale Physics · Physics 2023-07-21 Malo Duportal , Luca M. Berger , Stefan A. Maier , Andreas Tittl , Katharina Krischer

A new method based on the combination of small-anglescattering, reverse Monte Carlo simulations, and an aggregate recognition algorithm is proposed to characterize the structure of nanoparticle suspensions in solvents and polymer…

We describe a novel framework for estimating subsurface properties, such as rock permeability and porosity, from time-lapse observed seismic data by coupling full-waveform inversion, subsurface flow processes, and rock physics models. For…

Geophysics · Physics 2020-05-06 Dongzhuo Li , Kailai Xu , Jerry M. Harris , Eric Darve

The accurate description of iron oxides/water interfaces requires reliable force field parameters that can be developed through the comparison with sophisticated quantum mechanical calculations. Here a set of CLASS2 force field parameters…

Materials Science · Physics 2021-12-07 Paulo Siani , Enrico Bianchetti , Hongsheng Liu , Cristiana Di Valentin

Sensitivity analysis plays an important role in searching for constitutive parameters (e.g. permeability) subsurface flow simulations. The mathematics behind is to solve a dynamic constrained optimization problem. Traditional methods like…

Computational Physics · Physics 2019-06-05 Shu Wang , Satish Karra , Daniel O'Malley

We report a comprehensive study of aqueous halide adsorption on nanoparticles of gold and palladium that addresses several limitations hampering the use of atomistic modeling as a tool for understanding and improving wet-chemical synthesis…

Materials Science · Physics 2021-08-17 Joakim Löfgren , J. Magnus Rahm , Joakim Brorsson , Paul Erhart

Chemical heterogeneity of solid surfaces disrupts the adsorption of surfactants from the bulk liquid. While its presence can hinder the performance of some formulations, bespoke chemical patterning could potentially facilitate controlled…

A linear correlation is presented between the reduced surface tension \sigma^* and reduced temperature T^*_{extScal} by applying the extended scaling law. The correlation is applied quite accurately to 17 atomic, diatomic, and molecular…

Statistical Mechanics · Physics 2007-05-23 Mohammad Hadi Ghatee , Ali Soorghali

Typically, a salient object detection (SOD) model faces opposite requirements in processing object interiors and boundaries. The features of interiors should be invariant to strong appearance change so as to pop-out the salient object as a…

Computer Vision and Pattern Recognition · Computer Science 2019-09-12 Jinming Su , Jia Li , Yu Zhang , Changqun Xia , Yonghong Tian

Surface wettability has a huge influence on its functional properties. For example, to minimize smudging, surfaces should be able to repel oil droplets. To quantify surface wettability, the most common approach is to measure the contact…

Soft Condensed Matter · Physics 2020-04-09 Dan Daniel , Yunita Florida , Chee Leng Lay , Xue Qi Koh , Anqi Sng , Nikodem Tomczak

We show that a modified version of the Dukhin number is an appropriate scaling parameter for the ionic selectivity of uniformly charged nanopores. The modified Dukhin number is an unambiguous function of the variables $\sigma$ (surface…

Mesoscale and Nanoscale Physics · Physics 2020-12-29 Zsófia Sarkadi , D'avid Fertig , Mónika Valiskó , Dezső Boda

As a model system of the adsorption process of anti-corrosion additives on a metal surface, molecular dynamics simulations of benzotriazole (BTA) molecules with copper slabs were completed. As a force field, ReaxFF was used to simulate both…

Chemical Physics · Physics 2023-08-08 Kohei Nishikawa , Hirotoshi Akiyama , Kazuhiro Yagishita , Hitoshi Washizu

Resonance anomalous surface x-ray scattering (RASXS) technique was applied to electrochemical interface studies. It was used to determine the chemical states of electrochemically formed anodic oxide monolayers on platinum surface. It is…

Area-selective atomic layer deposition is a key technology for modern microelectronics as it eliminates alignment errors inherent to conventional approaches by enabling material deposition only in specific areas. Typically, the selectivity…

We show that smoothing of multiaffine surfaces that are generated by simulating a crosslinked polymer gel by a frustrated, triangular network of springs of random equilibrium lengths [G.M. Buend{\'\i}a, S.J. Mitchell, P.A. Rikvold, Phys.…

Statistical Mechanics · Physics 2007-05-23 G. M. Buendia , S. J. Mitchell , P. A. Rikvold

We study the surface tension of ionic solutions at air/water and oil/water interfaces. By using field-theoretical methods and including a finite proximal surface-region with ionic-specific interactions. The free energy is expanded to…

Soft Condensed Matter · Physics 2015-03-31 Tomer Markovich , David Andelman , Rudolf Podgornik

Understanding confined flows of complex fluids requires simultaneous access to the mechanical behaviour of the liquid and the boundary condition at the interfaces. Here, we use evanescent wave microscopy to investigate near-surface flows of…

Soft Condensed Matter · Physics 2020-12-01 Gabriel Guyard , Alexandre Vilquin , Nicolas Sanson , Frederic Restagno , Joshua D. Mcgraw

In the present paper, the connection between surface order-disorder phase transitions and the percolating properties of the adsorbed phase has been studied. For this purpose, four lattice-gas models in presence of repulsive interactions…

Computational Physics · Physics 2009-11-13 M. Cecilia Gimenez , Felix Nieto , Antonio J. Ramirez-Pastor

In this paper, we study electrostatic properties between two similar or oppositely charged surfaces immersed in an electrolyte solution by using mean-field approach accounting for solvent polarization and non-uniform size effect. Applying a…

Soft Condensed Matter · Physics 2022-02-11 Jun-Sik Sin

In this work, a force field for several ions in water is proposed. In particular, we consider the cations Li$^+$ , Na$^+$ , K$^+$, Mg$^{2+}$, Ca$^{2+}$ and the anions Cl$^-$, and SO$_4^{2-}$ . These ions were selected as they appear in the…

Chemical Physics · Physics 2024-01-25 I. M. Zeron , J. L. F. Abascal , C. Vega