English

Crossover of aging dynamics in polymer glass: from cumulative aging to non-cumulative aging

Soft Condensed Matter 2009-11-13 v1

Abstract

The aging behavior of polymer glass, poly(methyl methacrylate), has been investigated through the measurement of ac dielectric susceptibility ata fixed frequency after a temperature shift ΔT\Delta T (\le 20 K)between two temperatures, T1T_1 and T2T_2. A crossover from cumulative aging to non-cumulative aging could be observed with increasing ΔT\Delta T using a twin temperature (TT-) shift measurement. Based on a growth law of a dynamical coherent length given by activated dynamics, we obtained a unique coherent length for positive and negative TT-shifts. The possibility of the existence of temperature chaos in polymer glasses is discussed.

Keywords

Cite

@article{arxiv.0801.0794,
  title  = {Crossover of aging dynamics in polymer glass: from cumulative aging to non-cumulative aging},
  author = {Koji Fukao and Sinpei Yamawaki},
  journal= {arXiv preprint arXiv:0801.0794},
  year   = {2009}
}

Comments

7 pages, 6 figures