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The interface between semiconductors and ion-conducting electrolytes is characterised by charge distributions and potential drops that vary substantially with the evolution of surface states. These surface states at the very interface to…

Materials Science · Physics 2025-12-23 Marco Flieg , Margot Guidat , Matthias M. May

Interference Gating or iGate is a unique method for ultrafast time-resolved electron holography in a transmission electron microscope enabling a spatiotemporal resolution in the nm and ns regime with a minimal technological effort. Here,…

Applied Physics · Physics 2024-05-16 Tolga Wagner , Hüseyin Çelik , Dirk Berger , Ines Häusler , Michael Lehmann

In order to develop a better understanding of electrochemical $\mathrm{O_2}$ reduction in non-aqueous solvents, we apply two-photon photoelectron spectroscopy to probe the dynamics of $\mathrm{O_2}$ reduction at a DMSO/Cu(111) model battery…

Materials Science · Physics 2023-01-12 Angelika Demling , Sarah B. King , Philip Shushkov , Julia Stähler

We study the electrostatic potential of a molecular wire bridging two metallic electrodes in the limit of weak contacts. With the use of a tight-binding model including a fully three-dimensional treatment of the electrostatics of the…

Chemical Physics · Physics 2007-05-23 Stéphane Pleutin , Hermann Grabert , Gert-Ludwig Ingold , Abraham Nitzan

Understanding electrochemical interfaces at a microscopic level is essential for elucidating important electrochemical processes in electrocatalysis, batteries and corrosion. While \textit{ab initio} simulations have provided valuable…

Chemical Physics · Physics 2025-07-08 Jia-Xin Zhu , Jun Cheng

At the (001) interface between the two band-insulators LaAlO3 and SrTiO3, a high-mobility electron gas may appear, which has been the object of numerous works over the last four years. Its origin is a subject of debate between the interface…

Ionic crystals terminated at oppositely charged polar surfaces are inherently unstable and expected to undergo surface reconstructions to maintain electrostatic stability. Essentially, an electric field that arises between oppositely…

We propose the design of low strained and energetically favourable mono and bilayer graphene overlayer on anatase TiO$_2$ (001) surface and examined the electronic structure of the interface with the aid of first principle calculations. In…

Materials Science · Physics 2020-12-22 Shashi B. Mishra , Somnath C. Roy , B. R. K. Nanda

Visualizing individual charges confined to molecules and observing their dynamics with high spatial resolution is a challenge for advancing various fields in science, ranging from mesoscopic physics to electron transfer events in biological…

Mesoscale and Nanoscale Physics · Physics 2016-09-19 Tatiana Latychevskaia , Flavio Wicki , Jean-Nicolas Longchamp , Conrad Escher , Hans-Werner Fink

The Hall coefficient $R_H$ and resistivity $\rho$ of the topological insulator Bi$_2$Te$_2$Se display a number of puzzling features vs. temperature $T$. We propose a model that describes well the non-monotonic variation of $R_H(T)$. A key…

Mesoscale and Nanoscale Physics · Physics 2011-10-06 Yongkang Luo , Stephen Rowley , Jun Xiong , Shuang Jia , R. J. Cava , N. P. Ong

The effective barrier height between an electrode and a ferroelectric (FE) depends on both macroscopic electrical properties and microscopic chemical and electronic structure. The behavior of a prototypical electrode/FE/electrode structure,…

In this paper for the first time we report the results of molecular dynamics simulation of electrode/electrolyte interface of Li-O2 cathode under potential close to experimental values in 1M dimethyl sulfoxide (DMSO) solution of LiPF6 salt.…

Chemical Physics · Physics 2017-01-10 Artem Sergeev , Alexander Chertovich , Daniil Itkis , Anik Sen , Axel Gross , Alexei Khokhlov

We present measurements of the electric potential fluctuations on the surface of highly oriented pyrolytic graphite using electrostatic force and atomic force microscopy. Micrometric domain-like potential distributions are observed even…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Yonghua Lu , M. Munoz , C. S. Steplecaru , Cheng. Hao , Ming Bai , N. Garcia , K. Schindler , P. Esquinazi

Atomic-scale understanding of HfO2 ferroelectricity is important to help address many challenges in developing reliable and high-performance ferroelectric HfO2 (fe-HfO2) based devices. Though investigated from different angles, a factor…

Materials Science · Physics 2022-01-05 Shihui Zhao , Bowen Li , Yuzheng Guo , Huanglong Li

Motivated by the need for less destructive imaging of nanostructures, we pursue point-source in-line holography (also known as point projection microscopy, or PPM) with very low energy electrons (-100 eV). This technique exploits the recent…

Materials Science · Physics 2015-05-27 Lucian Livadaru , Josh Mutus , Robert A. Wolkow

The deposition of a thin oxide layer at metal/semiconductor interfaces has been previously reported as a means of reducing contact resistance in 2D electronics. Using X-ray photoelectron spectroscopy with in-situ Ti deposition, we fabricate…

Materials Science · Physics 2019-10-10 Keren M. Freedy , David H. Olson , Patrick E. Hopkins , Stephen J. McDonnell

Two-dimensional (2D) perovskite oxide interfaces are ideal systems where diverse emergent properties can be uncovered.The formation and modification of polaronic properties due to short-range strong charge-lattice interactions of 2D…

We study the effects of electrostatic gating on the lateral distribution of charge carriers in two dimensional devices, in a non-linear dielectric environment. We compute the charge distribution using the Thomas-Fermi approximation to model…

Mesoscale and Nanoscale Physics · Physics 2020-03-05 Eylon Persky , Hyeok Yoon , Yanwu Xie , Harold Y. Hwang , Jonathan Ruhman , Beena Kalisky

The electrostatic potential across a short ballistic molecular conductor depends sensitively on the geometry of its environment, and can affect its conduction significantly by influencing its energy levels and wave functions. We illustrate…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Gengchiau Liang , Avik Ghosh , Magnus Paulsson , Supriyo Datta

Ab initio calculations using the local spin density approximation and also including the Hubbard $U$ have been performed for three low energy configurations of the interface between LaAlO$_3$ and TiO$_2$-anatase. Two types of interfaces…

Materials Science · Physics 2012-04-13 Mariana Weissmann Valeria Ferrari