Related papers: Genesis of Polyatomic Molecules in Dark Clouds: CO…
We explore the origin of fast molecular outflows that have been observed in Active Galactic Nuclei (AGN). Previous numerical studies have shown that it is difficult to create such an outflow by accelerating existing molecular clouds in the…
We review the relevance of H2 molecules for structure formation in cosmology. Molecules are important at high redshifts, when the first collapsed structures appear with typical temperatures of a few hundred Kelvin. In these chemically…
{It has recently been proposed that giant molecular complexes form at the sites where streams of diffuse warm atomic gas collide at transonic velocities.} {We study the global statistics of molecular clouds formed by large scale colliding…
Sulfur dioxide (SO2) is a sulfur-containing molecule expected to exist as a solid in the interstellar medium (ISM). In this study, we performed laboratory experiments and computational analyses on the surface reactions of solid SO2 with…
The $\rm H_2$ mass of molecular clouds has traditionally been traced by the CO(J=1-0) rotational transition line. This said, CO is relatively easily photodissociated, and can also be destroyed by cosmic rays, thus rendering some fraction of…
We use the moving mesh code AREPO coupled to a time-dependent chemical network to investigate the formation and destruction of molecular gas in simulated spiral galaxies. This allows us to determine the characteristics of the gas that is…
CO$_2$ is an important, stable, and abundant molecule in the Universe, but it is very difficult to detect because it has no observable pure rotational transitions. The unique sensitivity and resolution of the James Webb Space Telescope…
A number of recent experimental studies have shown that solid-state complex organic molecules (COMs) can form under conditions that are relevant to the CO freeze-out stage in dense clouds. In this work, we show that alcohols can be formed…
Chemical processes taking place on ice-grain mantles are pivotal to the complex chemistry of interstellar environments. In this study, we conducted a comprehensive analysis of the catalytic effects of an amorphous solid water (ASW) surface…
It has been implicitly assumed that ices on grains in molecular clouds and proto planetary disks are formed by homogeneous layers regardless of their composition or crystallinity. To verify this assumption, we observed the H2O deposition…
Modelling the molecular gas that is routinely detected through CO observations of high-redshift galaxies constitutes a major challenge for ab initio simulations of galaxy formation. We carry out a suite of cosmological hydrodynamic…
Solid O2 has been proposed as a possible reservoir for oxygen in dense clouds through freeze-out processes. The aim of this work is to characterize quantitatively the physical processes that are involved in the desorption kinetics of CO-O2…
Molecular oxygen has been confirmed as the fourth most abundant molecule in cometary material O$_2$/H$_2$O $\sim 4$ %) and is thought to have a primordial nature, i.e., coming from the interstellar cloud from which our solar system was…
Complex organic molecules (COMs) have been observed not only in the hot cores surrounding low- and high- mass protostars, but also in cold dark clouds. Therefore, it is interesting to understand how such species can be formed without the…
Context. Water together with O2 are important gas phase ingredients to cool dense gas in order to form stars. On dust grains, H2 O is an important constituent of the icy mantle in which a complex chemistry is taking place, as revealed by…
We use 3D-PDR, a three-dimensional astrochemistry code for modeling photodissociation regions (PDRs), to post-process hydrodynamic simulations of turbulent, star-forming clouds. We focus on the transition from atomic to molecular gas, with…
Many theoretical and laboratory studies predict H2 to be formed in highly excited ro-vibrational states. The consequent relaxation of excited levels via a cascade of infrared transitions might be observable in emission from suitable…
Complex organic molecules (COMs) are widely detected in protostellar and protoplanetary systems, where they are thought to have been inherited in large part from earlier evolutionary phases. The chemistry of COMs in these earlier phases,…
The long-timescale behavior of adsorbed carbon monoxide on the surface of amorphous water ice is studied under dense cloud conditions by means of off-lattice, on-the-fly, kinetic Monte Carlo simula- tions. It is found that the CO mobility…
We examine several different simplified approaches for modelling the chemistry of CO in three-dimensional numerical simulations of turbulent molecular clouds. We compare the different models both by looking at the behaviour of integrated…