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We present first-principles many-body perturbation theory calculations of the quasiparticle electronic structure and of the optical response of HfO$_2$ polymorphs. We use the $GW$ approximation including core electrons by the projector…

Materials Science · Physics 2018-11-14 Benoît Sklénard , Alberto Dragoni , François Triozon , Valerio Olevano

We show that, in the high-density limit, restricted M{\o}ller-Plesset (RMP) perturbation theory yields $E_{\text{RMP}}^{(2)} = \pi^{-2}(1-\ln 2) \ln r_s + O(r_s^0)$ for the correlation energy per electron in the uniform electron gas, where…

Strongly Correlated Electrons · Physics 2011-04-26 Pierre-François Loos , Peter M. W. Gill

We study the evolution of the band-gap structure in few-layer MoTe$_2$ crystals, by means of low-temperature micro-reflectance (MR) and temperature-dependent photoluminescence (PL) measurements. The analysis of the measurements indicate…

The ab initio $GW$ method is considered as the most accurate approach for calculating the band gaps of semiconductors and insulators. Yet its application to transition metal oxides (TMOs) has been hindered by the failure of traditional…

Materials Science · Physics 2017-02-08 Georgy Samsonidze , Cheol-Hwan Park , Boris Kozinsky

Stacking monolayer semiconductors results in moir\'e patterns that host many correlated and topological electronic phenomena, but measurements of the basic electronic structure underpinning these phenomena are scarce. Here, we investigate…

We develop SOS-RILT-MP2, an efficient Gaussian-based periodic scaled opposite-spin second-order M{\o}ller-Plesset perturbation theory (SOS-MP2) algorithm that utilizes the resolution-of-the-identity approximation (RI) combined with the…

Chemical Physics · Physics 2025-03-27 Idan Haritan , Xiao Wang , Tamar Goldzak

The idea of adaptive perturbation theory is to divide a Hamiltonian into a solvable part and a perturbation part. The solvable part contains the non-interacting sector and the diagonal elements of Fock space from the interacting terms. The…

Quantum Physics · Physics 2021-06-14 Xin Guo

In this letter we present band gaps of II-VI semiconductors, calculated by the full potential linearized augmented plane wave (FP-LAPW) method with the modified Becke-Johnson (mBJ) potential. The accuracy of the calculated results is…

Strongly Correlated Electrons · Physics 2012-01-05 Imad Khan , Iftikhar Ahmad , H. A. Rahnamaye Aliabad , M. Maqbool

Using seven semiconductors/insulators with band gaps covering the range from 1 eV to 10 eV we systematically explore the performance of two different variants of self-consistency associated with famous Hedin's system of equations: the full…

Materials Science · Physics 2022-01-20 Andrey L. Kutepov

In quantum chemistry, obtaining a system's mean-field solution and incorporating electron correlation in a post Hartree-Fock (HF) manner comprise one of the standard protocols for ground-state calculations. In principle, this scheme can…

Chemical Physics · Physics 2020-09-02 Hong-Zhou Ye , Troy Van Voorhis

We have studied the electronic structure of InN and GaN employing G0W0 calculations based on exact-exchange density-functional theory. For InN our approach predicts a gap of 0.7 eV. Taking the Burnstein-Moss effect into account, the…

An ab initio approach formulated under an entropy-inspired repartitioning of the electronic Hamiltonian is presented. This ansatz produces orbital eigenvalues each shifted by entropic contributions expressed as subsets of scaled pair…

Chemical Physics · Physics 2025-06-10 Abdulrahman Y. Zamani , Kevin Carter-Fenk

We present photoluminescence (PL) spectroscopy measurements of single-layer MoSe2 as a function of uniform uniaxial strain. A simple clamping and bending method is described that allows for application of uniaxial strain to layered, 2D…

Within the framework of many-particle perturbation theory, we develop an analytical approach that allows us to determine the small distance behavior of Green's functions and related quantities in electronic structure theory. As a case…

Mathematical Physics · Physics 2025-03-17 Heinz-Juergen Flad , Michael Griebel

We consider magnetic oscillations due to Landau quantization in the mixed state of type-II superconductors. Our work is based on a previously developed formalism which allows the mean-field gap equations of the Abrikosov state to be…

Condensed Matter · Physics 2009-10-22 M. R. Norman , A. H. MacDonald , H. Akera

For a set of ten crystalline materials (oxides and semiconductors), we compute the electronic band structures using the Tran-Blaha [Phys. Rev. Lett. 102, 226401 (2009)] (TB09) functional. The band widths and gaps are compared with those…

We performed first-principles density functional theory (DFT) and GW calculations to investigate electronic structures of bulk and few-layer PdSe2. We obtained the quasiparticle band structure of bulk PdSe2, and the obtained energy gap…

Materials Science · Physics 2021-09-02 Han-gyu Kim , Hyoung Joon Choi

Interplay of superconductivity and magnetism in a composite prepared of the ferromagnetic half-metallic La_0.67Sr_0.33MnO (LSMO) nanoparticles and the conventional s-wave superconductor MgB_2 has been studied. A few principal effects have…

Superconductivity · Physics 2013-05-30 V. N. Krivoruchko , V. Yu. Tarenkov

We demonstrate that coupled-cluster singles-and-doubles Green's function (GFCCSD) method is a powerful and prominent tool drawing the electronic band structures and the total energies, which many theoretical techniques struggle to…

Materials Science · Physics 2018-05-29 Yoritaka Furukawa , Taichi Kosugi , Hirofumi Nishi , Yu-ichiro Matsushita

Tunneling data on MgB_{1.8}C_{0.2} show a reduction in the energy gap of the pi-bands by a factor of two from undoped MgB2 that is consistent with the Tc reduction, but inconsistent with the expectations of the dirty limit. Dirty-limit…

Superconductivity · Physics 2009-11-10 H. Schmidt , K. E. Gray , D. G. Hinks , J. F. Zasadzinski , M. Avdeev , J. D. Jorgensen , J. C. Burley