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The selection rules for dipole and Raman activity can be relaxed due to local distortion of a crystalline structure. In this situation a dipole-inactive mode can become simultaneously active in Raman scattering and in dipole interaction…

Disordered Systems and Neural Networks · Physics 2009-09-25 Lev I. Deych , M. Erementchouk , V. A. Ignatchenko

Raman spectroscopy uses light scattering to extract information on low-energy excitations of solids. The Raman process is described by diagrams which are fourth order in the light-matter interaction, and in particular the resonant…

Strongly Correlated Electrons · Physics 2024-01-30 Philipp Werner , Martin Eckstein , Naoto Tsuji

In the last decade, hybrid organic-inorganic halide perovskites have emerged as a new type of semiconductor for photovoltaics and other optoelectronic applications. Unlike standard, tetrahedrally bonded semiconductors (e.g. Si and GaAs),…

We describe a simplified approach to simulating Raman spectra using ab initio molecular dynamics (AIMD) calculations. Our protocol relies on on-the-fly calculations of approximate molecular polarizabilities using a sum over orbitals (as…

Raman optical activity (ROA), the dependence of Raman intensity on the circular polarization of incident and scattered light, has traditionally been observed in chiral molecules and magnetic materials, where inversion or time-reversal…

We report on Raman scattering measurements of single crystalline La$_{1-x}$Sr$_x$MnO$_3$ ($x$=0, 0.06, 0.09 and 0.125), focusing on the high frequency regime. We observe multi-phonon scattering processes up to fourth-order which show…

The polarized Raman scattering spectra from freshly cleaved $ab$, $ac$, and $bc$ surfaces of high quality twin free YBa$_2$Cu$_3$O$_{6.5}$ (Ortho-II) single crystals ($T_c$=57.5 K and $\Delta T = 0.6$ K) were studied between 80 and 300 K.…

Superconductivity · Physics 2008-03-14 M. N. Iliev , V. G. Hadjiev , S. Jandl , D. Le Boeuf , V. N. Popov , D. Bonn , R. Liang , W. N. Hardy

We explain quantitatively why resonant Raman scattering spectroscopy, an extensively used experimental tool in studying elementary electronic excitations in doped low dimensional semiconductor nanostructures, always produces an observable…

Strongly Correlated Electrons · Physics 2009-10-31 S. Das Sarma , Daw-Wei Wang

Angle-resolved polarized Raman (ARPR) spectroscopy provides insights into optical anisotropy and symmetry-related electron-photon/electron-phonon couplings of anisotropic layered materials (ALMs). However, since their discovery over ten…

Mesoscale and Nanoscale Physics · Physics 2025-07-21 Jia-Liang Xie , Tao Liu , Yu-Chen Leng , Rui Mei , Heng Wu , Chen-Kai Liu , Jia-Hong Wang , Yang Li , Xue-Feng Yu , Miao-Ling Lin , Ping-Heng Tan

Coherent Raman scattering provides highly sensitive vibrational analysis through nonlinear light-matter interactions. However, its application to metal interfaces has remained challenging because the intrinsically large non-resonant…

Erratum: In our paper, we show that the spectral representation for isotropic two-component composites also applies to uniaxial polycrystals. We have learned that this result was, in fact, first conjectured by G.W. Milton. While our…

Condensed Matter · Physics 2015-08-24 S. Barabash , D. Stroud

Raman spectroscopy is widely applied to detect different chemical compounds in organic matter and create label-free high-resolution maps on the level of separate cells. The main advantage of this technique is the possibility to study…

Applied Physics · Physics 2025-01-15 Petr Shvets , Aleksandr Goikhman

We introduce the first method to enable an optical amplification of a coherent Raman spectroscopy signal called radio frequency Doppler Raman spectroscopy. Doppler Raman measurements amplify the optical signals in coherent Raman…

We present an \textit{ab initio} study based on density-functional theory of first- and second-order Raman spectra of graphene-based materials with different stacking arrangements and numbers of layers. Going from monolayer and bilayer…

Materials Science · Physics 2018-06-18 Albin Hertrich , Caterina Cocchi , Pasquale Pavone , Claudia Draxl

The hyperbolic dispersion relation of phonon-polaritons (PhPol) provides high-momentum states, highly directional propagation, subdiffractional confinement, large optical density of states, and enhanced light-matter interactions. In this…

Materials Science · Physics 2023-07-12 A. Bergeron , C. Gradziel , R. Leonelli , S. Francoeur

Temperature-dependent Raman spectra of TbMnO$_3$ from 5 K to 300 K in the spectral range of 200 to 1525 cm$^{-1}$ show five first-order Raman allowed modes and two high frequency modes. The intensity ratio of the high frequency Raman band…

Strongly Correlated Electrons · Physics 2010-04-12 Pradeep Kumar , Surajit Saha , D. V. S. Muthu , J. R. Sahu , A. K. Sood , C. N. R. Rao

A theory of resonant Raman scattering spectroscopy of one dimensional electronic systems is developed on the assumptions that (i) the excitations of the one dimensional electronic system are described by the Luttinger Liquid model, (ii)…

Strongly Correlated Electrons · Physics 2016-08-31 D. -W. Wang , A. J. Millis , S. Das Sarma

Particle-in-cell (PIC) simulations of relativistic shocks are in principle capable of predicting the spectra of photons that are radiated incoherently by the accelerated particles. The most direct method evaluates the spectrum using the…

High Energy Astrophysical Phenomena · Physics 2015-05-20 Brian Reville , John G. Kirk

Inelastic light scattering spectra of Bi_2Se_3 and Sb_2Te_3 single crystals have been measured over the temperature range from 5 K to 300 K. The temperature dependence of dominant A^{2}_{1g} phonons shows similar behavior in both materials.…

We present a systematic study of the Raman spectra of optical phonons in graphene monolayers under tunable uniaxial tensile stress. Both the G and 2D bands exhibit significant red shifts. The G band splits into two distinct sub-bands (G+,…

Materials Science · Physics 2008-12-15 Mingyuan Huang , Hugen Yan , Changyao Chen , Daohua Song , Tony F. Heinz , James Hone