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Pb(Zn$_{1/3}$Nb$_{2/3}$)O$_{3}$ is one of the simplest representatives of the lead ferroelectric relaxors. Its solid solution with PbTiO$_{3}$, at concentrations near the morphotropic phase boundary, is especially important. In this paper,…

Materials Science · Physics 2007-05-23 O. Svitelskiy , D. La-Orauttapong , J. Toulouse , W. Chen , Z. -G. Ye

We calculate the eigenstates of a diatomic molecule in a range of model mean-field potentials, and evaluate the evolution of their associated Raman spectra with field strength. We demonstrate that dramatic changes in the appearance of the…

Materials Science · Physics 2022-02-22 Peter I. C. Cooke , Ioan B. Magdău , Graeme J. Ackland

High-gain resonant nonlinear Raman scattering on trapped cold atoms within a high-fineness ring optical cavity is simply explained under a nonlinear opto-mechanical mechanism, and a proposal using it to detect frequency of micro-trap on…

Atomic Physics · Physics 2014-03-24 Lin Zhang

The interest of micro and tip-enhanced Raman spectroscopy to analyze nanosized and nanostructured materials, chiefly semiconductors, oxides and pristine or functionalized carbon nanotubes, is reviewed at the light of the contributions to…

Materials Science · Physics 2007-06-07 Philippe Colomban , Gwénael Gouadec

We present an approach for the efficient calculation of vibrational Raman intensities in periodic systems within density functional theory. The Raman intensities are computed from the second order derivative of the electronic density matrix…

Materials Science · Physics 2009-11-07 Michele Lazzeri , Francesco Mauri

Raman spectroscopy provides spectral information related to the specific molecular structures of substances and has been well established as a powerful tool for studying biological tissues and diagnosing diseases. This article reviews…

We report on the development of a compact (volume $\approx$ 100\:cm$^3$), multimode diffraction-limited Raman spectrograph and probe designed to be compact as possible. The spectrograph uses `off the shelf' optics, a custom 3D-printed…

Instrumentation and Detectors · Physics 2020-03-04 Christopher H. Betters , Joss Bland-Hawthorn , Salah Sukkarieh , Itandehui Gris-Sanchez , Sergio G. Leon-Saval

We review recent development in Raman techniques and diamond anvil cell technology, that allow measurements of Raman of metals in the megabar pressure range. The Raman technique includes holographic transmission optics and single-stage…

In recent years, nanostructuring of dielectric and semiconducting crystals has enhanced controllability of their thermal conductivity. To carry out computational material search for nanostructured materials with desirable thermal…

Mesoscale and Nanoscale Physics · Physics 2016-02-23 Takuma Shiga , Daisuke Aketo , Lei Feng , Junichiro Shiomi

First principles computations of Raman intensities were performed for perovskite-family compound CaAl$_{1/2}$Nb$_{1/2}$O$_3$ (CAN). This compound features 1:1 (NaCl-type) ordering of Al and Nb superimposed onto the $b^-b^-c+$ octahedral…

Materials Science · Physics 2009-11-10 S. A. Prosandeev , U. Waghmare , I. Levin , J. Maslar

We have investigated ten standard single crystal substrates of complex oxides on the account of their applicability in the Raman spectroscopy based thin film research. In this study we suggest a spectra normalization procedure that utilizes…

Materials Science · Physics 2015-10-28 L. Gasparov , T. Jegorel , L. Loetgering , S. Middey , J. Chakhalian

We report an investigation of perovskite-type SmScO3 and NdScO3 single crystals by Raman scattering in various scattering configurations and at different wavelengths. The reported Raman spectra, together with the phonon mode assignment, set…

Materials Science · Physics 2011-05-09 O. Chaix-Pluchery , J. Kreisel

We employ a combined experimental-theoretical study of the first- and second-order Raman modes of monoclinic $\beta$-Ga$_{2}$O$_{3}$. The investigated materials is of particular interest due to its deep-UV bandgap paired with a high…

Materials Science · Physics 2022-01-19 Benjamin M. Janzen , Roland Gillen , Zbigniew Galazka , Janina Maultzsch , Markus R. Wagner

A possibility to greatly enhance frequency-conversion efficiency of stimulated Raman scattering is shown by making use of extraordinary properties of three-wave mixing of ordinary and backward waves. Such processes are commonly attributed…

Microscopic description of Raman spectra in nanopowders of nonpolar crystals is accomplished by developing the theory of disorder-induced broadening of optical vibrational eigenmodes. Analytical treatment of this problem is performed, and…

Mesoscale and Nanoscale Physics · Physics 2020-11-25 Oleg I. Utesov , Andrey G. Yashenkin , Sergei V. Koniakhin

Raman spectroscopy is a powerful technique to characterize materials. It probes non-destructively chemical composition, crystallinity, defects, strain and coupling phenomena. However, the Raman response of surfaces or thin films is often…

The Raman spectrum and particularly the Raman scattering intensities of monoclinic $\beta\text{-Ga}_2\text{O}_3$ are investigated by experiment and theory. The low symmetry of $\beta\text{-Ga}_2\text{O}_3$ results in a complex dependence of…

Materials Science · Physics 2017-02-07 Christian Kranert , Chris Sturm , Rüdiger Schmidt-Grund , Marius Grundmann

While many vibrational Raman spectroscopy studies of liquid water have investigated the temperature dependence of the high-frequency O-H stretching region, few have analyzed the changes in the Raman spectrum as a function of temperature…

Ferroaxial order is characterized by the breaking of mirror symmetry parallel to the crystallographic principal axis, which often originates from spontaneous rotational distortions of the crystal lattice. Such rotational distortions are, by…

Graphene has many unique properties that make it an ideal material for fundamental studies as well as for potential applications. Here we review the recent results on the Raman spectroscopy and imaging of graphene. Raman spectroscopy and…

Materials Science · Physics 2008-10-17 Zhen hua Ni , Ying ying Wang , Ting Yu , Ze xiang Shen
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