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Density functional theory is usually formulated in terms of the density in configuration space. Functionals of the momentum-space density have also been studied, and yet other densities could be considered. We offer a unified view from a…

This article presents a reformulation of the Theory of Functional Connections: a general methodology for functional interpolation that can embed a set of user-specified linear constraints. The reformulation presented in this paper exploits…

Numerical Analysis · Mathematics 2020-08-07 Carl Leake , Hunter Johnston , Daniele Mortari

We review some of the basic mathematical results about density functional theory.

Mathematical Physics · Physics 2023-04-12 Heinz Siedentop

Density Functional Theory (DFT) is one of the most widely used methods for "ab initio" calculations of the structure of atoms, molecules, crystals, surfaces, and their interactions. Unfortunately, the customary introduction to DFT is often…

Physics Education · Physics 2010-12-07 Nathan Argaman , Guy Makov

The restoration of particle number within Energy Density Functional theory is analyzed. It is shown that the standard method based on configuration mixing leads to a functional of both the projected and non-projected densities. As an…

Nuclear Theory · Physics 2011-08-08 Guillaume Hupin , Denis Lacroix , Michael Bender

The ongoing replication crisis in science has increased interest in the methodology of replication studies. We propose a novel Bayesian analysis approach using power priors: The likelihood of the original study's data is raised to the power…

Methodology · Statistics 2023-09-28 Samuel Pawel , Frederik Aust , Leonhard Held , Eric-Jan Wagenmakers

Usually, density functional models are considered approximations to density functional theory, However, there is no systematic connection between the two, and this can make us doubt about a linkage. This attitude can be further enforced by…

Chemical Physics · Physics 2020-11-10 Andreas Savin

This note states and proves a representation theorem for regular quantity functions, based on the theory of quantity spaces, thereby giving a new perspective on dimensional analysis and the classical $\pi$ theorem.

Rings and Algebras · Mathematics 2020-05-22 Dan Jonsson

Potential functional approximations are an intriguing alternative to density functional approximations. The potential functional that is dual to the Lieb density functional is defined and properties given. The relationship between…

Other Condensed Matter · Physics 2014-01-08 Attila Cangi , E. K. U. Gross , Kieron Burke

Though calculations based on density functional theory (DFT) are used remarkably widely in chemistry, physics, materials science, and biomolecular research and though the modern form of DFT has been studied for almost 60 years, some…

In a recent paper [Phys. Rev. A 77, 062511 (2008)], it was advocated to modify the variational principle for the action-integral functional in the Runge-Gross foundation of time-dependent density-functional theory. This was criticised in a…

Other Condensed Matter · Physics 2011-05-16 J. Schirmer

We establish a new generalized Taylor's formula for power fractional derivatives with nonsingular and nonlocal kernels, which includes many known Taylor's formulas in the literature. Moreover, as a consequence, we obtain a general version…

Spectral Theory · Mathematics 2024-01-29 Hanaa Zitane , Delfim F. M. Torres

Force fields are usually formulated directly in nuclear configuration space, whereas density functional theory is naturally formulated in terms of external potentials, densities, and variational duality. We show that exact force fields are…

Chemical Physics · Physics 2026-04-30 Nan Sheng

The derivation is studied in relation with the space of Schwartz of functions. This paper has been withdrawn by the author.

Classical Analysis and ODEs · Mathematics 2007-05-23 Antoine Balan

This work introduces a new functional series for expanding an analytic function in terms of an arbitrary analytic function. It is generally applicable and straightforward to use. It is also suitable for approximating the behavior of a…

General Mathematics · Mathematics 2012-04-27 Henrik Stenlund

We consider the set of power functions defined on the set of positive real number, and their linear combinations. After recalling some properties of the gamma function, we give two general definitions of derivatives of positive and negative…

General Mathematics · Mathematics 2015-04-29 Raoelina Andriambololona , Tokiniaina Ranaivoson , Hanitriarivo Rakotoson , Raboanary Roland

This article has been published as a chapter in "Chemical Reactivity Theory: A Density Functional View", ed. P. K. Chattaraj (CRC Press, New York, 2009), ch. 8, p. 105. In it, an overview of the relationship between time-dependent DFT and…

Quantum Physics · Physics 2010-03-03 A. S. Sanz , X. Gimenez , J. M. Bofill , S. Miret-Artes

The rich and diverse dynamics of particle-based systems ultimately originates from the coupling of their degrees of freedom via internal interactions. To arrive at a tractable approximation of such many-body problems, coarse-graining is…

Soft Condensed Matter · Physics 2022-03-31 Matthias Schmidt

We prove a stronger version of Jarden's Theorem for recurrence of powers of recursive functions

Number Theory · Mathematics 2013-07-02 Cheng Lien Lang , Mong Lung Lang

A density-functional theory is developed based on the Maxwell--Schr\"odinger equation with an internal magnetic field in addition to the external electromagnetic potentials. The basic variables of this theory are the electron density and…

Chemical Physics · Physics 2018-01-17 Erik Tellgren
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