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An attractive class of materials for photo(electro)chemical reactions are hybrids based on semiconducting metal oxides and nanocarbons (e.g. carbon nanotubes (CNT), graphene), where the nanocarbon acts as a highly-stable conductive scaffold…

Using ab initio methods, we examine the the charge distribution at the interface of alpha-alumina-supported Pt films, and we consider the influence of this interface on CO adsorption. We demonstrate that a combination of electrostatic…

Materials Science · Physics 2012-03-12 Valentino R. Cooper , Alexie M. Kolpak , Yashar Yourdshahyan , Andrew M. Rappe

The particle transport of impurities in magnetically confined plasmas under some conditions does not find, neither quantitatively nor qualitatively, a satisfactory theory-based explanation. This compromise the successful realization of…

Understanding the electronic properties of dopants near an interface is a critical challenge for nano-scale devices. We have determined the effect of dielectric mismatch and quantum confinement on the ionization energy of individual…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 J. A. Mol , J. Salfi , J. A. Miwa , M. Y. Simmons , S. Rogge

Zinc oxide (ZnO) is the most important material for the fabrication of modern varistors (variable resistors). It is known that the highly nonlinear current-voltage relationship of ZnO varistors is due to effects taking place at the grain…

Materials Science · Physics 2010-03-30 Jan Harloff

Two-dimensional charge carrier accumulation at oxide heterointerfaces presents a paradigm shift for oxide electronics. Like a capacitor, interfacial charge buildup couples to an electric field across the dielectric medium. To prevent the…

Materials Science · Physics 2018-06-25 Valentino R. Cooper , Houlong L. Zhuang , Lipeng Zhang , P. Ganesh , Haixuan Xu , Paul R. C. Kent

The reduced dimensionality in two-dimensional materials leads a wealth of unusual properties, which are currently explored for both fundamental and applied sciences. In order to study the crystal structure, edge states, the formation of…

Mesoscale and Nanoscale Physics · Physics 2021-01-04 Felix Kern , Martin Linck , Daniel Wolf , Nasim Alem , Himani Arora , Sibylle Gemming , Artur Erbe , Alex Zettl , Bernd Büchner , Axel Lubk

Biphasic interfaces are complex but fascinating regimes that display a number of properties distinct from those of the bulk. The CO$_2$-H$_2$O interface, in particular, has been the subject of a number of studies on account of its…

Materials Science · Physics 2025-02-13 Samuel G. H. Brookes , Venkat Kapil , Christoph Schran , Angelos Michaelides

The electrostatic interaction between colloidal particles trapped at the interface between two immiscible electrolyte solutions is studied in the limit of small inter-particle distances. Within an appropriate model exact analytic…

Soft Condensed Matter · Physics 2014-05-07 Arghya Majee , Markus Bier , S. Dietrich

We study the chemical nature of the bonding of an oxide layer to the parent metal. In order to disentangle chemical effects from strain/misfit, Ti(10$\bar{1}$0)/TiO$_{2}$(100) interface has been chosen. We use the density functional…

Materials Science · Physics 2012-12-10 Linggang Zhu , Graeme J. Ackland

Electrical characterization of few-layer MoS2 based field effect transistors with Ti/Au electrodes is performed in the vacuum chamber of a scanning electron microscope in order to study the effects of electron beam irradiation on the…

Catalytic conversion of CO$_2$ into useful chemicals is an attractive alternative to expensive physical carbon sequestration methods. However, this approach is challenging because current chemical conversion methods employ high temperatures…

Chemical Physics · Physics 2015-07-30 Babatunde Alawode , Alexie Kolpak

First-principles calculations based on density-functional theory in the pseudo-potential approach have been performed for the total energy, crystal structure and cell polarization for SrTaO$_2$N/SrTiO$_3$ heterostructures. Different…

Quantitative description of reaction mechanisms in aqueous phase electrochemistry requires experimental characterization of local water structure at the electrode/aqueous interface and its evolution with changing potential. Gaining such…

Chemical Physics · Physics 2017-11-07 Yujin Tong , François Lapointe , Matin Thämer , Martin Wolf , R. Kramer Campen

Two-dimensional electron gas (2DEG) in interfaces and surfaces based on perovskite SrTiO$_3$ (STO) has exhibited various interesting phenomena and is used to develop oxide electronics. Recently, KTaO$_3$ (KTO) shows great potential and is…

Materials Science · Physics 2022-01-17 Ning Wu , Bang-Gui Liu

Atomic and electronic structures of TiO_2(110) surface with possible adsorptional, substitutional and interstitial Au or Pt elemental impurities at full and one-sixth monolayer concentrations were investigated by density functional theory…

Strongly Correlated Electrons · Physics 2012-11-19 Ersen Mete , Oğuz Gülseren , Şinasi Ellialtıoğlu

The analysis of the structure, chemical stability, electronic and ferroelectric properties of the interfaces between Pt(001) and PbZrTiO$_3$(001) (PZT) have been performed with $ab$ $initio$ methods. We show that the chemical environment…

Materials Science · Physics 2020-01-08 Anna V. Kimmel

Electronic charge transfer at the atomic scale can reveal fundamental information about chemical bonding, but is far more challenging to directly image than the atomic structure. The charge density is dominated by the atomic nuclei, with…

Materials Science · Physics 2025-05-01 Christoph Hofer , Jacob Madsen , Toma Susi , Timothy J. Pennycook

The electrostatic interaction between two non-identical, moderately charged colloids situated in close proximity of each other at a fluid interface is studied. By resorting to a well-justified model system, this problem is analytically…

Soft Condensed Matter · Physics 2018-04-30 Arghya Majee , Timo Schmetzer , Markus Bier

Study of the dephasing in electronic systems is not only important for probing the nature of their ground states, but also crucial to harnessing the quantum coherence for information processing. In contrast to well-studied conventional…

Mesoscale and Nanoscale Physics · Physics 2017-07-14 Jian Liao , Yunbo Ou , Haiwen Liu , Ke He , Xucun Ma , Qi-Kun Xue , Yongqing Li
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