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A free surface induces enhanced dynamics in glass formers. We study the dynamical enhancement of glassy films with a distinguishable-particle lattice model of glass free of elastic effects. We demonstrate that the thickness of the surface…

Soft Condensed Matter · Physics 2025-06-17 Qiang Zhai , Hai-Yao Deng , Xin-Yuan Gao , Leo S. I. Lam , Sen Yang , Ke Yan , Chi-Hang Lam

Direct atomically resolved observation of dynamics deep in the glassy regime has proved elusive for atomic and molecular glasses. Studies below the glass transition temperature Tg are especially rare due to long waiting times required to…

Mesoscale and Nanoscale Physics · Physics 2010-06-10 Sumit Ashtekar , Gregory Scott , Joseph Lyding , Martin Gruebele

We describe a model for the thermodynamics and dynamics of glass-forming liquids in terms of excitations from an ideal glass state to a Gaussian manifold of configurationally excited states. The quantitative fit of this three parameter…

Soft Condensed Matter · Physics 2015-06-25 Dmitry V. Matyushov , C. A. Angell

The aging behavior of polymer glass, poly(methyl methacrylate), has been investigated through the measurement of ac dielectric susceptibility ata fixed frequency after a temperature shift $\Delta T$ ($\le $ 20 K)between two temperatures,…

Soft Condensed Matter · Physics 2009-11-13 Koji Fukao , Sinpei Yamawaki

The description of activated relaxation of glassy systems in the multidimensional configurational space is a long-standing open problem. We develop a phenomenological description of the out-of-equilibrium dynamics of a model with a rough…

Disordered Systems and Neural Networks · Physics 2014-10-09 Chiara Cammarota , Enzo Marinari

The binary hard-sphere mixture is one of the simplest representations of a many-body system with competing time and length scales. This model is relevant to fundamentally understand both the structural and dynamical properties of materials,…

An instructive and apparently simple model of fully-coupled rotators, the so-called Hamiltonian Mean Field (HMF) model, together with a generalized version with variable interaction range, have revealed a very complex out-of-equilibrium…

Statistical Mechanics · Physics 2015-06-25 Andrea Rapisarda , Alessandro Pluchino

We analyse, using Inhomogenous Mode-Coupling Theory, the critical scaling behaviour of the dynamical susceptibility at a distance epsilon from continuous second-order glass transitions. We find that the dynamical correlation length xi…

Disordered Systems and Neural Networks · Physics 2014-12-17 Saroj Kumar Nandi , Giulio Biroli , Jean-Philippe Bouchaud , Kunimasa Miyazaki , David R. Reichman

The study of spin-glass dynamics, long considered the paradigmatic complex system, has reached important milestones. The availability of single crystals has allowed the experimental measurement of spin-glass coherence lengths of almost…

A universal dynamical crossover temperature, Tcr, in glassy liquids, associated with the {\alpha}-\b{eta} bifurcation temperature, TB, has been observed in dielectric spectroscopy and other experiments. Tcr lies significantly above the…

Soft Condensed Matter · Physics 2024-03-29 Shubham Kumar , Sarmistha Sarkar , Biman Bagchi

Glasses behave as solids due to their long relaxation time; however the origin of this slow response remains a puzzle. Growing dynamic length scales due to cooperative motion of particles are believed to be central to the understanding of…

Soft Condensed Matter · Physics 2012-10-17 Sara Jabbari-Farouji , Rojman Zargar , Gerard Wegdam , Daniel Bonn

In this work we revisit the description of dynamics based on the concepts of metabasins and activation in mildly supercooled liquids via the analysis of the dynamics of a paradigmatic glass former between its onset temperature $T_{o}$ and…

Soft Condensed Matter · Physics 2021-06-15 Marco Baity-Jesi , Giulio Biroli , David R. Reichman

We show how dynamical heterogeneities in glass forming systems emerge as a consequence of the existence of dynamical constraints, and we offer an interpretation of the glass transition as an entropy crisis in trajectory space (space-time)…

Statistical Mechanics · Physics 2009-11-07 Juan P. Garrahan , David Chandler

We use computer simulations to probe the thermodynamic and dynamic properties of a glass-former that undergoes an ideal glass-transition because of the presence of randomly pinned particles. We find that even deep in the equilibrium glass…

Disordered Systems and Neural Networks · Physics 2018-12-03 Misaki Ozawa , Atsushi Ikeda , Kunimasa Miyazaki , Walter Kob

Strong changes in bulk properties, such as modulus and viscosity, are observed near the glass transition temperature, T_{g}, of amorphous materials. For more than a century, intense efforts have been made to define a microscopic origin for…

Disordered Systems and Neural Networks · Physics 2024-04-24 Joseph B. Schlenoff , Khalil Akkaoui

We review the phenomena of dynamical heterogeneity in glass-forming systems and its description within replica and mean-field theories of the glass transition.

Disordered Systems and Neural Networks · Physics 2022-09-08 Giulio Biroli , Kunimasa Miyazaki , David R. Reichman

The fragility, that controls the temperature-dependent viscous properties of liquids as the glass transition is approached, in various glass-forming liquids with different atomic interactions and densities is investigated by molecular…

Soft Condensed Matter · Physics 2016-08-03 Lijin Wang , Pengfei Guan , W. H. Wang

The dynamics of a heteropolymer chain in solution is studied in the limit of long chain length. Using functional integral representation we derive an effective equation of motion, in which the heterogeneity of the chain manifests itself as…

Condensed Matter · Physics 2009-10-28 Jiunn-Ren Roan , E. I. Shakhnovich

The viscosity of glass-forming liquids increases by many orders of magnitude if their temperature is lowered by a mere factor of 2-3 [1,2]. Recent studies suggest that this widespread phenomenon is accompanied by spatially heterogeneous…

Disordered Systems and Neural Networks · Physics 2015-05-28 Walter Kob , Sandalo Roldan-Vargas , Ludovic Berthier

It has been recognized of late that even amorphous, glass-forming materials in two dimensions (2D) are significantly affected by Mermin-Wagner type long wavelength thermal fluctuation which is inconsequential in three (3D) and higher…

Disordered Systems and Neural Networks · Physics 2024-07-19 Santu Nath , Shiladitya Sengupta