Related papers: Electric quadrupole transitions in carbon dioxide
Detailed characterization of exoplanets has begun to yield measurements of their atmospheric properties that constrain the planets' origins and evolution. For example, past observations of the dayside emission spectrum of the hot Jupiter…
Infrared absorption spectroscopy study of endohedral water molecule in a solid mixture of H$_2$O@C$_{60}$ and C$_{60}$ was carried out at liquid helium temperature. From the evolution of the spectra during the ortho-para conversion process,…
A large peculiar velocity of the intergalactic medium produces a Doppler shift of the cosmic microwave background with a frequency-dependent quadrupole term. This quadrupole will act as a source for polarization of the cosmic microwave…
Carbon monoxide molecules in their electronic, vibrational, and rotational ground state are highly attractive for trapping experiments. The optical or ac electric traps that can be envisioned for these molecules will be very shallow,…
A novel variational method is proposed for calculating the percolation threshold, the real-space structure, and the thermodynamical compressibility of a disordered two-dimensional electron liquid. Its high accuracy is verified against prior…
An electronically coarse-grained model for water reveals a persistent vestige of the liquid-gas transition deep into the supercritical region. A crossover in the density dependence of the molecular dipole arises from the onset of…
Absorption lines from water, methane and carbon monoxide are detected in the atmosphere of exoplanet HR8799b. A medium-resolution spectrum presented here shows well-resolved and easily identified spectral features from all three molecules…
The diffusion of molecules on interstellar grain surfaces is one of the most important driving forces for the molecular complexity in the interstellar medium. Due to the lack of laboratory measurements, astrochemical modeling of grain…
Investigating the fate of dissolved carbon dioxide under extreme conditions is critical to understanding the deep carbon cycle in the Earth, a process that ultimately influences global climate change. We used first-principles molecular…
We report the detection of more than 48 velocity-resolved ground rotational state transitions of H2(16)O, H2(18)O, and H2(17)O - most for the first time - in both emission and absorption toward Orion KL using Herschel/HIFI. We show that a…
The unique isomeric transition at 7.8 eV in $~^{229}\mathrm{Th}$ has a magnetic dipole ($M1$) and an electric quadrupole ($E2$) multipole mixing. So far, the $E2$ component has been widely disregarded. Here, we investigate the nuclear…
Parity-violating differences in rotational constants of a chiral 5d transition metal complex, that was previously experimentally well-characterised by broad-band microwave spectroscopy, are predicted with a recently established efficient…
We report new precise p$(\vec{e},e^\prime p)\pi^0$ measurements at the peak of the $\Delta^{+}(1232)$ resonance at $Q^2=\unit[0.20](GeV/c)^2$ performed at the Mainz Microtron (MAMI). The new data are sensitive to both the electric…
Quadrupole excitations of even-even Ru and Pd isotopes are described within microscopic approach based on the general collective Bohr model which includes the effect of coupling with the pairing vibrations. The excitation energies and E2…
We report new elastic and inelastic cross sections for O($^3P$)+CO$_2$ scattering at collision energies from 0.03 to 5 eV, of major importance to O escape from Mars, Venus, and CO$_2$-rich atmospheres. The cross sections were calculated…
UV absorption cross sections are an essential ingredient of photochemical atmosphere models. Exoplanet searches have unveiled a large population of short-period objects with hot atmospheres, very different from what we find in our solar…
The urgent need to mitigate rising atmospheric CO2 levels motivates the search for stable, efficient, and tunable adsorbent materials. In this study, we employ first-principles density functional theory to investigate the adsorption of CO2…
Electron cooling, in which free electrons lose energy to vibrational excitation of gases, has been identified as a significant process in the atmospheres of Mars and Venus for electron impact on CO2. This process does not appear to have…
We present a detailed investigation of the ultranarrow magnetic-quadrupole $^{1}\mathrm{S}_0$-$^{3}\mathrm{P}_2$ transition in neutral strontium and show how it can be made accessible for quantum simulation and quantum computation. By…
We discuss 3D global simulations of the early Martian climate that we have performed assuming a faint young Sun and denser CO2 atmosphere. We include a self-consistent representation of the water cycle, with atmosphere-surface interactions,…