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The mobility of atoms, molecules and radicals in icy grain mantles regulate ice restructuring, desorption, and chemistry in astrophysical environments. Interstellar ices are dominated by H2O, and diffusion on external and internal (pore)…
We describe a phenomenological model for molecular hydrogen formation suited for applications in galaxy formation simulations, which includes on-equilibrium formation of molecular hydrogen on dust and approximate treatment of both its…
Recent observations with the Submillimeter Wave Astronomy Satellite indicate abundances of gaseous H2O and O2 in dense molecular clouds which are significantly lower than found in standard homogeneous chemistry models. We present here…
We have performed experimental investigations of methanol formation via the reactions of low energy $CH_{3}^{+}$ ions with an amorphous solid water (ASW) surface around 10 K. A newly developed experimental apparatus enabled irradiation of…
A model is proposed for the formation of water ice mantles on grains in interstellar clouds. This occurs by direct accretion of monomers from the gas, be they formed by gas or surface reactions. The model predicts the existence of a…
The recent discovery of terrestrial-type organic species such as methyl formate and dimethyl ether in the cold interstellar gas has proved that the formation of organic matter in the Galaxy begins at a much earlier stage of star formation…
Formation of interstellar complex organic molecules is currently thought to be dominated by the barrierless coupling between radicals on the interstellar icy grain surfaces. Previous standard DFT results on the reactivity between CH$_3$ and…
The results of experiments on the formation of molecular hydrogen on low density and high density amorphous ice surfaces are analyzed using a rate equation model. The activation energy barriers for the relevant diffusion and desorption…
Clouds containing molecular dark matter in quantities relevant for star formation may exist in minihaloes of the type of cold dark matter included in many cosmological simulations or in the regions of some galaxies extending far beyond…
The build-up of galaxies is regulated by a complex interplay between gravitational collapse, galaxy merging and feedback related to AGN and star formation. The energy released by these processes has to dissipate for gas to cool, condense,…
CO2 ices are known to exist in different astrophysical environments. In spite of this, its physical properties (structure, density, refractive index) have not been as widely studied as those of water ice. It would be of great value to study…
In the Milky Way and other main-sequence galaxies, stars form exclusively in molecular gas, which is traced by CO emission. However, low metallicity dwarf galaxies are often `CO-dark' in the sense that CO emission is not observable even at…
We investigate the propagation of a shock wave into a warm neutral medium and cold neutral medium by one-dimensional hydrodynamic calculations with detailed treatment of thermal and chemical processes. Our main result shows that thermal…
We examine the triggering process of molecular cloud formation around diffuse HII regions. We calculate the time evolution of the shell as well as of the HII region in a two-phase neutral medium, solving the UV and FUV radiative transfer,…
The formation of correlated structures is of importance in many diverse contexts such as strongly coupled plasmas, soft matter, and even biological mediums. In all these contexts the dynamics are mainly governed by electrostatic…
We present a suite of six fully cosmological, three-dimensional simulations of the collapse of an atomic cooling halo in the early Universe. We use the moving-mesh code arepo with an improved primordial chemistry network to evolve the…
Irradiation- and collision-induced fragmentation studies provide information about geometry, electronic properties and interactions between structural units of various molecular systems. Such knowledge brings insights into…
In the currently-accepted model for star formation out of the interstellar gas in galaxies, the basic construction material is assumed to be large clouds of atomic hydrogen (HI). These clouds are thought to form higher-density complexes of…
The chemistry of the diffuse interstellar medium is driven by the combined influences of cosmic rays, ultraviolet (UV) radiation, and turbulence. Previously detected at the outer edges of photodissociation regions (PDRs) and formed from the…
We report here a study of reversible pressure-induced structural transformation between two amorphous forms of SO$_2$: molecular at pressures below 26 GPa and polymeric above this pressure, at temperatures of 77 - 300 K. The transformation…